破火山口研究述评

破火山研究是火山学研究的一个重要分支,也是国内外学者持续关注的热点,这是因为形成破火山口的岩浆演化时间长,多是大型多金属、贵金属、铀矿等矿床的聚集地,大型破火山口的形成在地球生物进化史中影响很大。 笔者等对破火山口的概念、容易混淆使用的分类和名词、世界知名破火山口及其形成理论研究、大型破火山口的研究认识与矿床形成的关系、中国破火山研究和今后努力的方向进行了一个总结。 实际上在科学研究的阶梯上搭了一个向上继续向上的阶。 期待学者在这方面又高水平的研究,为国家战略资源保障和为世界破火山口研究做出中国贡献。     

浙江拔茅破火山岩浆作用：开放体系多机制复合演化

拔茅火山杂岩的成分变化范围广泛,包括玄武质,玄武粗安质,粗面安山质,粗面英安质,流纹英安质到流纹质和高硅流纹质岩石都有,它们不是由单一母岩浆演化而来,也不是由单一岩浆房喷发形成的,而是来自多种类型的岩浆房,并经历过复杂的演化过程,为开放体系多机制复合演化,其中早期双峰式基性端元是由上地幔部分熔融形成的,而酸性端无则是地壳物质边熔融边喷发（分离熔融）的结果,作为火山杂岩主体的粗面英安质岩石,其岩浆是在高位主岩浆房内由玄武质岩浆与流纹英安质岩浆混合形成的,发生混合的流纹英安质与玄武质岩浆的比例为57：43,而粗面安山质岩浆则是溶部岩浆房内由玄武质岩浆分离结晶形成的,晚期侵出－侵入的流纹英安质岩穹和高硅流纹斑岩株则分别代表高位次级岩浆房的成分及其硅质帽。     

Use of micro-XRF chemical analysis for mapping volcanogenic massive sulfide related hydrothermal alteration: Application to the subaqueous felsic dome-flow complex of the Cap d'Ours section,Glenwood rhyolite,Rouyn-Noranda,Québec,Canada

A new analytical method using micro-X-ray fluorescence (XRF) is presented for the in situ analysis of major elements in rock samples. This approach has allowed for a separate study of hydrothermal alteration of matrix versus fragments in volcaniclastic material (i.e. flow breccia). This is particularly important for volcanogenic massive sulfide (VMS) exploration in subaqueous felsic dome-flow complexes, where brecciated facies are omnipresent and the imprint of hydrothermal alteration is typically heterogeneous. In this study, eleven elements are measured with a 1.7 by 1.3 mm window considered to be representative of each sample, based on replicate analyses. An average is calculated for the analyzed window and yields a nearly complete analysis with the exception of loss of ignition (LOI). Micro-XRF data were validated using whole rock XRF analyses performed on the same sample block. The application of this chemical method has been tested successfully on thin sections from the Cap d'Ours section of the Glenwood rhyolite in the Rouyn-Noranda region of Québec, Canada. With 58 samples spaced at approximately 50 m intervals, two styles of alteration zoning were recognized: (1) a lateral and concordant zoning expressed by vent-proximal silicification in the west grading toward vent-distal chlorite–sericite alteration to the east, and (2) vertical and discordant zoning expressed by stronger sericitization in the upper part of later volcanic quartz- and feldspar-phyric endogenous lobes. The former is typical of cooling induced by seawater interaction at the lava–water interface at temperatures greater than 400 °C, whereas the latter is related to lower temperature (< 300 °C) hydrothermal mineralization associated with endogenous lobe emplacement within the volcanic pile. The presented results clearly demonstrate the potential use of the micro-XRF data for characterizing weak to intense hydrothermal alteration in highly fragmented volcanic rocks.     

New stratigraphic,geochronological, and structural data from the southern Guanajuato Mining District,México: implications for the caldera hypothesis

Abstract

The Cenozoic stratigraphy of the southern Guanajuato Mining District (GMD) was established 40 years ago. The existence of a caldera structure that produced the Cenozoic volcanic cover was postulated and the world-class silver ore deposit of the Oligocene age has been closely related to magmatism. In this context, we present a new geological map of the southern GMD, U–Pb and Ar–Ar ages of the volcanic units, and structural data for the Cenozoic faults. Our results document that the volcanic centre was active between ca. 33.5 Ma and ca. 31.3 Ma, coeval with NW–SE normal faulting. We propose that the Bufa, Calderones, and Cedro formations are stratigraphic units directly related to the volcanic centre. Although the younger Chichíndaro Rhyolite scarcely crops out within the study area, it appears to be more extensive outside of the study area, forming part of the rhyolitic volcanism of the Mesa Central of Mexico. In the study area, the Chichíndaro Rhyolite buries major faults, demonstrating that it was emplaced after the peak of faulting. The two main structures are the El Cubo and Veta Madre grabens; also there are several faulted and brecciated zones where silver–gold mineralization was emplaced. The extension direction changed from NE to NW producing normal faulting, reactivating older structures and allowing dike intrusion. The extensional phase continued to be active throughout the Oligocene. The age of the volcanic event and a new K–Ar age of the Veta Madre vein of 29.8 ± 0.8 Ma (K–Ar in adularia) indicate that the hydrothermal event began immediately after the emplacement of the Cedro Formation. The emplacement of the Chichíndaro Rhyolite allowed hydrothermal activity to be active for two million years or more.     

