祖母绿产地鉴别研究综述

祖母绿是一种名贵彩色宝石,其产地来源对祖母绿价值的评定具有重要影响。祖母绿的产地鉴别因而成为宝石实验室的重要技术,也是宝石学领域的研究热点。祖母绿的包裹体、谱学特征和化学成分是常用且关键的产地鉴别信息,但随着祖母绿产地研究数据的积累,传统的产地鉴别方法备受挑战。文章系统整理和归纳分析了全球各产地祖母绿的宝石学特征、包裹体信息、谱学特征和主微量成分数据,在综述前人研究结果的基础上,系统阐明了目前祖母绿产地鉴别的研究现状,总结了不同产地祖母绿的宝石学特征和包裹体特征,划分了紫外-可见光-近红外(UV-VIS-NIR)光谱类型,揭示了各产地祖母绿的成分指纹信息,并以案例的形式阐明区分祖母绿常见重要产地的方法。全球尺度的对比虽然表明不同产地祖母绿包裹体种类多数雷同、光谱趋同、成分含量范围重叠明显,但也从包裹体出现频率、UV-VIS-NIR光谱样式类型、重水吸收样式和成分投图参数的选择上提供了产地鉴别的新思路。综上所述,文章旨在促进祖母绿鉴别技术的发展,为祖母绿的产地溯源提供科学依据。     

The Central Scandinavian Dolerite Group—Protracted hotspot activity or back-arc magmatism?: Constraints from U–Pb baddeleyite geochronology and Hf isotopic data

The Central Scandinavian Dolerite Group (CSDG) occurs in five separate complexes in central Sweden and SW Finland. U–Pb baddeleyite ages of dolerite dikes and sills fall into three age intervals: 1264–1271 (the Dalarna complex), 1256–1259 (the Västerbotten-Ulvö-Satakunta complexes) and 1247 Ma (the Jämtland complex). Timing and spatial distribution of CSDG are unlike expressions of the voluminous and short-lived magmatism which characterises plume-associated large igneous provinces (LIPs). Protracted mafic magmatism in association with mantle plume tail (hotspot) activity beneath the Fennoscandian lithosphere or discrete events of extension behind an active margin (subduction) are considered more plausible tectonic settings. Both settings are consistent with timing, relative magma volumes between complexes and vertical ascent of individual magma pulses through the crust, as inferred from seismic sections [Korja, A., Heikkinen, P., Aaro, S., 2001. Crustal structure of the northern Baltic Sea palaeorift. Teconophysics 331, 341–358]. In the hotspot model, the lack of a linear track of intrusions can be explained by an almost stationary position of Fennoscandia relative to the hotspot, in agreement with palaeomagnetic data [Elming, S.-Å., Mattsson, H., 2001. Post Jotnian basic intrusion in the Fennoscandian Shield, and the break up of Baltica from Laurentia: a palaeomagnetic and AMS study. Precambrian Res. 108, 215–236]). Together with geological evidence, dolerite sill complexes and dike swarms in Labrador (Canada), S Greenland and central Scandinavia in the range 1234–1284 Ma are best explained by long-lived subduction along a continuous Laurentia-Baltica margin preceding Rodinia formation. There is no support for the hypothesis that CSDG was fed by magma derived from a distal mantle plume located between Baltica and Greenland and, hence, for rifting between the cratons at 1.26 Ga.The epsilon-Hf in various members of the CSDG varies between 4.7 and 10.3, which are overall higher than both older and younger Mesoproterozoic mafic intrusions in central Fennoscandia. Magma generated from a hotspot mantle source that was mixed to highly variable degrees with an enriched subcontinental lithospheric mantle could account for the wide range in Hf isotope composition. In the course of Hf isotope development work during this project we have analysed four fragments of the Geostandard 91500 reference zircon and after evaluating the existing ICPMS and TIMS data we calculate a mean ¹⁷⁶Hf/¹⁷⁷Hf value of 0.282303 ± 0.000003 (2σ).     

