Experimental Investigation of the Upper Thermal Stability of Mg-rich Actinolite; Implications for Kiruna-Type Iron Deposits

The occurrence of actinolite in magnetite deposits of possiblemagmatic origin has prompted an experimental investigation ofthe upper thermal stability of Mg-rich actinolite to determinehow the stability of actinolite changes with increasing Fe content.Experiments were carried out primarily on the compositionalre-equilibration of natural tremolite [molar Fe/(Fe + Mg) =Fe-number = 0·014] in the presence of synthetic clinopyroxene(Ca_0·80Fe_0·67Mg_0·54Si_2·00O₆), syntheticpigeonite/orthopyroxene (Ca_0·08Fe_1·19Mg_0·70Si_2·02O₆),quartz, and water to a more Fe-rich actinolite over the rangeof 600–880°C, 1 and 4 kbar, at the Ni–NiO oxygenbuffer, for durations of 1–2 weeks. The bulk compositionof the mineral mixture is close to actinolite with Fe-number= 0·5. These experiments constitute a half-reversal ofthe amphibole composition, which, when approached from a Mg-richstarting composition, provides information on the minimum Fecontent of actinolite at a given temperature. Compositionalchanges were monitored by electron microprobe analysis of amphibolerim compositions and/or overgrowths on the original tremolite.At 4 kbar and 880–800°C, tremolite shows strong re-equilibrationwith overgrowths of an Fe-rich but low-Ca (1·7 > Ca> 1·4) actinolite; Fe-rich cummingtonite (Ca <0·7)begins to nucleate at 860°C. At 800–700°C, tremoliteshows weak compositional re-equilibration but strong nucleationof Fe-rich cummingtonite. Similar results were observed at 1kbar, with tremolite showing strong re-equilibration to low-Caactinolite at 790–600°C with cummingtonite nucleationat 800°C and below. The wide variation in Ca contents ofthe re-equilibrated amphiboles was unexpected. Additional univariantreversal experiments were carried out on the thermal decompositionof a natural actinolite (Fe-number = 0·22) from PleitoMelón, Chile, indicating the breakdown of actinoliteto clinopyroxene, orthopyroxene, quartz, and water at 780°Cand 1 kbar, and 850°C and 4 kbar. Considering only amphiboleswith Ca >1·7 a.p.f.u., the thermal stability of actinoliteis observed to decrease in a linear manner over the P–Trange investigated with a dT/dFe-number slope of –372°C/Fe-numberat 1 kbar and –546°C/Fe-number at 4 kbar. The highthermal stabilities (750–900°C) of actinolites withFe-numbers in the range of 0–0·4 overlap with therange of water-saturated melting for a typical andesite or tonalite.These conditions also overlap the field of experimental Fe–P-richmelt formation, suggesting that actinolite may have an igneousorigin in Kiruna-type ore deposits. KEY WORDS: actinolite; mineral stability; Kiruna deposits, thermodynamic values; cummingonite     

Postmaterialism and Support for the Environment in the United States

Postmaterialist theory suggests that under conditions of continuously expanding economic and personal security, younger generations will be less oriented to acquiring material goods and more committed than their older peers to attaining postmaterial social goals such as increased free self-expression and a healthy natural environment. Using the latest World Values Survey sample for the United States, ordinary least squares (OLS) and logit regressions are employed to test whether youth is a predictor of postmaterialism as theory suggests, and whether postmaterialism positively predicts environmental concern and individual actions in support of the environment. Age is found to be a negative and statistically significant factor in explaining variation in the postmaterialism index, and this index is in turn found to be a statistically significant positive factor in explaining individual environmental concern and activism. A combination of increased economic security and entrance of younger generations into adulthood could well matter for our environmental future.     

An extreme value analysis of the flow of Burbage Brook

An extreme value analysis of the flow of Burbage Brook is carried out by modelling peaks over a high threshold. The aims are to illustrate recently developed statistical techniques and to report on interesting features of the flow of the brook over a 58-year period. Peak flows are found to show marked seasonal variation and a downward trend. Then-year return level is estimated for various values ofn, and the reliability of the estimates is assessed.     

高温高压下元素配分的原位实验与计算模拟研究进展

地球内部元素的配分行为具有重要意义,有助于揭示地球内部物质循环、元素成矿、超临界流体性质等基础地质问题。同步辐射微聚焦X射线荧光光谱(SR-μXRF)结合金刚石压腔(DAC)技术,可以在高温高压条件下实现高准确度和高分辨率的原位(in situ)测试元素在不同物相间的浓度,并获取配分系数。而基于地球化学热力学的理论计算模拟,可以获得元素在不同物相间的赋存形式,有助于揭示元素配分机制。本文综述了SR-μXRF结合DAC技术和地球化学热力学计算模拟原位测定高温高压下元素配分的研究方法,及其在地球内部元素迁移、成矿作用和地球早期形成过程等领域中的应用进展,认为利用该套方法研究高温高压下元素配分行为的体系将变得更加复杂,对温度、压力条件则要求更高。本文旨在更新和丰富高温高压下元素配分系数数据,深化对地球内部物质循环等问题的认知。     

Beyond fisheries management: The Phronetic dimension

This paper has two main sources of inspiration. Firstly, building on Flyvbjerg's “Making Social Science Matter”[Flyvbjerg B. Making social science matter: why social inquiry fails and how it can succeed again. Cambridge: Cambridge University Press; 2003], I argue that the contribution of the social sciences to fisheries resource management must essentially be “phronetic” (after Aristotle's phronesis, i.e. practical wisdom), in contrast to the “scientific” (Aristotle: episteme) contribution of the natural sciences. Secondly, inspired by the recent publication “Fish for Life: Interactive Governance for Fisheries” [Kooiman J, Jentoft S, Pullin R, Bavinck M, editors. Fish for life: interactive governance for fisheries. Amsterdam: Amsterdam University Press; 2005], I hold that phronesis is basically what the notion of governance adds to management. Governance is the broader concept, inviting a more reflexive, deliberative and value-rational methodology than the instrumental, means-end oriented management concept. I claim that for interdisciplinarity to work in fisheries it is essential to recognize the fundamental methodological differences that exist between the social and natural sciences.     

