Geochemistry constraints of Mesozoic–Cenozoic calc-alkaline magmatism in the South Shetland arc, Antarctica

Geochemical data from basalts, basaltic andesites, and andesites of the Mesozoic–Cenozoic (143–44 Ma) from Livingston, Greenwich, Robert, King George, and Ardley Islands of the South Shetland archipelago, Antarctica, are presented. The rocks have variable SiO₂ of approximately 46–61 wt%, Al₂O₃ of 15–26 wt%, and total alkali (K₂O+Na₂O) of 2–6 wt%. Most samples have low Mg#, Cr, and Ni, which indicates that they have undergone significant fractional crystallization from mantle-derived melts. The presence of olivine cumulatic in the samples from Livingston and Robert Islands explains some high MgO, Ni, and Cr values, whereas low Rb, Zr, and Nb values could be related to undifferentiated magmas. N-MORB-normalized trace element patterns show that South Shetland Islands volcanic rocks have a geochemical pattern similar to that found for other island arcs, with enrichment in LILE relative to HFSE and in LREE relative to HREE. The geochemistry pattern and presence of calcic plagioclase, orthopyroxene, Mg-olivine, and titanomagnetite phenocrysts suggest a source related to the subduction process. The geochemical data also suggest magma evolution from the tholeiitic to the calc-alkaline series; some samples show a transitional pattern. Samples from the South Shetland archipelago show moderate LREE/HREE ratios relative to N-MORB and OIB, depletion in Nb relative to Yb, and high Th/Yb ratios. These patterns probably reflect magma derived from a lithospheric mantle source previously modified by fluids and sediments from a subduction zone.

Resumo

Dados geoquímicos de basaltos, andesitos basálticos e andesitos mesozóicos–cenozóicos (143–44 Ma) das ilhas Livingston, Greenwich, Robert, King George e Ardley do Arquipélago Shetland do Sul, Antártica são discutidas neste artigo. As rochas tem conteúdos de SiO₂ variando de 46 a 61%, Al₂O₃ de 15 a 26% e álcalis (K₂O+Na₂O) de 2 a 6%. A maior parte das amostras tem conteúdos baixos de Mg#, Cr e Ni, indicando que sofreram significante cristalização fracionada de fusões derivadas do manto. A presença de fases cumuláticas nas amostras das ilhas Livingston e Robert explicaria os elevados valores de MgO, Ni, Cr, enquanto que baixos valores de Rb, Zr e Nb observados nas amostras destas ilhas poderiam estar relacionados a magmas não diferenciados. Os padrões de elementos-traço normalizados pelo N-MORB mostram que as rochas vulcânicas das Ilhas Shetland do Sul têm padrão geoquímico similar àqueles encontrados em outros arcos de ilhas com enriquecimento em LILE em relação aos HFSE e em ETRL em relação aos ETRP. O padrão geoquímico e a ocorrência de fenocristais de plagioclásio cálcico, ortopiroxênio, olivina magnesiana e titanomagnetita sugerem origem relacionada a processos de subducção. Dados geoquímicos obtidos para as amostras do arquipélago Shetland do Sul sugerem um magma evoluindo de toleítico para cálcico-alcalino, observando-se em algumas amostras um padrão transicional. As amostras do arquipélago Shetland do Sul mostram em relação ao N-MORB e OIB, moderadas razões ETRL/ETRP, empobrecimento em Nb relativo a Yb e elevada razão Th/Yb Estes padrões refletem, provavelmente, magma derivado de uma fonte mantélica litosférica, que foi modificada por fluídos e sedimentos da zona de subducção.     

