有机化学物质碳氮稳定同位素系列标准物质研制

实验室和研究人员所使用的碳、氮同位素标准物质一般由国际原子能机构(IAEA)获得,然而近年来,随着碳氮同位素在实验室质量监控、方法评价、仪器校准等方面的广泛应用,市场需求量不断增加, IAEA研制的碳、氮同位素标准物质的种类与数量逐渐不能满足科学研究快速发展的需求。我国急需研制适应当今分析技术水平的有机质碳氮同位素国家标准物质用以进行质量监控、方法评价、仪器校准。为保证量值传递精度,本文研制了4个有机化学物质的碳氮稳定同位素标准物质,其中3个为尿素样品,1个为L-谷氨酸。经检验4种标准物质的均匀性通过F值检验,标准物质的δ~(13)C和δ~(15)N值经过一年的稳定性检验,特征量值变化在测量方法允许的不确定度范围内,由此判定δ~(13)C和δ~(15)N值稳定性良好。由包括研制单位实验室在内的12家实验室协同定值,采用高温燃烧-气体同位素质谱法测定了δ~(13)C和δ~(15)N值,系列标准物质δ~(13)C和δ~(15)N认定值区间呈梯度分布,δ~(13)C值为-40‰～0‰,δ~(15)N值为-10‰～30‰,涵盖了我国天然样品中有机质碳氮稳定同位素组成范围;研制的系列标准物质δ~(13)C的定值扩展不确定度不大于0.08‰,δ~(15)N的定值扩展不确定度不大于0.09‰,定值水平与国际标准物质相当。该系列标准物质已被国家质检总局批准为国家一级标准物质,批准号为GBW04494～GBW04497。可被用于地质、生态、环境等多种样品δ~(13)C和δ~(15)N比值测定时的分析监控、仪器校准、方法评价、质量保证和质量监控。     

Main progress and prospect for China's hydrogeological survey

This paper reviewed the main achievements of hydrogeological survey in China, summarized the significant progress of hydrogeological survey over the past decade, and forecasted the key responsibilities for hydrogeological survey in the p14th Five-year Planq. The significant progress includes: China established the 1: 50 000 standard hydrogeological survey system with Chinese characteristics and produced the new generation of high-quality hydrogeological maps; the national groundwater monitoring project was completed and accepted, which marks China taking the leading position in groundwater monitoring internationally; fruitful results were achieved in the national groundwater quality survey, and groundwater quality background values were basically identified and checked; hydrogeological and environmental geological survey was continuously promoted in karst areas and the ecological restoration of rocky desertification achieved remarkable results; China strengthened layer exploration techniques for groundwater, integrating the key and practical techniques of layer exploration and monitoring; the exploration of groundwater in the poverty-stricken regions and old revolutionary base areas were effectively promoted to strongly guarantee the poverty alleviation and drinking water safety; the mystery of desert groundwater was uncovered, making up for the shortage of 1: 250 000 hydrogeological survey in the Badain Jaran Desert; and more efforts were made to conduct survey on the water resources in the basin, and to finish the unified measurement of national-scale groundwater level.     

利用限制性最大似然方法和贝叶斯方法估计大菱鲆生长性状的遗传参数。

Bayesian and restricted maximum likelihood(REML) approaches were used to estimate the genetic parameters in a cultured turbot Scophthalmus maximus stock. The data set consisted of harvest body weight from 2 462progenies(17 months old) from 28 families that were produced through artificial insemination using 39 parent fish. An animal model was applied to partition each weight value into a fixed effect, an additive genetic effect, and a residual effect. The average body weight of each family, which was measured at 110 days post-hatching, was considered as a covariate. For Bayesian analysis, heritability and breeding values were estimated using both the posterior mean and mode from the joint posterior conditional distribution. The results revealed that for additive genetic variance, the posterior mean estimate( δ_a~2=9 320) was highest but with the smallest residual variance,REML estimates( δ_a~2=8 088) came second and the posterior mode estimate( δ_a~2=7 849) was lowest. The corresponding three heritability estimates followed the same trend as additive genetic variance and they were all high. The Pearson correlations between each pair of the three estimates of breeding values were all high,particularly that between the posterior mean and REML estimates(0.996 9). These results reveal that the differences between Bayesian and REML methods in terms of estimation of heritability and breeding values were small. This study provides another feasible method of genetic parameter estimation in selective breeding programs of turbot.     

Robustness of the holistic seismic risk evaluation in urban centers using the USRi

The Urban Seismic Risk index (USRi) published in a previous article (Carreño et al., Nat Hazards 40:137–172, 2007) is a composite indicator that measures risk from an integrated perspective and guides decision-making for identifying the main interdisciplinary factors of vulnerability to be reduced or intervened. The first step of the method is the evaluation of the potential physical damage (hard approach) as a result of the convolution of the seismic hazard with the physical vulnerability of buildings and infrastructure. Subsequently, a set of social context conditions that aggravate the physical effects is also considered (soft approach). According to this procedure, the physical risk index is evaluated for each unit of analysis from existing loss scenarios, whereas the total risk index is obtained by multiplying the former index by an impact factor using an aggravating coefficient, based on variables associated with the socio-economic conditions of each unit of analysis. The USRi has been developed using the underlying holistic and multi-hazard approach of the Urban Risk Index framework proposed for the evaluation of disaster risk in different megacities worldwide. This article presents the sensitivity analysis of the index to different parameters such as input data, weights and transformation functions used for the scaling or normalization of variables. This analysis has been performed using the Monte Carlo simulation to validate the robustness of this composite indicator, understanding as robustness how the cities maintain the ranking as well as predefined risk level ranges, when compared with the deterministic results of risk. Results are shown for different cities of the world.     

