Zircon LA-ICP MS U-Pb Age, Sr-Nd-Pb Isotopic Compositions and Geochemistry of the Triassic Post-collisional Wulong Adakitic Granodiorite in the South Qinling, Central China, and Its Petrogenesis

The Indosinian post-collisional Wulong pluton intruded into the Mesoproterozoic Fuping Group, South Qinling, central China. In the southern part of the pluton, some mafic enclaves have sharp or gradational contact relationships with the host biotite granodiorite. Geochemistry, zircon LA-ICP MS （laser ablation inductively-coupled plasma mass spectrometry） U-Pb chronology and Sr- Nd-Pb isotope geochemistry of the pluton are reported in this paper. The biotite granodiorite shows close compositional similarities to high-silica adakite. Its chondrite-normalized REE patterns are characterized by strong HREE depletion （Yb = 0.33--0.96 10-6 and Y = 4.77-11.19 ×10^-6）, enrichment of Ba （775-1386 x 10-6） and Sr （643-1115 × 10^-6） and high Sr/Y （57.83-159.99） and Y/Yb （10.99-14.32） ratios, as well as insignificant Eu anomalies （6Eu = 0.70-0.83）, suggesting a feldspar-poor, garnet±amphibole-rich residual mineral assemblage. The mafic enclaves have higher MgO （4.15- 8.13%）, Cr （14.79-371.31 × 10-6）, Ni （20.00-224.24× 10^-6） and Nb/Ta （15.42-21.91） than the host granodiorite, implying that they are mantle-derived and might represent underplated mafic magma. Zircon LA-ICP MS dating of the granodiorite yields a ^206pb/^238U weighted mean age of 208±2 Ma （MSWD=0.50, 1σ）, which is the age of emplacement of the host biotite granodiorite. This age indicates that the Wulong pluton formed during the late-orogenic or post-collisional stage （〈242±21 Ma） of the South Qinling belt. The host biotite granodiorite displays ^87Sr/^86Sr = 0.7059-0.7062, Isr = 0.7044-- 0.7050,^143Nd/^144Nd = 0.51236-0.51238, εNd（t）= -2.26 to -2.66 to ^206Pb/^204pb = 18.099-18.209, ^207pb/^204pb = 15.873-15.979 and ^208pb/^204pb = 38.973-39.430. Those ratios are similar to those of the Mesoproterozoic Yaolinghe Group in the South Qinling. Furthermore, its Nd isotopic model age （-1.02 Ga） is consistent with the age （-1.1 Ga） of the Yaolinghe Group. Based on the integrated geological and ge     

西南极菲尔德斯半岛第三纪钙碱性火山岩的生成与演化

西南极菲尔德斯半岛第三纪火山岩的岩石学和岩石化学特征表明,它们基本属于钙碱性火山岩系列,是岛弧火山作用的产物。该岩石组合中,随岩石中SiO_2含量的增加,斜长石斑晶数量减少,微量元素Cr、V丰度降低,Sr、Ba丰度下降,这些揭示了岩浆中斜长石和单斜辉石的分离结晶作用。稀土元素的系统变化也证明了这一点。主元素和微量元素的定量计算所验证了岩浆的分离结晶作用演化过程。     

缅甸中部抹谷早白垩世构造岩浆作用及对特提斯演化的启示

本文系统报道了缅甸抹谷变质带中部Yinmabin花岗闪长岩体及其基性岩墙的主量元素、微量元素及锆石U-Pb年龄和Lu-Hf同位素组成,重点讨论了花岗闪长岩和基性岩墙的岩石成因、物质来源及其地质意义。抹谷Yinmabin花岗闪长岩体主量元素显示富钠(N2O/K2O=1.5~1.75)、准铝(ACNK=0.94~0.97)和钙碱性岩石系列的地球化学特征。样品富集轻稀土(LREE)元素、大离子亲石元素(LILE),相对亏损高场强元素(HFSE)。岩体的主、微量元素地球化学特征均显示其具有活动陆缘I型花岗岩的地球化学属性。抹谷Yinmabin花岗闪长岩的锆石U-Pb年龄为131~135 Ma,其εHf(t)值在-15.66~-2.99之间,平均值为-8.77,单阶段模式年龄(tDM)为795~1569 Ma;而后期侵位的辉绿岩的锆石U-Pb年龄为120~118 Ma,其εHf(t)值在-13.72~+5.82之间,平均值为-2.72,单阶段模式年龄(tDM)为570~1341 Ma,表明这些岩石可能主要来源于古老下地壳部分熔融但同时也受到地幔物质的加入混染。与滇西以及北拉萨岩浆带的Lu-Hf同位素特征十分相近,暗示抹谷-毛淡棉地块早白垩世岩浆岩带与波密-察隅-高黎贡-拉萨岩浆岩带形成环境相似,可能是腾冲岩浆岩带向南延伸的一部分。结合岩石成因、源区性质和区域构造演化,认为抹谷花岗闪长岩体及基性岩墙的形成与中特提斯洋板块的俯冲作用密切相关,同时俯冲-碰撞转换的时限应该在120 Ma左右。这对于研究抹谷地体在中生代期间中特提斯洋俯冲碰撞过程具有重要的地质意义。     

