Arsenic accumulation in the roots of Helianthus annuus and Zea mays by irrigation with arsenic-rich groundwater: Insights from synchrotron X-ray fluorescence imaging

The aim of this study was to investigate the accumulation of arsenic (As) in and on roots of Zea mays (maize) and Helianthus annuus (sunflower) by means of synchrotron-based micro-focused X-ray fluorescence imaging (μ-XRF). Plant and soil samples were collected from two field sites in the Hetao Plain (Inner Mongolia, China) which have been regularly irrigated with As-rich groundwater. Detailed μ-XRF element distribution maps were generated at the Fluo-beamline of the Anka synchrotron facility (Karlsruhe Institute of Technology) to assess the spatial distribution of As in thin sections of plant roots and soil particles. The results showed that average As concentrations in the roots (14.5–27.4 mg kg⁻¹) covered a similar range as in the surrounding soil, but local maximum root As concentrations reached up to 424 mg kg⁻¹ (H. annuus) and 1280 mg kg⁻¹ (Z. mays), respectively. Importantly, the results revealed that As had mainly accumulated at the outer rhizodermis along with iron (Fe). We therefore conclude that thin crusts of Fe-(hydr)oxides cover the roots and act as an effective barrier to As, similar to the formation of Fe plaque in rice roots. In contrast to permanently flooded rice paddy fields, regular flood irrigation results in variable redox conditions within the silty and loamy soils at our study site and fosters the formation of Fe-(hydr)oxide plaque on the root surfaces.     

Methodological comparison for quantitative analysis of fossil and recently derived carbon in mine soils with high content of aliphatic kerogen

In mine soil, quantification of soil organic carbon (OC) derived recently from biomass decomposition is complicated by the presence of fossil (geogenic) C derived from coal, oil shale, or similar material in the overburden. The only reliable method for such measurement is ¹⁴C analysis (i.e. radiocarbon dating) using instrumentation such as accelerator mass spectrometry, which is too expensive for routine laboratory analysis. We tested two previously used and two new methods for recent C quantification and compared them with ¹⁴C AMS radiocarbon dating as a reference using a set of soil samples (n = 14) from Sokolov, Czech Republic: (i) ¹³C isotope ratio composition, (ii) cross polarization magic angle spinning ¹³C nuclear magnetic resonance (CPMAS ¹³C NMR) spectroscopy, (iii) near infrared spectroscopy (NIRS) coupled with partial least squares regression and (iv) Rock–Eval pyrolysis. Conventional methods for OC determination (dry combustion, wet dichromate oxidation, loss-on-ignition) were also compared to quantify any bias connected with their use. All the methods provided acceptable recent carbon estimates in the presence of mostly aliphatic fossil C from kerogen. However, the most accurate predictions were obtained with two approaches using Rock–Eval pyrolysis parameters as predictors, namely (i) S₂ curve components and (ii) oxygen index (OI). The S₂ curve approach is based on the lower thermal stability of recent vs. fossil organic matter. The OI approach corresponded well with ¹³C NMR spectra, which showed that samples rich in recent C were richer in carboxyl C and O-alkyl C. These two methods showed the greatest potential as routine methods for recent C quantification.     

The material conditions for research in France from 1600 to 1850: Physics,chemistry and astronomy

The income of the scientists in France during the 17th to the middle of the 19th century is reviewed and compared to the cost of their instruments. Only a small number of scientists received enough public money to be able to do full-time research; this number increased substantially after the Revolution. Most scientists had to have other sources of income, in particular to be able to purchase their instruments. Large research projects, generally decided and financed by the Academy of Sciences, took place during this period, requiring collaborative interdisciplinary efforts and a considerable logistics: they anticipate our present cooperative programs and giant research facilities.     

