Mineral inclusions and geochemical characteristics of microdiamonds from the DO27, A154, A21, A418, DO18, DD17 and Ranch Lake kimberlites at Lac de Gras, Slave Craton, Canada

A mineral inclusion, carbon isotope, nitrogen content, nitrogen aggregation state and morphological study of 576 microdiamonds from the DO27, A154, A21, A418, DO18, DD17 and Ranch Lake kimberlites at Lac de Gras, Slave Craton, was conducted. Mineral inclusion data show the diamonds are largely eclogitic (64%), followed by peridotitic (25%) and ultradeep (11%). The paragenetic abundances are similar to macrodiamonds from the DO27 kimberlite (Davies, R.M., Griffin, W.L., O'Reilly, S.Y., 1999. Diamonds from the deep: pipe DO27, Slave craton, Canada. In: Gurney, J.J., Gurney, J.L., Pascoe, M.D., Richardson, S.H. (Eds.), The J. B. Dawson Vol., Proc. 7th Internat. Kimberlite Conf., Red Roof Designs, Cape Town, pp. 148–155) but differ to diamonds from nearby kimberlites at Ekati (e.g., Lithos (2004); Tappert, R., Stachel, T., Harris, J.W., Brey, G.P., 2004. Mineral Inclusions in Diamonds from the Panda Kimberlite, S. P., Canada. 8th International Kimberlite Conference, extended abstracts) and Snap Lake to the south (Dokl. Earth Sci. 380 (7) (2001) 806), that are dominated by peridotitic stones.

Eclogitic diamonds with variable inclusion compositions and temperatures of formation (1040–1300 °C) crystallised at variable lithospheric depths sometimes in changing chemical environments. A large range to very ¹³C-depleted C-isotope compositions (δ¹³C=−35.8‰ to −2.2‰) and an NMORB bulk composition, calculated from trace elements in garnet and clinopyroxene inclusions, are consistent with an origin from subducted oceanic crust and sediments. Carbon isotopes in the peridotitic diamonds have mantle compositions (δ¹³C mode −4.0‰). Mineral inclusion compositions are largely harzburgitic. Variable temperatures of formation (garnet T_Ni=800–1300 °C) suggest the peridotitic diamonds originate from the shallow ultra-depleted and deeper less depleted layers of the central Slave lithosphere. Carbon isotopes (δ¹³C av.=−5.1‰) and mineral inclusions in the ultradeep diamonds suggest they formed in peridotitic mantle (670 km). The diamonds may have been entrained in a plume and subcreted to the base of the central Slave lithosphere.

Poorly aggregated nitrogen (IaA without platelets) in a large number of eclogitic (67%) and peridotitic (32%) diamonds, with similar nitrogen contents, indicates the diamonds were stored in the mantle at low temperatures (1060–<1100 °C) following crystallisation in the Archean. Type IaA diamonds have largely cubo-octahedral growth forms, and Type II and Type IaAB diamonds, with higher nitrogen aggregation states, mostly have octahedral morphologies. However, no correlation between these groups and their mineral inclusion compositions, C-isotopes, and N-contents rules out the possibility of unique source origins and suggests eclogitic and peridotitic diamonds experienced variable mantle thermal states. Variation in mineral inclusion chemistries in single diamonds, possible overgrowths of ¹³C-depleted eclogitic diamond on diamonds with peridotitic and ultradeep inclusions, and Type I ultradeep diamond with low N-aggregation is consistent with diamond growth over time in changing chemical environments.     