内蒙古科尔沁右翼中旗敖兰三队侵入体年龄及地球化学特征

内蒙古科尔沁右翼中旗敖兰三队侵入体的同位素年代学及岩石地球化学研究表明,敖兰三队侵入体巨晶正长花岗岩具有低Sr、高Yb型花岗岩特征,其LA-ICP-MS锆石~(206)Pb/~(238)U年龄加权平均值为220±1Ma,表明该侵入体是晚三叠世早期侵位形成的。岩石高硅、富碱、高铁镁比、贫钙、贫镁和低钛;稀土元素配分曲线呈现"海鸥式"分布特征,显示强烈的Eu负异常。微量元素特征显示较低的Sr、Ba含量,较高的Yb、Zr和Y含量,在微量元素原始地幔标准化蛛网图上显示明显的Sr、Ba和Ti的负异常。岩石具有高的Rb/Sr和Rb/Nb,显示出壳源岩浆的成分特征。综合分析表明,本区巨晶正长花岗岩为低压下地壳部分熔融的产物。根据(Y+Nb)-Rb、(Yb+Ta)-Rb、Nb-Y-Ce三角图解,并结合区域构造演化,认为巨晶正长花岗岩形成于造山后伸展的构造环境。在中—晚三叠世,内蒙古科尔沁右翼中旗地区构造体制经历了重要的转变,由挤压体制转变为造山后软流圈上涌、岩石圈减薄。     

The Cretaceous Ofuku Pluton and Its Relation to Mineralization in the Western Akiyoshi Plateau,Yamaguchi Prefecture,Japan

The relationship between the magmatism of the Cretaceous Ofuku pluton and mineralization in and around the Akiyoshi Plateau, Yamaguchi Prefecture, Japan was investigated using a combination of field observation, petrographic and geochemical analyses, K–Ar geochronology, and fluid inclusion data. The Ofuku pluton has a surface area of 1.5 × 1.0 km, and was intruded into the Paleozoic accretionary complexes of the Akiyoshi Limestone, Ota Group and Tsunemori Formation in the western part of the Akiyoshi Plateau. The pluton belongs to the ilmenite‐series and is zoned, consisting mainly of early tonalite and granodiorite that share a gradational contact, and later granite and aplite that intruded the tonalite and granodiorite. Harker diagrams show that the Ofuku pluton has intermediate to silicic compositions ranging from 60.4 to 77.9 wt.% SiO₂, but a compositional gap exists between 70.5 to 73.4 wt.% SiO₂ (anhydrous basis). Modal and chemical variations indicate that the assumed parental magma is tonalitic. Quantitative models of fractional crystallization based on mass balance calculations and the Rayleigh fractionation model using major and trace element data for all crystalline phases indicate that magmatic fractionation was controlled mainly by crystal fractionation of plagioclase, hornblende, clinopyroxene and orthopyroxene at the early stage, and quartz, plagioclase, biotite, hornblende, apatite, ilmenite and zircon at the later stage. The residual melt extracted from the granodiorite mush was subsequently intruded into the northern and western parts of the Ofuku pluton as melt lens to form the granite and aplite. The age of the pluton was estimated at 99–97 Ma and 101–98 Ma based on K–Ar dating of hornblende and biotite, respectively. Both ages are consistent within analytical error, indicating that the Ofuku pluton and the associated Yamato mine belong to the Tungsten Province of the San‐yo Belt, which is genetically related to the ilmenite‐series granitoids of the Kanmon to Shunan stages. The aplite contains Cl‐rich apatite and REE‐rich monazite‐(Ce), allanite‐(Ce), xenotime and bastnäsite‐(Ce), indicating that the residual melt was rich in halogens and REEs. The tonalite–granodiorite of the Ofuku pluton contains many three‐phase fluid inclusions, along with daughter minerals such as NaCl and KCl, and vapor/liquid (V/L) volume ratios range from 0.2 to 0.9, suggesting that the fluid was boiling. In contrast, the granite and aplite contain low salinity two‐phase inclusions with low V/L ratios. The granodiorite occupies a large part of the pluton, and the inclusions with various V/L ratios with chloride daughter minerals suggest the boiling fluids might be related to the mineralization. This fluid could have carried base metals such as Cu and Zn, forming Cu ore deposits in and around the Ofuku pluton. The occurrence and composition of fluid inclusions in the igneous rocks from the Akiyoshi Plateau are directly linked to Cu mineralization in the area, demonstrating that fluid inclusions are useful indicators of mineralization.     

