Rock–water interactions and pollution processes in the volcanic aquifer system of Guadalajara,Mexico, using inverse geochemical modeling

In order to understand and mitigate the deterioration of water quality in the aquifer system underlying Guadalajara metropolitan area, an investigation was performed developing geochemical evolution models for assessment of groundwater chemical processes. The models helped not only to conceptualize the groundwater geochemistry, but also to evaluate the relative influence of anthropogenic inputs and natural sources of salinity to the groundwater. Mixing processes, ion exchange, water–rock–water interactions and nitrate pollution and denitrification were identified and confirmed using mass-balance models constraint by information on hydrogeology, groundwater chemistry, lithology and stability of geochemical phases. The water–rock interactions in the volcanic setting produced a dominant NaHCO₃ water type, followed by NaMgCaHCO₃ and NaCaHCO₃. For geochemical evolution modeling, flow sections were selected representing recharge and non-recharge processes and a variety of mixing conditions. Recharge processes are dominated by dissolution of soil CO₂ gas, calcite, gypsum, albite and biotite, and Ca/Na exchange. Non-recharge processes show that the production of carbonic acid and Ca/Na exchange are decreasing, while other minerals such as halite and amorphous SiO₂ are precipitated. The origin of nitrate pollution in groundwater are fertilizers in rural plots and wastewater and waste disposal in the urban area. This investigation may help water authorities to adequately address and manage groundwater contamination.     

松辽盆地北部徐家围子断陷营城组大型破火山口的发现

破火山口的形成是火山物质喷发量最大、破坏力最强的一种火山作用现象,因此,探寻破火山口存在的证据是明晰松辽盆地北部徐家围子断陷下白垩统营城组火山喷发规律和叠置关系的关键。徐家围子断陷营城组地层中徐东破火山口呈一个长轴约17km,短轴约10km的椭圆形、塌陷深度近3km的大型破火山口,其天窗式塌陷是下方岩浆房的不对称形态或岩浆房的不对称抽空导致。徐东破火山口内被厚层流纹质凝灰岩和熔岩填充,剖面上显示一对发育完整的正、逆断层,指示徐东破火山口经历了完整的沉降、塌陷、火山喷发过程。徐东破火山口形成于大陆裂谷背景下,是岩石圈减薄,大规模岩浆作用的产物。受区域NNW向构造格架控制,形成破火山口南北延伸的椭圆形态。     

Structural pattern of the western Las Cañadas caldera (Tenerife, Canary Islands) revealed by audiomagnetotellurics

The local and regional structural pattern of volcanic edifices strongly controls the space distribution of electrical resistivity. Here we report on the structural context of the western part of the Las Cañadas caldera of Tenerife (LCC) thought to have initiated the formation of the caldera. Using a new dataset of 11 audiomagnetotelluric tensors we emphasize the resistivity distribution of Ucanca caldera and propose a major revision of its extension. We find that Ucanca caldera has a limited westwards extent and that El Cedro sector is a depression margin of the caldera. According to the extent of hydrothermalized rocks at the base of the LCC wall and the distribution of Pico Teide – Pico Viejo vents, we constrain the location and size of Ucanca caldera. The interpretation of these results also constrains the extension of the Icod Valley and proposes a headwall located below the Pico Teide – Pico Viejo Complex.     

Volcanic geology of Admiralty Bay,King George Island,Antarctica

At Admiralty Bay of central King George Island, Keller Peninsula, Ull-man Spur and Point Hennequin are main Tertiary volcanic terranes. Field investigation and isotopic datings indicate that, there occurred three periods of eruptions ( three volcanic cycles) and accompanying N-toward migration of the volcanic center on Keller Peninsula. After the second period of eruptions, the crater collapsed and a cal-dera was formed, then later eruptions were limited at the northern end of the peninsula and finally migrated to Ullman Spur. Thus Keller Peninsula is a revived caldera, and its volcanism migrated toward E with time. Point Hennequin volcanism happened more or less simultaneously with the above two areas, but has no clear relation in chemical evolution with them, frequently it belongs to another independent volcanic center.     

The Luingo caldera: The south-easternmost collapse caldera in the Altiplano–Puna plateau,NW Argentina

This article identifies the Pucarilla–Cerro Tipillas Volcanic Complex and its major eruptive source, the Luingo caldera (26° 10′S–66° 40′W). Detailed geological mapping, stratigraphic sections, facies analysis and correlations, including the identification of typical caldera components, allow us to infer the position of a collapse caldera, elongated at N65° and with a diameter of 19 km × 13 km, which is responsible for an eruption of 135 km³ (DRE) of magma. The high-crystal contents of the associated ignimbrites, combined with its tectonic setting, indicate that regional and local tectonic structures played a crucial role in the formation of the caldera.     