Hemispheric asymmetry of sunspot area in solar cycle 23 and rising phase of solar cycle 24: Comparison of three data sets

Analysis of long-term solar data from different observatories is required to compare and confirm the various level of solar activity in depth. In this paper, we study the north–south asymmetry of monthly mean sunspot area distribution during the cycle-23 and rising phase of cycle-24 using the data from Kodaikanal Observatory (KO), Michelson Doppler Imager (MDI) and Solar Optical Observing Network (SOON). Our analysis confirmed the double peak behavior of solar cycle-23 and the dominance of southern hemisphere in all the sunspot area data obtained from three different resources. The analysis also showed that there is a 5–6 months time delay in the activity levels of two hemispheres. Furthermore, the wavelet analysis carried on the same data sets showed several known periodicities (e.g., 170–180 days, 2.1 year) in the north–south difference of sunspot area data. The temporal occurrence of these periods is also the same in all the three data sets. These results could help in understanding the underlying mechanism of north–south asymmetry of solar activity.     

The Euro-Atlantic Circulation Response to the Madden-Julian Oscillation Cycle of Tropical Heating: Coupled GCM Intervention Experiments

Abstract

Intervention experiments using the Coupled Forecast System model, version 2 (CFSv2), have been performed in which various Madden-Julian Oscillation (MJO) evolutions were added to the model’s internally generated heating: Slow Repeated Cycles, Slow Single Cycle, Fast Repeated Cycles, and Fast Single Cycle. In each experiment, one of these specified MJO evolutions of tropical diabatic heating was added in multiple ensemble reforecasts of boreal winter (1 November to 31 March for 31 winters: 1980–2010). Since in each experiment, multiple re-forecasts were made with the identical heating evolution added, predictable component analysis is used to identify modes with the highest signal-to-noise ratio. Traditional MJO-phase analysis of total model heating (dominated by internally generated heating) shows that the MJO-related heating structure compares well with heating estimated from observed fast and slow episodes; however, the model heating is larger by a factor of two. The evolution of Euro-Atlantic circulation regimes indicates a clear response due to the added heating, with a robust increase in the frequency of occurrence of the negative phase of the North Atlantic Oscillation (NAO?) after the heating crosses into the Pacific and a somewhat less robust increase in the positive phase of the NAO (NAO+) following Indian Ocean heating. In the Fast Cycle experiments, the model response is somewhat muted compared with the Slow Cycle experiments. The Scandinavian Blocking regime becomes more frequent prior to the NAO? regime. The two leading modes in the predictable component analysis of 300?hPa height (Z300), synoptic scale feedback (DZ300), and planetary wave diabatic heating in all experiments form an oscillatory pair with high statistical significance. The oscillatory pair represents the cyclic response to the particular MJO signal (Fast or Slow, Single, or Repeated Cycles) in each case. The period is about 64 days for the Slow Cycle and 36 days for the Fast Cycle, consistent with the imposed periods. The time series of one of the leading modes of Z300 is highly anti-correlated with the frequency of occurrence of the NAO– in the Repeated Cycle experiments. A clear cycle involving the Z300 and DZ300 leading modes is identified.     

UTEVA树脂分离纯化珊瑚中铀、钍的改进研究

珊瑚是记录海洋环境变化信息的载体之一,测定其U/Ca比值可重建海水温度或测定Th/U同位素比值可计算年龄重建海平面高度等.准确测定珊瑚中U、Th含量及同位素比值是提取所记载的海洋环境变化信息的前提,其难点在于高Ca基体分离和痕量U、Th富集纯化.基于此,本研究拟采用UTEVA树脂改进了一步富集分离珊瑚中U、Th的前处理...     

Sediment cascades and the entangled relationship between human impact and natural dynamics at the pre-pottery Neolithic site of Göbekli Tepe,Anatolia