U – Pb zircon ages from leucogneiss in the Etheridge Group and their significance for the early history of the Georgetown region,north Queensland

The Timbarra Tablelands pluton is an extensive (～550 km²) complexly zoned intrusion forming one of many predominantly monzogranite I‐type plutons, which constitute the Moonbi Supersuite in northern New South Wales, Australia. It comprises an outer rim of Rocky River monzogranite (Zones 1–3), an intermediate zone of Sandy Creek syenogranite (Zones 4A–4C), surrounding a core of Surface Hill syenogranite (Zones 5–7). The suite is calc‐alkaline, high‐K, and varies from mildly metaluminous to weakly peraluminous with increasing fractionation. Average Rb/Sr ratios range from 0.4 in the least evolved very coarse‐grained monzogranite (Zone 3) to 46 in the most evolved very fine‐grained biotite microgranite (Zone 6). Trace‐element modelling indicates that the observed compositional variation could have been produced by crystal fractionation. New bulk rock major‐ and trace‐element data for 71 samples are presented, and indicate that a compositional continuum exists that varies between 63 and 78 wt% SiO₂. Importantly, there is no systematic chemical variation with spatial distribution of samples from the core of the pluton to its margin, requiring multiple separate pulses of an evolving magma to explain compositional discontinuities. The pluton is interpreted to have been emplaced at mesozonal levels (～180 ± 60 MPa, 5–10 km depth) and crystallised at temperatures between 620 and 820°C under moderately oxidising conditions (log fO₂ = ‐11.5 to ‐19). The association of gold‐molybdenite mineralisation at Timbarra with moderately oxidised I‐type magmas is consistent with fractionation‐redox controls on ore‐element behaviour in magmatic systems in other studies.     

安徽青阳—九华山复式岩体的成因及成矿潜力——来自锆石Hf同位素和微量元素的证据

青阳—九华山复式岩体是安徽南部地区出露面积最大、最具代表性的复式岩体,该复式岩体的岩浆源区、演化过程和成矿联系等问题仍需要进一步查明。在前期对青阳—九华山复式岩体的地质、地球化学特征研究基础上,本文进一步开展了锆石微量元素与Hf同位素分析与研究。结果显示,青阳—九华山复式岩体4个阶段从早到晚（花岗闪长岩二长花岗岩正长花岗岩细粒花岗斑岩）,晚期(第三、第四阶段)比早期(第一、第二阶段)岩浆岩的锆石εHf（t）值呈显著增高趋势,岩浆形成温度升高（705.3℃ 715.9℃ 827.1℃ 805.5℃）,氧逸度降低（93.8 149.170.1 69.9）。进一步分析认为,青阳—九华山复式岩体源于同一具有壳幔混源的岩浆源区,随着时间的演化,岩浆房中幔源组分比例逐渐增高,幔源物质的加入,不仅提高了晚期岩浆形成温度,一定程度改变了源区组成。青阳—九华山复式岩体4个阶段花岗岩均经历了榍石、角闪石、金红石、斜长石等矿物的分离结晶,晚期（第三、第四阶段）花岗岩相比早期（第一、第二阶段）花岗岩具有更高的分异程度。青阳—九华山复式岩体中第一、第二阶段花岗岩具有较好的W—多金属矿床成矿潜力。     

