微晶白云母负载纳米TiO2及其光催化性能研究

以微晶白云母为载体,钛酸丁酯为钛源,采用溶胶-凝胶法合成制备微晶白云母负载纳米TiO2光催化剂,然后用X射线衍射,扫描电镜等对微晶白云母负载TiO2光催化剂进行表征。再以微晶白云母负载纳米TiO2光催化剂对亚甲基蓝进行了光催化降解研究,特别针对有无紫外光照射条件下微晶白云母、纳米TiO2、微晶白云母/纳米TiO2等在亚甲基蓝溶液中的行为进行研究,结果表明:所制备的微晶白云母负载TiO2光催化剂对亚甲基蓝具有较好的光催化降解能力,1250目微晶白云母负载TiO2在紫外光照射下光催化反应4h,其降解率可达99%以上。     

Blue grabbing: Reviewing marine conservation in Redang Island Marine Park,Malaysia

While academic literature and media attention has rightly focused on the numerous instances of land grabbing taking place in various corners of the world, far less attention is paid to the enclosure, appropriation and dispossession taking place in the guise of marine conservation – or the recently developed concept of “blue grabbing”. Blue grabbing articulates how marine conservation results in the appropriation of marine resources and coastal land from previous custodians by more powerful actors, such as state and tourist operators. Blue grabbing can be considered a form of primitive accumulation, yet dispossession via marine conservation does not take the conventional form of privatising land, as the spaces involved are still formally state-owned areas. Rather, it is the benefits from natural resources that contribute to capital accumulation of tourist operators and indirectly the state. Restrictions on local resource use are justified using degradation narratives of “overfishing”, while financial benefits from tourism are drained from local communities within a system lacking transparency. This intervention draws on fieldwork research to reveal how blue grabbing plays out in Redang Island Marine Park, Malaysia, yet given that blue grabbing is a recently developed concept, argues there is a pressing need for research to build a more informed picture.     

山东蓝宝石（刚玉）热处理改善研究

本文采用高温热处理法,对山东蓝宝石进行改善实验,其内容主要涉及消除色斑,消除丝状包裹体,减轻蓝宝石发黑（色太深）现象。在此基础上对蓝宝石高温热处理改善机理进行探讨,研究认为：（１）高温环境下通过缺陷传递使晶格中Ｆｅ２＋变为Ｆｅ３＋;（２）恒温时间的变化率为粒径变化率的两倍;（３）降温速率极限为：φ＝ＲＳｆ（Ｔ）ｒ２;（４）改善后蓝宝石总带灰色色调的主要原因是Ｆｅ２＋－Ｆｅ３＋荷移加强和纳米级包裹体数量增加所致。     

红宝石和蓝宝石概述

系统地介绍了红宝石、蓝宝石的主要品种与不同矿区的产地特征,同时论述了红、蓝宝石和相似宝石及仿冒品的主要鉴别标志,并对优化、处理技术、宝石质量评价标准等作了扼要的阐述。     

Public preferences for policy intervention to protect public health from maritime activities: A 14 European country study

Marine ecosystems provide a wide range of goods and services that directly and indirectly benefit economies and support human health and wellbeing. However, these ecosystems are vulnerable to anthropogenic influences such as climate change, pollution and habitat destruction. The European Union (EU) recognises the role of the blue economy in providing jobs and contributing to economic growth, with the EU Integrated Maritime Policy being a cross-sectoral framework within which maritime activities are managed and coordinated. Sustainability is a central tenet, ensuring that sectors such as aquaculture and offshore wind energy, which are earmarked for growth, must develop in ways that do not negatively impact the health of the marine environment. However, there is currently little consideration of how these activities might impact public health. The current research used survey data from 14 European countries to explore public perceptions of these issues, broadly focusing on 10 maritime activities, with a specific focus on five activities related to the EU’s 2012 Blue Growth Strategy. The respondents appreciated the interconnections between these maritime activities, environmental protection and public health, as well as the potential trade-offs. Preferences for policy intervention to protect public health from different activities were predicted by both marine contact (marine sector employment, recreational activities) and socio-demographic (political attitudes, gender, age) variables, potentially aiding future engagement and communication initiatives. Substantive differences observed across countries in terms of policy preferences for different activities, however, warn against generalising for the European population as a whole.     

The nature of blue luminescence from natural benitoite BaTiSi<Subscript>3</Subscript>O<Subscript>9</Subscript>

It is proved that blue luminescence from benitoite is connected with intrinsic luminescence centers, namely isolated TiO₆ octahedra. The metastable level ³T_1u is the emitting level at low temperatures with a long decay time of 1.1 ms. At higher temperatures an energy level with higher radiation probability must be involved in the emission process, and this level is situated at 0.06 eV higher than the lowest level. These two levels may be connected with ³T_1u level splitting or with closely spaced ³T_1u and ³T_2u levels. Decay time shortening and thermal quenching are connected with nonradiative decay within the TiO₆ luminescence center, while energy migration does not take place at least up to room temperature.     