Pyroclastic Flow Hazard at Volcán Citlaltépetl

Volcán Citlaltépetl (Pico de Orizaba) with an elevation of 5,675 m is the highest volcano in North America. Its most recent catastrophic events involved the production of pyroclastic flows that erupted approximately 4,000, 8,500, and 13,000 years ago. The distribution of mapped deposits from these eruptions gives an approximate guide to the extent of products from potential future eruptions. Because the topography of this volcano is constantly changing computer simulations were made on the present topography using three computer algorithms: energy cone, FLOW2D, and FLOW3D. The Heim Coefficient (), used as a code parameter for frictional sliding in all our algorithms, is the ratio of the assumed drop in elevation (H) divided by the lateral extent of the mapped deposits (L). The viscosity parameter for the FLOW2D and FLOW3D codes was adjusted so that the paths of the flows mimicked those inferred from the mapped deposits. We modeled two categories of pyroclastic flows modeled for the level I and level II events. Level I pyroclastic flows correspond to small but more frequent block-and-ash flows that remain on the main cone. Level II flows correspond to more widespread flows from catastrophic eruptions with an approximate 4,000-year repose period. We developed hazard maps from simulations based on a National Imagery and Mapping Agency (NIMA) DTED-1 DEM with a 90 m grid and a vertical accuracy of ±30 m. Because realistic visualization is an important aid to understanding the risks related to volcanic hazards we present the DEM as modeled by FLOW3D. The model shows that the pyroclastic flows extend for much greater distances to the east of the volcano summit where the topographic relief is nearly 4,300 m. This study was used to plot hazard zones for pyroclastic flows in the official hazard map that was published recently.     

Nouvelles données sur le téphra de Sarliève et le téphra CF7, marqueurs chrono-stratigraphiques de Grande Limagne (Massif central,France)

A trachytic tephra, discovered in the ancient lake of Sarliève, ‘Grande Limagne’, has been dated using the thermoluminescence technique. The obtained age, 16±4 ka ($\text{2}\text{σ}$), is older than that of the trachytic volcanoes of the Cha??ne des Puys, the ashes of which have already been locally recognised in the region. Its analysis confirms its originality. In the course of the comparisons made to search for its spring, it appears that the wide-dispersion tephra CF7, beforehand correlated by hypothesis to the Puy de Clierzou, probably originates from the Kilian crater or the Puy de Vasset. To cite this article: D. Miallier et al., C. R. Geoscience 336 (2004).     

Rhinocerotid tooth enamel 18O/16O variability between 23 and 12 Ma in southwestern France

The relationship between the oxygen isotope ratio of mammal tooth enamel and that of drinking water was used to reconstruct changes in the Miocene oxygen isotope ratio of rainfall (meteoric water ${\delta }^{18}$O_MW). These, in turn, are related to climatic parameters (temperature, precipitation and evaporation rate). ${\delta }^{18}$O values of rhinocerotid teeth from the Aquitaine Basin (southwestern France) suggest a significant climatic change between 17 and 12 Ma, characterized by cooling together with precipitation increase, in agreement with other terrestrial and oceanic records. To cite this article: I. Bentaleb et al., C. R. Geoscience 338 (2006).     

Expériences de drainage et estimation de paramètres en milieu poreux non saturé

Two drainage experiments were carried out to identify the hydraulic parameters of a quartz sand by using inverse modelling. Our results, based on sensitivity and error analyses, show that (i) water content measurements are essential to estimate the parameters of the van Genuchten–Mualem retention curve, (ii) the saturated conductivity ($K_{\mathrm{s}}$) has a low sensitivity to pressure data and is not sensitive to other measures (water content and measured outflow), (iii) the inverse approach can be verified by comparing the simulated outflow to the measured one. To cite this article: H. Beydoun, F. Lehmann, C. R. Geoscience 338 (2006).     

Événements panafricains dans l'Adrar Souttouf (Sahara marocain)

The Adrar Souttouf belt (Western Sahara) lies in the northern part of the Mauritanide belt and was considered as a part of the Hercynian Mauritanian-Appalachian belt. Recently the presence of a Panafrican protolith (595 Ma) was evidenced by the age of inherited zircons from an eclogitic unit and led to consider complex Panafrican events included in the Hercynian belt, as in the central and southern Mauritanide belt. Our new field survey completed by ten KAr dating (whole rocks and separate minerals) confirmed that multiphased Panafrican formations outcrop within the center of the Adrar Souttouf massif. Diverse events ranged from ca. 1000 to 500 Ma, some of them being indicative of an oceanic type environment and metamorphism. The 1000 Ma metamorphic event is recorded for the first time in the West African craton. A large Hercynian remobilisation is also evidenced. To cite this article: M. Villeneuve et al., C. R. Geoscience 338 (2006).     