Natural background levels and threshold values for groundwater in fluvial Pleistocene and Tertiary marine aquifers in Flanders,Belgium

Aquifers from the same typology can have strongly different groundwater chemistry. Deducing the groundwater quality of less well-characterized aquifers from well-documented aquifers belonging to the same typology should be done with great reserve, and can only be considered as a preliminary approach. In the EU’s 6th FP BRIDGE project “Background cRiteria for the IDentification of Groundwater thrEsholds”, a methodology for the derivation of threshold values (TV) for groundwater bodies is proposed. This methodology is tested on four aquifers in Flanders of the sand and gravel typology. The methodology works well for all but the Ledo-Paniselian aquifer, where the subdivision into a fresh and saline part is disproved, as a gradual natural transition from fresh to saline conditions in the aquifer is observed. The 90 percentile is proposed as natural background level (NBL) for the unconfined Pleistocene deposits, ascribing the outliers to possible influence of pollution. For the Tertiary aquifers, high values for different parameters have a natural origin and the 97.7 percentile is preferred as NBL. The methodology leads to high TVs for parameters presenting low NBL, when compared to the standard used as a reference. This would allow for substantial anthropogenic inputs of these parameters.     

复合桩基水泥土非线性应力-应变关系模型

在不同区域采集相关样品,根据不同水泥掺合比及护龄期不同,采用几种不同围压分别进行水泥土三轴压缩试验,通过试验结果得到应力一应变曲线,提出一个具有峰值后下降并趋于某定值性质的分段连续函数,并以该分段连续函数表示水泥土的力学模型。     

Food and energy in the diet of brown and rainbow trout from Lake Benmore,New Zealand

The diet of brown trout (Salmo trutta) and rainbow trout (S. gairdnerii) was studied in specimens from Lake Benmore, a deep, oligo‐trophic lake in South Island, New Zealand. Between November and July, both species fed mainly on small molluscs (Potamopyrgus antipodarum, Physa sp., and Gyraulus corinna) gleaned from the littoral weed beds. Energy values for the three species of mollusc were determined: P. antipodarum, 6000 J g^‐1; G. corinna, 5500 J g^‐1; Physa sp., 9800 J g^‐1. Potamopyrgus antipodarum yielded little energy to the fish, unless its shell broke during passage through the gut. Physa sp. was the most profitable mollusc, irrespective of shell breakage and Potamopyrgus antipodanim the least profitable. The mean energy value per snail for G. corinna and Physa sp. eaten by rainbow trout was 25–30% less than for snails eaten by brown trout, possibly because rainbow trout ingested empty shells from the sediment surface. Rainbow trout extracted about 20% more energy than brown trout from unbroken shells. In July, 84% of the brown trout switched to predation of common bullies, Gobio‐morphus cotidianus, probably as a result of bully reproductive behaviour. Rainbow trout did not show the same change, apparently because they were feeding in deeper water where few bullies were available. The low‐energy diet and its possible connection with growth rate are discussed.     

三峡工程水库重点监视区不同蓄水阶段地震波Q值分析

利用2001～2015年三峡数字遥测地震台网记录到的数字地震观测资料,结合三峡工程水库蓄水情况,采用Atkinson方法分析该地区的地震波衰减特征,得到不同蓄水阶段、不同库段的非弹性衰减结果。结果显示,Q值与频率变化的线性关系较好,各频点在拟合线附近波动;3个库段在不同蓄水阶段均具有较小的Q0值和中等的η值,表明三峡工程水库重点监视区构造复杂,且介质的均匀程度较低;仙女山-九畹溪断裂附近地区Q值较大,表明该地区构造运动比较稳定;巴东高桥断裂附近地区Q值较小,表明该地区构造运动比较强烈;泄滩地区随着水位的升高,Q0值增大,表明该地区介质均匀程度有所提高。     

亚纯函数微分多项式的一个正规定则

证明了下面两个定理：（1）设n,k≥2为正整数,a为有穷非零复数,F为区域D上的亚纯函数族,F中任一函数的零点重级至少为k．vf,g∈F,fLn（f）与gLn（g）IM分担a．则F在D上正规,其中L（f）为f（k）＋a1f^（k-1）＋…＋akf,这里a1,…,ak为常数．（2）设n,k为正整数,且n≥2,a为有穷非零复数,F为区域D上的亚纯函数族,F中任一函数的零点重级至少为k,且fLn（f（z））=a能够推出｜f^（k）（z）｜≤A,其中A为正数,则F在区域D上正规．     

CPI values of terrestrial higher plant-derived long-chain n-alkanes: a potential paleoclimatic proxy

Carbon Preference Index (CPI values) of higher plant-derived long-chain n-alkanes extracted from 62 surface soil samples in eastern China exhibited a specific pattern of variations, namely gradual increase with the increasing latitudes. Such regular variations existed in both forest soil and grassland soil. Our data implied that CPI values of higher plant-derived long-chain n-alkanes had a certain connection with climatic conditions, and such a connection was not influenced by vegetation types. Together with previous data from marine sediments, loess/paleosol sequences, tertiary red clay and modern plants, our observation made us conclude that CPI values of higher plant-derived long-chain n-alkanes may be used as an excellent proxy for paleoclimatic studies.