地质标准物质的回顾与展望

我国地质物料化学成分标准物质的研究始于七十年代的后期.地矿部西北地质研究所等首先研制了超基性岩和铬铁矿标准物质,继后由物化探研究所和岩矿测试研究所牵头,在区域化探全国扫面的推动下,先后研制了水系沉积物、土壤和岩石三个系列标准物质.稍后核工业部、冶金部和化工部也着手研制了相应专业的地质标准物质.八十年代是地质标准物质研制的全盛时期,在这个阶段之后地质标准物质基本上形成了比较完整的体系.根据1992年国家技术监督局公布的国家一级标准物质目录^[1],在样品数量上冶金类标准物质居第一位,地质类标准物质居第二位,约占四分之一;依发布的标准值项目数计^[2],地质类标准物质居于首位,占50%以上.我国地质标准物质与外国相比,在数量、品种类型和系列性方面均占世界领先地位,在定值的元素和定值精度方面亦为国际先进水平.     

利用GNSS星间链路对中高轨航天器测定轨的可行性研究

目的 目前中高轨航天器精密轨道确定普遍采用地面跟踪测量体制,面临跟踪弧段不够、跟踪精度不高、无载体自主定位能力的问题。GNSS星间链路网络的建立为中高轨航天器定轨提供了新思路。介绍了基于GNSS星间链路的中高轨航天器定轨新方法,设计仿真模型分析了其可见性、定位精度、链路预算,并进行了自主定轨模拟计算。结果表明:以 GNSS星间链路实现中高轨航天器测定轨,可见星数目多、定位精度好、链路余量高,对中高轨航天器在径向的定轨精度可以达到6m 以内,切向和法向在2m 以内。本文测定轨方案可行,为GNSS在新领域的应用提供了思路。     

地质样品中金的测定方法研究

简介了近年来地质样品中金的分析测试方法,重点对地质样品金分析中的样品加工及分解、分离富集、测定方法等方面进行概述,并对我实验测试中心在相关方面工作进行了简单介绍.     

岩矿石标本真电参数的测试方法与测试系统(WXE)的研制

现有岩矿标本电参数的测试系统,所测的都是视电参数。本文研究了测试岩矿标本真电参数的方法。它通过测试系统隐含的本底电参数,将实测的视参数转换为真参数。据此,研制了新型岩矿标本真电参数测试系统( WXE)。     

泡沫塑料吸附测金中无臭灰化技术的改进

根据泡沫塑料(简称泡塑)吸附测金的无臭灰化技术的机理,作者采用了3ml圆底瓷坩埚灰化,解决了大批量佯品的灰化问题和电极装样困难的问题,并节省了灰化用的滤纸。     

Repeating aftershocks of the great 2004 Sumatra and 2005 Nias earthquakes

We investigate repeating aftershocks associated with the great 2004 Sumatra–Andaman (Mw 9.2) and 2005 Nias–Simeulue (Mw 8.6) earthquakes by cross-correlating waveforms recorded by the regional seismographic station PSI and teleseismic stations. We identify 10 and 18 correlated aftershock sequences associated with the great 2004 Sumatra and 2005 Nias earthquakes, respectively. The majority of the correlated aftershock sequences are located near the down-dip end of a large afterslip patch. We determine the precise relative locations of event pairs among these sequences and estimate the source rupture areas. The correlated event pairs identified are appropriately referred to as repeating aftershocks, in that the source rupture areas are comparable and significantly overlap within a sequence. We use the repeating aftershocks to estimate afterslip based on the slip-seismic moment scaling relationship and to infer the temporal decay rate of the recurrence interval. The estimated afterslip resembles that measured from the near-field geodetic data to the first order. The decay rate of repeating aftershocks as a function of lapse time t follows a power-law decay 1/t^p with the exponent p in the range 0.8–1.1. Both types of observations indicate that repeating aftershocks are governed by post-seismic afterslip.     

无载气氢化物发生－石英缝管捕集原子吸收光谱法测定地质试样中的铋

文章介绍石英缝管原子捕集技术在氢化物－火焰原子吸收光谱法测定Ｂｉ中的应用。采用自制的无载气氢化物发生装置，对实验条件进行了最佳化。实验结果表明，原子捕集技术的应用使氢化物－火焰原子吸收法的灵敏度提高２．２倍；方法检出限（３σ）达２．５ｎｇ；２０ｎｇ／ｍｌＢｉ的标准溶液１０次测定的ＲＳＤ为２．９％。方法用于地质标样中微量Ｂｉ的测定，结果与推荐值符合。