The Ordovician Sierras Pampeanas–Puna basin connection: Basement thinning and basin formation in the Proto-Andean back-arc

The Ordovician Sierras Pampeanas, located in a continental back-arc position at the Proto-Andean margin of southwest Gondwana, experienced substantial mantle heat transfer during the Ordovician Famatina orogeny, converting Neoproterozoic and Early Cambrian metasediments to migmatites and granites. The high-grade metamorphic basement underwent intense extensional shearing during the Early and Middle Ordovician. Contemporaneously, up to 7000 m marine sediments were deposited in extensional back-arc basins covering the pre-Ordovician basement. Extensional Ordovician tectonics were more effective in mid- and lower crustal migmatites than in higher levels of the crust. At a depth of about 13 km the separating boundary between low-strain solid upper and high-strain lower migmatitic crust evolved to an intra-crustal detachment. The detachment zone varies in thickness but does not exceed about 500 m. The formation of anatectic melt at the metamorphic peak, and the resulting drop in shear strength, initiated extensional tectonics which continued along localized ductile shear zones until the migmatitic crust cooled to amphibolite facies P–T conditions. P–T–d–t data in combination with field evidence suggest significant (ca. 52%) crustal thinning below the detachment corresponding to a thinning factor of 2.1. Ductile thinning of the upper crust is estimated to be less than that of the lower crust and might range between 25% and 44%, constituting total crustal thinning factors of 1.7–2.0. While the migmatites experienced retrograde decompression during the Ordovician, rocks along and above the detachment show isobaric cooling. This suggests that the magnitude of upper crustal extension controls the amount of space created for sediments deposited at the surface. Upper crustal extension and thinning is compensated by newly deposited sediments, maintaining constant pressure at detachment level. Thinning of the migmatitic lower crust is compensated by elevation of the crust–mantle boundary. The degree of mechanical coupling between migmatitic lower and solid upper crust across the detachment zone is the main factor controlling upper crustal extension, basin formation, and sediment thickness in the back-arc basin. The initiation of crustal extension in the back-arc, however, crucially depends on the presence of anatectic melt in the middle and lower crust. Consumption of melt and cooling of the lower crust correlate with decreasing deposition rates in the sedimentary basins and decreasing rates of crustal extension.     

Determination of Molybdenum, Antimony and Tungsten at sub μg g−1 Levels in Geological Materials by ID-FI-ICP-MS

We have developed a rapid and accurate method for the determination of Mo, Sb and W in geological samples using isotope dilution inductively coupled plasma-mass spectrometry with a flow injection system (ID-FI-ICP-MS). The chemical procedure requires HF digestion of the sample with a Mo-Sb-W mixed spike, subsequent evaporation and dissolution of Mo, Sb and W from Mg and Ca fluorides with HF. Recovery yields of Mo, Sb and W in the extraction were > 94% for samples of peridotite, basalt and andesite composition, with the exception of W in samples of peridotite composition for which recovery was 81%. No matrix effects were observed in the determination of the isotope ratios of Mo, Sb and W in solutions prepared from peridotite, basalt and andesite samples down to a dilution factor of 100. Detection limits of Mo, Sb and W in silicate materials were at the several ng g⁻¹ level. Analysis of the silicate reference materials PCC-1, DTS-1, BCR-1, BHVO-1, AGV-1 from the US Geological Survey and JP-1, JB-1, -2, -3, JA-1, -2, and -3 from the Geological Survey of Japan as well as the Smithsonian reference Allende powder yielded reliable Mo, Sb and W concentrations. The repeatability in the analysis of basalts and andesites was < 9%. This technique requires only 0.2 ml sample solution, and is therefore suitable for analyzing small and/or precious samples such as meteorites, mantle peridotites and their mineral separates.