The Edinburgh-Cape blue object survey

The Edinburgh-Cape Blue Object Survey is a major survey to discover blue stellar objects brighter than B 18 in the southern sky. It is covering an area of sky of 10,000 square degrees with |b| > 30° and < 0°. The blue stellar objects are selected by automatic techniques from U and B pairs of UK Schmidt Telescope plates scanned with the COSMOS measuring machine. Follow-up photometry and spectroscopy are being obtained with the SAAO telescopes to classify objects brighter than B = 16.5. This paper describes the survey, the techniques used to extract the blue stellar objects, the photometric accuracy, the spectroscopic classification, and the completeness of the survey.     

Ranking the risk of CO2 emissions from seagrass soil carbon stocks under global change threats

Seagrass meadows are natural carbon storage hotspots at risk from global change threats, and their loss can result in the remineralization of soil carbon stocks and CO₂ emissions fueling climate change. Here we used expert elicitation and empirical evidence to assess the risk of CO₂ emissions from seagrass soils caused by multiple human-induced, biological and climate change threats. Judgments from 41 experts were synthesized into a seagrass CO₂ emission risk score based on vulnerability factors (i.e., spatial scale, frequency, magnitude, resistance and recovery) to seagrass soil organic carbon stocks. Experts perceived that climate change threats (e.g., gradual ocean warming and increased storminess) have the highest risk for CO₂ emissions at global spatial scales, while direct threats (i.e., dredging and building of a marina or jetty) have the largest CO₂ emission risks at local spatial scales. A review of existing peer-reviewed literature showed a scarcity of studies assessing CO₂ emissions following seagrass disturbance, but the limited empirical evidence partly confirmed the opinion of experts. The literature review indicated that direct and long-term disturbances have the greatest negative impact on soil carbon stocks per unit area, highlighting that immediate management actions after disturbances to recover the seagrass canopy can significantly reduce soil CO₂ emissions. We conclude that further empirical evidence assessing global change threats on the seagrass carbon sink capacity is required to aid broader uptake of seagrass into blue carbon policy frameworks. The preliminary findings from this study can be used to estimate the potential risk of CO₂ emissions from seagrass habitats under threat and guide nature-based solutions for climate change mitigation.     

Investigation of Biosorption Behavior of Methylene Blue on Pleurotus ostreatus (Jacq.) P. Kumm.

The effect of varying parameters such as dye concentration, adsorbent dose, pH and temperature on the adsorption capacity of Pleurotus ostreatus is investigated. The commonly available white rot fungus Pleurotus ostreatus is investigated as a viable biomaterial for the biological treatment of synthetic basic methylene blue effluents. The results obtained from the batch experiments reveal the ability of the fungus to remove methylene blue. The performance is dependent on the dye concentration, pH, and fungal biomass. The equilibrium and kinetics of adsorption are investigated and the Langmuir equation is used to fit the equilibrium isotherm. The adsorption isotherm of methylene blue follows only the Langmuir model with a correlation coefficient of ca. 0.96–0.99. The maximum adsorption capacity is ca. 70 mg of dye per g of dry fungus at pH 11, 70 mg L^–1 dye, and 0.1 g L^–1 fungus concentration, respectively. This study demonstrates that the fungus could be used as an effective biosorbent for the treatment of dye‐containing wastewater streams.     

P–T–t evolution of granulite facies metamorphism and partial melting in the Winding Stair Gap,Central Blue Ridge,North Carolina,USA

The Winding Stair Gap in the Central Blue Ridge province exposes granulite facies schists, gneisses, granofelses and migmatites characterized by the mineral assemblages: garnet–biotite–sillimanite–plagioclase–quartz, garnet–hornblende–biotite–plagioclase–quartz ± orthopyroxene ± clinopyroxene and orthopyroxene–biotite–quartz. Multiple textural populations of biotite, kyanite and sillimanite in pelitic schists support a polymetamorphic history characterized by an early clockwise P–T path in which dehydration melting of muscovite took place in the stability field of kyanite. Continued heating led to dehydration melting of biotite until peak conditions of 850 ± 30 °C, 9 ± 1 kbar were reached. After equilibrating at peak temperatures, the rocks underwent a stage of near isobaric cooling during which hydrous melt ± K‐feldspar were replaced by muscovite, and garnet by sillimanite + biotite + plagioclase. Most monazite crystals from a pelitic schist display patchy zoning for Th, Y and U, with some matrix crystals having as many as five compositional zones. A few monazite inclusions in garnet, as well as Y‐rich cores of some monazite matrix crystals, yield the oldest dates of c. 500 Ma, whereas a few homogeneous matrix monazites that grew in the main foliation plane yield dates of 370–330 Ma. Culling and analysis of individual spot dates for eight monazite grains yields three age populations of 509 ± 14 Ma, 438 ± 5 Ma and 360 ± 5 Ma. These data suggest that peak‐temperature metamorphism and partial melting in the central Blue Ridge occurred during the Salinic or Taconic orogeny. Following near isobaric cooling, a second weaker thermal pulse possibly related to intrusion of nearby igneous bodies resulted in growth of monazite c. 360 Ma, coinciding with the Neoacadian orogeny.