Estimation of boundary values in a North Atlantic circulation model using an adjoint method

A 1° × 1° resolution version of the MIT-GCM in the North Atlantic is used to test whether open-boundary conditions can be constrained by observations inside the domain using an adjoint method. In this preliminary feasibility study, the model is run during 1993 with a simplified vertical mixing physics. It is constrained by monthly SST fields, monthly climatological θ, S fields and TOPEX/POSEIDON altimetry. The adjoint model is built using automatic differentiation software. The method aims at bringing the model’s trajectory to consistency with data, by adjusting the initial θ, S fields, the time-varying atmospheric forcing fields and the time-varying open-boundary values. An originality of the work is the ‘nested approach’, which uses optimized fields from a global, coarser resolution model for the open-boundary conditions and for the prior estimates of the surface conditions adjustments. A solution is obtained after 75 iterations. This study shows that significant changes can be obtained on the open-boundary values, and that a general improvement in the circulation is achieved in the constrained solution, mainly in the Gulf Stream and equatorial regions. Changes at the open boundaries are characterized by a large temporal variability and small spatial scales. Large local adjustments are found close to the bottom and are likely unrealistic. There, the method tends to compensate for some model’s deficiencies by computing large corrections on the open-boundary values. The analysis of the cost function gradients with respect to the controls allows us to explore the local consistency between the constraints from the different data sets. This study suggests that no fundamental difficulty emerges when constraining open-boundary values. Its extension to a longer run with complete mixing physics can be envisaged.     

Wave-height distributions and nonlinear effects

Theoretical distributions proposed for describing the crest-to-trough heights of linear waves are reviewed briefly. To explore the effects of nonlinearities, these are generalized to second-order waves, utilizing quasi-deterministic results on the expected shape of large waves. The efficacy of Gram–Charlier models in describing the effects of third-order nonlinearities on the distributions of wave heights, crests and troughs are examined in detail. All models and a fifth-order Stokes–Rayleigh type model recently proposed are compared with linear and nonlinear waves simulated from the JONSWAP spectrum representative of long-crested extreme seas, and also with oceanic data gathered in the North Sea. Uncertainties arising from the variability of probability estimates derived from sample populations of limited size are considered. Ultimately, the comparisons show that nonlinearities do not have any discernable effect on the crest-to-trough heights of oceanic waves. Most of the linear models considered yield similar and reasonable predictions of the observed data trends. Gram–Charlier type distributions seem neither effective nor particularly useful in describing the statistics of large wave heights or crests under oceanic conditions. However, they do surprisingly well in predicting unusually large wave heights and crests observed in some 2D wave-flume experiments and 3D numerical simulations of long-crested narrow-band random waves.     

‘It׳s part of me’; understanding the values,images and principles of coastal users and their influence on the social acceptability of MPAs

Improving the social acceptability or ‘social licence’ of Marine Protected Areas (MPAs) is a key challenge facing countries all around the world. As the world moves slowly towards the establishment of a global network of MPAs, it is increasingly apparent that a greater understanding of social responses to MPAs is required, given they are often met with resistance from local communities. A series of in-depth, semi structured interviews were conducted across coastal users in New South Wales, Australia, including surfers, recreational fishers, professional fishers, spearfishers, walkers, divers, snorkellers, kayakers and other community members. The research identified the values, images and principles at work amongst coastal users to determine the dominant ‘cultural models’ within the community and how these models influenced attitudes towards MPAs. This research indicates that traditional consultation models may not be sufficient to address the full spectrum of community needs, and in fact suggests the need to re-conceive the make -up of ‘the community’ itself. In the context of MPA planning ‘the community’ is not an amalgamation of a range of homogenous stakeholder groups but instead a diverse and complex mix of identities and value systems which are not confined to particular interest groups. Incorporating consideration of the diverse range of values, images and principles found within and across stakeholder groups will require new and innovative approaches to participation and management.     

An evaluation of remote sensing derived soil pH and average spring groundwater table for ecological assessments

Ecological assessments such as species distribution modelling and benchmarking site quality towards regulations often rely on full spatial coverage information of site factors such as soil acidity, moisture regime or nutrient availability. To determine if remote sensing (RS) is a viable alternative to traditional data sources of site factor estimates, we analysed the accuracy (using ground truth validation measurements) of traditional and RS sources of pH and mean spring groundwater level (MSL, in m) estimates. Traditional sources were a soil map and hydrological model. RS estimates were obtained using vegetation indicator values (IVs) from a Dutch national system as an intermediate between site factors and spectral response. IVs relate to those site factors that dictate vegetation occurrence, whilst also providing a robust link to canopy spectra. For pH, the soil map and the RS estimate were nearly as accurate. For MSL, the RS estimates were much closer to the observed groundwater levels than the hydrological model, but the error margin of the estimates still exceeded the tolerance range of moisture sensitive vegetation. The relatively high accuracy of the RS estimates was made possible by the availability of local calibration points and large environmental gradients in the study site. In addition, the error composition of the RS estimates could be analysed step-by-step, whereas the traditional sources had to be accepted ‘as-is’. Also considering that RS offers high spatial and temporal resolution at low costs, RS offered advantages over traditional sources. This will likely hold true for any other situation where prerequisites of accurate RS estimates have been met.