相山铀矿田与斯特列利措夫铀矿田特征对比

相山铀矿田和斯特列利措夫铀矿田均产于破火山口中,相山火山盆地的基底为震旦系变质岩,斯特列利措夫盆地的基底为多期活化的片麻状花岗岩。两盆地的破火山口盖层均为陆相火山岩系,相山破火山口火山岩系为酸性和中酸性岩,斯特列利措夫破火山口火山岩系则为酸性和基性火山岩呈互层产出。破火山口内的构造和蚀变作用发育程度存在明显差异,这是两个铀矿田成矿远景不同的主要原因。     

Identification of the source caldera for the Middle Miocene ash-flow tuffs in the Kii Peninsula based on apatite trace-element composition

A large caldera cluster consisting of at least four calderas (Omine, Odai, Kumano-North and Kumano calderas) existed in the central–southern part of the Kii Peninsula approximately 14–15 Ma. On the other hand, thick Middle Miocene ash-flow tuffs, referred to as the Muro Ash-flow Tuff and the Sekibutsu Tuff Member, are distributed in the northern part of the Kii Peninsula. Although these tuffs are considered to have erupted from the caldera cluster in the central-southern Kii Peninsula, identifying the source caldera in the cluster has been controversial because of similarities in the petrological characteristics and identical radiometric ages of the volcaniclastic rocks of these calderas. We successfully discriminated the characteristics of the eruptive products of each caldera in the caldera cluster based on the apatite trace-element compositions of the pyroclastic dikes and ash-flow tuffs of the calderas. We also demonstrated that the source caldera of at least the lower main part of the Muro Ash-flow Tuff and the Sekibutsu Tuff Member was the Odai Caldera, which is located in the central Kii Peninsula. Our findings show possible correlations among the pyroclastic conduits and ash-flow tuffs of the caldera-fill and/or outflow deposits, even in cases where they have been densely welded and diagenetically altered. This method is useful for the study of deeply eroded ancient calderas.     

High CO2 Levels in Boreholes at El Teide Volcano Complex (Tenerife, Canary Islands): Implications for Volcanic Activity Monitoring

Emissions of CO₂ have been known for more than a hundred years as fumarolic activity at the terminal crater of El Teide volcano and as diffuse emissions at numerous water prospection drillings in the volcanic island of Tenerife. Large concentrations of CO₂ (>10% in volume) have been found inside galleries, long horizontal tunnels excavated for water mining. However, CO₂ concentrations of only 2900 ppm have been observed at the surface of the central region of the island (Las Cañadas del Teide caldera). In this work we analysed CO₂ concentrations in the subsurface of Las Cañadas caldera, in an attempt to study the vertical distribution of carbon dioxide and, in particular, the low emissions at the surface. This has been done through a series of 17 vertical profiles in two deep boreholes excavated in the Caldera. We found high levels of CO₂, varying in time from 13 vol% up to 40 vol% in different profiles directly above the water table, while no significant concentrations were detected above the thermal inversion that takes places in both boreholes at approximately 100 m from the water table. Water analyses also showed high dissolved CO₂ levels in equilibrium with the air, and an average 13C value in DIC of +4.7 (PDB), apparently induced by fast CO₂ degassing in the bicarbonated water.     

Petrological variation of large-volume felsic magmas from Hakkoda-Towada caldera cluster: Implications for the origin of high-K felsic magmas in the Northeast Japan Arc