This study presents a meta-analysis of radiocarbon ages for the environs of Göbekli Tepe – one of the oldest monumental structures worldwide – using cumulative probability functions to diachronically assess phases of geomorphodynamic activity as controlled by natural or anthropogenic drivers. We employ sediment cascades as a heuristic framework to study the complex responses of the geomorphological system to various triggers at local to supra-regional scales. Possible triggers include climatic variability as documented by supra-regional hydroclimatic proxy data, regional demographic trends, and local to regional socioeconomic developments such as the emergence of sedentism or the introduction and dispersal of livestock herding. Our results show that phases of intensified geomorphodynamic activity occurred between ca. 7.4–7.0 and 5.8–3.3 ka BP. These phases roughly coincide with phases of population growth in southern Turkey and climatic variations in Turkey and the Levant. The phase between ca. 5.8–3.3 ka BP also corresponds to the time when organized agriculture and the seeder plough were introduced. Also, the identified phases are in agreement with the general trend of varying geomorphodynamic activity in the Eastern Mediterranean as driven by human impact and climatic change. However, neither the Younger Dryas–Holocene transition nor the development of herding during the Pre-Pottery Neolithic left a clear signature. We demonstrate how the different depositional environments in the studied landscape compartments vary with respect to their spatiotemporal coverage and discuss challenges when trying to understand processes that once shaped landscapes of past societies. © 2020 The Authors. Earth Surface Processes and Landforms published by John Wiley & Sons Ltd     

Observations on decadal sandbar behaviour along a large-scale curved shoreline

Nearshore sandbars are characteristic features of sandy surf zones and have been observed with a variety of geometries in cross-shore (e.g. location) and longshore direction (e.g. planform). Although the behaviour of sandbars has been studied extensively on spatial scales up to kilometres and timescales up to years, it remains challenging to observe and explain their behaviour on larger spatial and temporal scales, especially in locations where coastline curvature can be prominent. In this paper, we study a data set with 38 years of coastal profiles, collected with alongshore intervals of 50 m, along the 34 km-long curved sandy shoreline of Sylt island, Germany. Sylt's shoreline has an orientation difference of ~20° between the northern and southern half of the island. We found that the decadal coastal profiles on the southern half show features of a low-tide terrace and a sandbar located further from the shoreline (~441 m). On the nothern half, the sandbar was located closer to the shoreline (~267 m) and was less pronounced, while the profiles show transverse bar and rip features. The alongshore planform also differed systematically and significantly along the two island sides. The sandbar on the southern island half, with alongshore periodicity on a larger length scale (~2240 m), was coupled out-of-phase to the shoreline, while no phase coupling was observed for the sandbar with periodicity on a shorter length scale (~670 m) on the northern half. We related the observed geometric differences of the sandbars to the difference in the local wave climate along Sylt, imposed by the shoreline shape. Our observations imply that small alongshore variations in wave climate, due to the increasing shoreline curvature on larger spatial scales, can lead to significant alongshore differences in the decadal evolution of coastal profiles, sandbars and shorelines. © 2020 The Authors. Earth Surface Processes and Landforms published by John Wiley & Sons Ltd     

Comparison of the return period for landslide-triggering rainfall events in Japan based on standardization of the rainfall period

The intensity of rainfall events with potential to cause landslides has varying temporal characteristics. In this study, the time at which the 72-h accumulated rainfall reached its maximum was used to standardize the period of rainfall measurement. The proposed standardization of the rainfall period was used in conjunction with the return level of rainfall intensity, obtained from intensity–duration–frequency curves, to investigate rainfall intensity anomalies associated with 10 hazardous rainfall events that triggered numerous landslides at the regional scale in Japan. These landslides included shallow landslides in volcanic and non-volcanic areas, as well as deep-seated landslides. The rainfall events that triggered the shallow landslides were divided into two types: downpours that repeatedly reached close to the 100-year return level within approximately 3–4 h, and accumulated rainfall that reached close to 200–400 mm over longer time intervals but within 72 h. Lithological differences seemed unrelated to the differences between the two types of shallow-landslide-triggering rainfall; however, precipitation >1000 mm was necessary to trigger deep-seated landslides. Although the characteristics of the hyetographs differed markedly among the landslide-triggering rainfall events, all the landslides could have been triggered when the mean rainfall intensity reached the 100-year rainfall level during the standardized period. Thus, the landslide trigger can be evaluated indirectly based on the increase in the return level of the mean rainfall intensity, which could provide a means for estimating the time of landslide occurrence.