辽东凤凰山正长花岗岩SHRIMP U-Pb年龄、地球化学特征与陆内伸展作用

【研究目的】 辽宁丹东地区发育着一期A型花岗岩,因其特殊的成因演化,特定的构造背景及其重要的地球动力学意义而备受关注。【研究方法】 本文通过对辽宁丹东凤凰山岩体SHRIMP锆石U-Pb年代学、岩石地球化学特征的分析,探讨了该岩体形成时代、岩石成因及地球动力学背景。【研究结果】 辽东凤凰山黑云母正长花岗岩锆石U-Pb年龄分别为（122.3±1.7）Ma、（125.0±1.7）Ma、 （122±2）Ma,代表岩浆结晶年龄,凤凰山正长花岗岩侵位时代属于早白垩世。地球化学分析结果显示,SiO₂含量为65.65%～73.62%,K₂O为3.52%～5.76%,Na₂O为3.64%～4.26%,Al₂O₃为13.4%～15.49%,A/CNK值1.02～1.46,属铝过饱和型。碱度率AR在2.71～5.13,基本在铝质A型花岗岩AR值范围内,FeO_t/MgO比值为4.69～18.05,表现为A型花岗岩的A1和A2过渡类型。Rb/Nb比值为6.02～8.64,明显高于大陆壳的Rb/Nb比值2.2～4.7,说明陆壳物质对岩体成岩影响较大,从而导致Rb的含量增加。相对富集大离子亲石元素Rb、Th, Zr、Hf,亏损Sr、P、Ba、Ti、Nb。稀土总量较高,轻重稀土之间的分馏不明显,Eu具明显的负异常。【结论】 综上,凤凰山正长花岗岩可能产生于陆内剪切相关的伸展环境,应为自中侏罗世开始由板块俯冲引起的东亚大陆边缘构造过程的响应。     

湖南彭公庙岩体地球化学特征、时代及钨锡成矿潜力

南岭成矿带加里东期大花岗岩基的钨锡成矿潜力是近年来地质学家关注的热点。本文以湖南省彭公庙岩体为研究对象,精确厘定了产于彭公庙岩体内部的石牛仙钨矿的形成时代,同时厘定了彭公庙岩体中粗粒黑云母花岗闪长岩形成时代,分析了其地球化学特征,并与典型的成钨锡矿花岗岩进行对比,以此评估其钨锡成矿潜力。黑云母花岗闪长岩LA-ICP-MS锆石和独居石U-Pb年龄分别为436.1±2.5 Ma(MSWD=1.9,n=19)和436.8±2.8 Ma(MSWD=2.7,n=20),指示其侵位于早志留世。石牛仙钨矿床白云母³⁹Ar/⁴⁰Ar同位素坪年龄为150.2±1.2 Ma(MSWD=0.42),成矿时代与彭公庙成岩时代明显不同。彭公庙岩体分异程度不高,成矿元素W和Sn含量低,主要来源于上地壳贫粘土的变质砂岩,与南岭典型的成钨、成锡花岗岩分异程度高、成矿元素含量高、来源于富粘土的上地壳物质部分熔融区别明显,说明其成矿潜力有限。最后,在综合前人研究成果的基础之上,指出应综合地球物理、地球化学、构造蚀变信息等资料,重点评价彭公庙岩体内部及周缘晚期晚侏罗世花岗岩岩脉或...     

大别山地区鸡公山岩体锆石U-Pb年龄、Sr-Nd-Hf同位素特征及其地质意义

鸡公山花岗岩是桐柏-大别山造山带的一处重要岩基。为探讨鸡公山花岗岩的岩石成因和动力学背景,指导区域找矿,对鸡公山岩体开展了锆石U-Pb定年、岩石地球化学和Sr-Nd-Hf同位素研究。岩石地球化学分析结果显示,岩体具准铝质-弱过铝质花岗岩特征,属于高钾钙碱性系列;副矿物有少量角闪石,为分异I型花岗岩。锆石U-Pb定年测得岩体年龄值为141.8±0.8 Ma(n=26, MSWD=1.15),表明鸡公山岩体形成于早白垩世。全岩Sr同位素(⁸⁷Sr/⁸⁶Sr)_i为0.707 75～0.708 18,εNd(t)值为-19.21～ -17.63,两阶段模式年龄为2.49~2.36 Ga。锆石¹⁷⁶Hf/¹⁷⁷Hf值为0.281 845～0.282 083,εHf(t)为-29.67～-21.31,两阶段模式年龄为3.07～2.54 Ga。Sr-Nd-Hf同位素特征暗示形成鸡公山岩体的岩浆可能是扬子板块中下地壳新太古代大别表壳岩物质重熔形成。岩体具较高的(La/Yb)_N、Sr/Y值,铕负异常不明显,与大别山埃达克型花岗岩特征类似,形成于构造伸展机制下,为尚未发生拆沉的加厚下地壳部分熔融产物。鸡公山岩体可能是岩体内伟晶岩脉的母体花岗岩。