华北克拉通南缘豫西下汤地区2.3 Ga岩浆作用和1.94 Ga变质作用

本文报道了华北克拉通南缘豫西鲁山下汤地区古元古代片麻状花岗岩和黑云角闪斜长片麻岩的全岩地球化学和锆石SHRIMP U-Pb年龄和Hf同位素组成。岩石呈包体形式存在于中元古代花岗岩中。片麻状花岗岩具深熔特征,岩浆锆石年龄为2.30Ga;岩石高SiO2和K2O,低ΣFeO、MgO和CaO,具稀土总量较高(ΣREE=165.8×10-6)、轻重稀土分离较强[(La/Yb)n=37.8]及弱负铕异常(Eu/Eu*=0.76)的稀土模式;εNd(t)(t=2.30Ga)=-0.75;tDM(Nd)=2.66Ga。黑云角闪斜长片麻岩变质原岩为辉长闪长岩,捕获锆石年龄为2.25Ga;岩石低SiO2和MgO,高Al2O3和P2O5,具稀土总量高(ΣREE=373.4×10-6)、轻重稀土分离不强[(La/Yb)n=9.4]及较强负铕异常(Eu/Eu*=0.44)的稀土模式;εNd(t)(t=2.25Ga)=-1.21;tDM(Nd)=2.75Ga。片麻状花岗岩和黑云角闪斜长片麻岩都记录了1.94Ga变质锆石年龄。片麻状花岗岩的岩浆锆石组成域的εHf(t)(t=2.30Ga)=-6.71～0.38,tDM1(Hf)=2627～2910Ma,tDM2(CC)(Hf)=2823～3255Ma。黑云角闪斜长片麻岩的捕获锆石组成域的εHf(t)(t=2.25Ga)=-19.58～-1.73,tDM1(Hf)=2664～3360Ma,tDM2(CC)(Hf)=2968～4011Ma。结合前人资料,得出如下结论:华北克拉通南缘豫陕晋结合部地区存在一规模较大的约2.3Ga地质体分布区;华北克拉通南缘很可能存在规模巨大的>2.7Ga基底;中部造山带与孔兹岩带具有类似的古元古代晚期构造热事件演化历史。     

华北克拉通的形成以及早期板块构造

地球上最早的地壳岩石是高钠的花岗质(TTG)岩石,但是否有更老的洋壳存在过、以及陆壳是怎样形成的,涉及到地球动力学几乎所有的问题。其中板块构造是在什么时候开始的,就是个延续了数十年热度不减的前沿科学问题。流行的说法是板块构造始于新元古代,也有一些学者认为在新太古代就已经开始,或者认为自从地球上有了水的记录,就开始有板块构造。在众多的判别板块构造的标志中,蛇绿岩残片和古老的高压变质岩无疑是两个最具影响力的问题。前者可以确定有远古的古老洋壳存在过并成为缝合带中的残片,后者可以指示曾有地表的岩石单元被俯冲到深部,是俯冲、消减与碰撞的岩石学证据。本文在讨论和比较了太古宙绿岩带与蛇绿岩,以及早前寒武纪高温高压(HTHP)麻粒岩/高温—超高温(HT-UHT)麻粒岩与造山带高压变质带之后,认为尚不能作为板块构造的证据。本文还对华北的新太古代末的稳定大陆形成以及古元古代活动带的裂谷-俯冲-碰撞进行了论述。提出华北克拉通在新太古代末的绿岩带-高级区格局可能标志着热体制下有限的横向活动构造,微陆块被火山-沉积岩系焊接,随后发生变质作用和花岗岩化,完成稳定大陆的克拉通化过程。其构造机制可能是适度规模且多发的地幔柱构造控制下小尺度的横向构造运动的机制。华北克拉通的古元古代活动带有与绿岩带-高级区不同的构造样式,表壳岩带状分布,经受了强烈的变形以及中级变质作用,伴随花岗岩的侵入,虽然没有蛇绿岩和高压变质带,但已表现出板块构造的雏形特征。     

华北克拉通南北缘三叠纪钼矿化类型、特征及地球动力学背景

华北克拉通南北缘是中国最重要的钼成矿带,特别是近年来在南北缘陆续发现了大量的钼矿床,显示了巨大的钼资源前景。其中三叠纪钼矿床的不断发现引人注目。在华北克拉通北缘及邻区三叠纪钼矿床在空间上总体呈EW向展布,矿床产出受区域东西向断裂控制,钼矿床的形成与三叠纪酸性侵入体关系密切,多产于花岗岩体中、斑岩体内外接触带或附近,矿床类型包括斑岩型和石英脉型。在华北克拉通南缘及邻区,三叠纪钼矿床总体上呈NW向展布,受区域NW向断裂控制,钼矿床的形成与晚三叠世酸性侵入体及碳酸盐脉有关,矿床产于斑岩体内及附近,矿床类型包括斑岩型、石英脉型及碳酸盐脉型。成矿年代学研究表明,华北克拉通北缘及邻区三叠纪钼矿主要形成于248~220Ma,而南缘及邻区三叠纪钼矿床主要形成于226~210Ma。其对应的成矿动力学背景为印支期华北板块与西伯利亚板块同碰撞造山过程和扬子板块与华北板块同碰撞造山过程。     