Abstract The Hakkoda‐Towada caldera cluster (HTCC) is a typical Late Cenozoic caldera cluster located in the northern part of the Northeast Japan Arc. The HTCC consists of five caldera volcanoes, active between 3.5 Ma and present time. The felsic magmas can be classified into high‐K (HK‐) type and medium‐ to low‐K (MLK‐) type based on their whole‐rock chemistry. The HK‐type magmas are characterized by higher K₂O and Rb contents and higher ⁸⁷Sr/⁸⁶Sr ratios than MLK‐type magmas. Both magmas cannot be derived from fractional crystallization of any basaltic magma in the HTCC. Assimilation‐fractional crystallization model calculations show that crustal assimilation is necessary for producing the felsic magmas, and HK‐type magmas are produced by higher degree of crustal assimilation with fractional crystallization than MLK‐type magmas. Although MLK‐type magmas were erupted throughout HTCC activity, HK‐type magmas were erupted only during the initial stage. The temporal variations of magma types suggest the large contribution of crustal components in the initial stage. A major volcanic hiatus of 3 my before the HTCC activity suggests a relatively cold crust in the initial stage. The cold crust probably promoted crustal assimilation and fractional crystallization, and caused the initial generation of HK‐type magmas. Subsequently, the repeated supply of mantle‐derived magmas raised temperature in the crust and formed relatively stable magma pathways. Such a later system produced MLK‐type magmas with lesser crustal components. The MLK‐type magmas are common and HK‐type magmas are exceptional during the Pliocene–Quaternary volcanism in the Northeast Japan Arc. This fact suggests that exceptional conditions are necessary for the production of HK‐type magmas. A relatively cold crust caused by a long volcanic hiatus (several million years) is considered as one of the probable conditions. Intensive crustal assimilation and fractional crystallization promoted by the cold crust may be necessary for the generation of highly evolved HK‐type felsic magmas.     

Acid-sulphate Type Alteration and Mineralization in the Desmos Caldera, Manus Back-arc Basin, Papua New Guinea

Abstract: The Onsen acid‐sulphate type of mineralization is located in the Desmos caldera, Manus back‐arc basin. Hydrothermal precipitates, fresh and altered basaltic andesite collected from the Desmos caldera were studied to determine mineralization and mobility of elements under seawater dominated condition of hydrothermal alteration. The mineralization is characterized by three stages of advanced argillic alteration. Alteration stage I is characterized by coarse subhedral pyrophyllite with disseminated anhedral pyrite and enargite which were formed in the temperature range of 260–340°C. Alteration stage II which overprinted alteration stage I was formed in the temperature range of 270–310°C and is characterized by euhedral pyrite, quartz, natroalunite, cristobalite and mixed layer minerals of smectite and mica with 14–15 Å XRD peak. Alteration stage III is characterized by amorphous silica, native sulphur, covellite, marcasite and euhedral pyrite, which has overprinted alteration stages I and II. Relative to the fresh basaltic andesite samples, the rims and cores of the partly altered basaltic andesite samples have very low major, minor and rare earth elements content except for SiO₂ which is much higher (58–78 wt%) than SiO₂ content of the fresh basaltic andesite (55 wt%). REE patterns of the partly altered basaltic andesite specimens are variably depleted in LREE and have pronounced negative Eu anomalies. Normalization of major, minor and REE content of the partly altered basaltic andesites to the fresh basaltic andesite indicates that all the elements except for SiO2 in the partly altered basaltic andesite are strongly lost (e.g. Al₂O₃ = ‐8.3 to ‐10.9 g/100cm³, Ba = ‐2.2 to ‐5.6 mg/100cm³, La = ‐130 to ‐200 μg/100cm³) during the alteration process. Abnormal depletion of MgO, total Fe as Fe₂O₃, LREE especially Eu and enrichment of SiO₂ in the altered basaltic andesites from the Desmos caldera seafloor is caused by interaction of hot acidic hydrothermal fluid, which originates from a mixing of magmatic fluid and seawater.     

Tomographic imaging of seismic velocity structure in and around the Onikobe volcanic area, northeastern Japan: implications for fluid distribution

We estimated three-dimensional P- (V_p) and S-wave velocity (V_s) and V_p/V_s structures in and around the Onikobe volcanic area, northeastern Japan, by local travel time tomography. We used travel time data from source and receiver pairs located within and outside the study area, which plays an important role in obtaining the optimum ray coverage and in elucidating the deeper structure more accurately. Detailed information on deeper structures is essential for imaging the complete volcanic system from the magmatic source zone through areas of shallow hydrothermal circulation. More than 50 000 travel time data for the P-waves and 35 000 for the S-waves were used to image the velocity structure. Our results show the following dominant features: (1) two conduits in the upper crust with low V_p and low V_s indicative of H₂O-rich fluid pathways: one lying beneath Naruko volcano, the other beneath the focal area of the 1962 Northern Miyagi earthquake (M6.5); (2) an underlying broad region in the lower crust with low V_p, low V_s and high V_p/V_s, suggestive of a zone of partial melt, from which the fluids in (1) are derived; and (3) low V_p/V_s areas near the surface of the Sanzugawa and Onikobe calderas, suggesting a diffuse vapor-saturated cap.