Morphologic investigation of “uncharted” seamount from central Indian basin revisited with multibeam sonar system

Morphology of a seamount at 12°35'E and 76°18.5’ and two abyssal hills in its vicinity is described using the Hydrosweep multibeam‐swath bathymetric system. The height of the seamount is 1350 m, and it occupies an area of 330 km². Its basal width is 22.5 km, and the mount has a gentle and longer western flank and a steep and shorter eastern flank. There is a characteristic terracelike feature on the western flank, about 300 m from the top. A caldera is also observed on top of the seamount. Slope angles in this area are high (over 35"). Results of morphologic studies of the seamount from the multibeam survey are comparable to those from a narrow‐beam echosounding survey. The origin of the seamount may be related to the presence of a fracture zone at 75°45'E.     

Hazard assessment at volcanic fields: the Campi Flegrei case history

Volcanological analysis of the 10 000 yr –1538 explosive activity at Campi Flegrei shows that the most common explosive eruptions are characterized by the emplacement of flow or surge deposits, originating from the interaction between magma and shallow and/or sea water. The minimum volumes of pyroclastic products range between 0.04 and 0.7 km³; the proximal areas covered by these products range from 3–4 to 40–50 km². The pyroclastic flow and surge deposits occurring inside the caldera have been strongly controlled by pre-existent morphology; because of this, the area of present Napoli city was blanketed by approximately 5 m of pyroclastic deposits, during the last 5000 yr.Previous analysis suggests that the presence of even very low topographic obstacles may influence pyroclastic density current run out such that future eruptive deposits would mainly be confined inside the caldera rim. We suggest that a future eruption at Campi Flegrei would not seriously involve the urbanized area of Napoli city located on the hills. On the contrary, the plains located on the eastern side of the caldera (Fuorigrotta, Bagnoli) would be the most damaged area.     

Gas geochemistry of the Valles caldera region, New Mexico and comparisons with gases at Yellowstone, Long Valley and other geothermal systems

Noncondensible gases from hot springs, fumaroles, and deep wells within the Valles caldera geothermal system (210–300°C) consist of roughly 98.5 mol% CO₂, 0.5 mol% H₂S, and 1 mol% other components. ³He/⁴He ratios indicate a deep magmatic source (R/R_a up to 6) whereas δ¹³C–CO₂ values (−3 to −5‰) do not discriminate between a mantle/magmatic source and a source from subjacent, hydrothermally altered Paleozoic carbonate rocks. Regional gases from sites within a 50-km radius beyond Valles caldera are relatively enriched in CO₂ and He, but depleted in H₂S compared to Valles gases. Regional gases have R/R_a values ≤1.2 due to more interaction with the crust and/or less contribution from the mantle. Carbon sources for regional CO₂ are varied. During 1982–1998, repeat analyses of gases from intracaldera sites at Sulphur Springs showed relatively constant CH₄, H₂, and H₂S contents. The only exception was gas from Footbath Spring (1987–1993), which experienced increases in these three components during drilling and testing of scientific wells VC-2a and VC-2b. Present-day Valles gases contain substantially less N₂ than fluid inclusion gases trapped in deep, early-stage, post-caldera vein minerals. This suggests that the long-lived Valles hydrothermal system (ca. 1 Myr) has depleted subsurface Paleozoic sedimentary rocks of nitrogen. When compared with gases from many other geothermal systems, Valles caldera gases are relatively enriched in He but depleted in CH₄, N₂ and Ar. In this respect, Valles gases resemble end-member hydrothermal and magmatic gases discharged at hot spots (Galapagos, Kilauea, and Yellowstone).     

江西会昌密坑山锡多金属矿床与破火山口机构的形成和演化的关系

江西会昌密坑山中生代火山岩盆地是新近开发的重要锡多金属矿产区。本文首次确定本区为一发育完全的复活破火山口,在总结该区锡多金属矿化特征的基础上,通过资料分析,揭示出成矿作用与火山作用在时间、空间、物质来源等方面的内在联系,建立成矿模式,指明找矿方向,在理论和实践上具有一定意义。     

天姆尖破火山口碎斑熔岩的发现及其意义

赣杭带东段天姆尖地区首次识别出大面积分布的碎斑熔岩体系,它具有典型的喷溢相－侵出相一次火山岩相“三相一体”特征,在岩石化学成份上表现为富硅,碱,铁而贫镁,锰,钙,岩石结晶分异指数为77－93,稀土元素铕亏损明显,放射性成因铀铅含量高,岩石蚀变表现为面式分布,具前锋带特点,这一发现对赣杭带寻找新的富大铀矿远景区有着重要的指标意义。