河南舞阳南部张士英岩体的地球化学与成因及其构造意义

张士英岩体岩石类型以石英二长岩、石英正长岩为主。岩体属于准铝质的高钾-钾玄岩系列(Al2O3为14.8%～16.7%,A/CNK=0.77～1.02,K2O/Na2O在1.00～1.43之间),稀土元素总量在261.7～381.0μg/g之间,轻稀土元素相对富集,稀土元素球粒陨石标准化模式呈右倾平滑曲线,(La/Yb)N比值为28～50,具有轻微的Eu负异常,Eu/Eu?比值在0.73～0.87之间。微量元素组成上表现为Sr、Ba、Nb、Ta的亏损,而Th、U相对富集。(87Sr/86Sr)i初始平均值为0.709,εNd(t)值为-13.9～-19.9,Nd的模式年龄为1.48～2.10Ga。岩体锆石LA-ICP-MSU-Pb年龄为(124.2±0.5)Ma,为早白垩世岩浆作用的产物。岩体侵位的区域地质背景为华北克拉通白垩纪大规模岩石圈转型和减薄时期,岩石的微量元素及同位素特征表明,岩体主要来源于下地壳物质的部分熔融,但有年轻地幔物质的加入。反映在区域强烈伸展拉张和岩石圈减薄背景下,软流圈地幔岩浆底侵所造成的下地壳部分熔融及壳幔混合过程。     

贺兰山孔兹岩系的变质时代及其对华北克拉通西部陆块演化的制约

贺兰山孔兹岩系作为华北克拉通西部孔兹岩带的重要组成部分,其变质时代问题一直悬而未决.利用SHRIMP锆石U-Pb定年技术,对贺兰山孔兹岩系中3个代表性富铝片麻岩(石榴堇青钾长片麻岩、石榴堇青二长片麻岩与石榴黑云斜长片麻岩)样品进行了精确定年.发现这3种岩石虽处不同层位,但其碎屑锆石年龄却非常集中,各测点207Pb/206Pb年龄总体变化在2.0～2.1Ga之间,加权平均年龄则在2017～2040Ma之间.这些碎屑锆石都具有岩浆结构特征,反映当时曾存在大规模花岗质岩浆活动,所成岩体为孔兹岩系沉积提供了充足物源.另有少量大于2.5Ga的碎屑锆石(2520～2949Ma),表明本区存在太古代岩浆活动记录.本区石榴堇青二长片麻岩中发育典型的变质增生锆石,其成因很可能与黑云母的脱水熔融反应有关.利用该锆石确定贺兰山孔兹岩系的变质时代为1950±8Ma.该时代与东部大青山、乌拉山孔兹岩系变质时代相同,表明华北克拉通西部的阴山地块与鄂尔多斯地块大体是以平行的方式正面拼贴到一起的,形成了目前的孔兹岩带.     

华北克拉通北缘喀喇沁变质核杂岩早白垩世构造演化过程与形成模式

对于喀喇沁变质核杂岩早白垩世构造过程与形成模式长期以来存在着不同的认识。通过详细的野外构造观察及擦痕应力场反演,并结合前人年代学数据,有效地制约了喀喇沁变质核杂岩早白垩世的构造演化,并对其形成模式进行了分析。结果表明,起源于晚侏罗世的喀喇沁变质核杂岩,在早白垩世(141～100 Ma)再次经历了强烈的伸展与岩浆活动。在此伸展活动中,沿着核部杂岩两侧分别发育了NE走向、倾向相反的楼子店-八里罕和上店-东风大型正断层,进而控制两侧半地堑式的小牛与平庄盆地的发育。在这两条边界断层的伸展运动及随后的均衡隆升中,核部杂岩不断抬升与剥露,先后发育了NE-NNE向的伸展韧性变形带与脆性正断层。这些早白垩世韧性和脆性伸展构造一致指示拉张方向为NW-SE向。综合分析表明,区内早白垩世伸展活动经历了141～134 Ma的初始伸展与同构造岩体侵位阶段、133～126 Ma的边界断层强烈活动与核部快速抬升阶段以及125～100Ma的均衡隆升阶段。喀喇沁变质核杂岩在早白垩世的伸展活动中转变为地垒式伸展穹窿,其强烈伸展活动出现在华北克拉通破坏峰期,动力学背景是古太平洋板块俯冲导致的远场弧后拉张。     

U-Pb Age and Hf Isotope Study of Detrital Zircons from the Wanzi Supracrustals： Constraints on the Tectonic Setting and Evolution of the Fuping Complex, Trans-North China Orogen

Located in the middle segment of the Trans-North China Orogen, the Fuping Complex is considered as a critical area in understanding the evolution history of the North China Craton （NCC）. The complex is composed of various high-grade and multiply deformed rocks, including gray gneiss, basic granulite, amphibolite, fine-grained gneiss and marble, metamorphosed to upper amphibolite or granulite facies. It can be divided into four rock units： the Fuping TTG gneisses, Longquanguan augen gneisses, Wanzi supracrustals, and Nanying granitic gneisses. U-Pb age and Hf isotope compositions of about 200 detrital zircons from the Wanzi supracrustals of the Fuping Complex have been analyzed. The data on metamorphic zircon rims give ages of 1.82-1.84 Ga, corresponding to the final amalgamation event of the NCC, whereas the data for igneous zircon cores yield two age populations at -2.10 and -2.51 Ga, with some inherited ages scattering between 2.5 and 2.9 Ga. These results suggest that the Wanzi supracrustals were derived from the Fuping TTG gneisses （-2.5 Ga） and the Nanying granitic gneisses （2.0-2.1 Ga） and deposited between 2.10 and 1.84 Ga. All zircons with -2.51 Ga age have positive initial εHf values from ＋1.4 to ＋10.9, suggesting an important crustal growth event at -2.5 Ga through the addition of juvenile materials from the mantle. The Hf isotope data for the detrital zircons further imply that the 2.8 Ga rocks are important components in the lower crust, which is consistent with a suggestion from Nd isotope data for the Eastern Block. The zircons of 2.10 Ga population have initial εHf values of-4.9 to ＋6.1, interpreted as mixing of crustal re-melt with minor juvenile material contribution at 2.1 Ga. These results are distinct from that for the Western Block, supporting that the Fuping Complex was emplaced in a tectonic active environment at the western margin of the Eastern Block.     

大别山早白垩世变质核杂岩的结构与演化

大别山中部混合岩-片麻岩穹隆的构造属性认识方面一直众说纷纭.通过对中大别杂岩及其边界剪切带或断裂带的构造解析,并结合对前人相关研究的总结,我们将中大别杂岩厘定为早白垩世的变质核杂岩,其中商麻断裂与晓天-磨子潭断裂和水吼-五河剪切带构成了一个完整的拆离断层带,并将变质核杂岩的形成时间限定在145～120 Ma.中大别杂岩...     

中生代复杂构造体系的成矿过程与成矿作用——以华北大陆北缘西拉木伦钼铜多金属成矿带为例

西拉木伦钼铜多金属成矿带处于华北克拉通与中亚造山带的过渡区,是古生代古亚洲构造域与中生代西太平洋构造域的交汇部位。在中生代受多种构造体系的制约,如中亚造山带造山后期局部伸展、蒙古-鄂霍茨克俯冲-碰撞造山作用、古太平洋板块的向西俯冲和中国东部岩石圈减薄事件的影响等。西拉木伦成矿带成矿斑岩锆石U-Pb年龄和辉钼矿Re-Os同位素年龄资料显示,钼铜矿成岩成矿主要集中在260～220Ma、180～150Ma和140～120Ma三个时期。结合华北克拉通北缘构造演化历史,推测这三期成矿作用主要与造山后局部伸展、构造体系转折和陆内伸展(岩石圈减薄)过程有关,并相应建立了"车户沟式"、"鸡冠山式"和"敖伦花式"三类斑岩钼铜矿床成矿模式。进一步研究表明,岩石的酸碱性、岩浆来源、岩浆的氧逸度、岩浆演化方式、构造背景等因素,制约了成矿作用的专属性。