流体包裹体和C-H-O同位素对湘中古台山金矿床成因制约

古台山金矿是湘中盆地最典型的高品位石英脉型金矿床,主要赋存于新元古界和震旦系板岩-千枚岩中。为了探明古台山金矿的成矿物质和成矿流体来源,本次工作对其开展了详细的野外地质考察,对不同阶段石英进行了系统的包裹体岩相学观察、显微测温、激光拉曼探针及H-O同位素分析,对与金矿化密切相关的铁白云石进行了C-O同位素分析。包裹体岩相学及测温结果显示,不同阶段石英主要发育CO_2三相和水溶液两相包裹体,金沉淀阶段CO_2三相包裹体丰度最高,包裹体均一温度集中在180~320℃之间,盐度集中在0~13%NaCleqv之间。激光拉曼显示不同阶段石英包裹体成分主要为H_2O、CO12及少量的CH_4和N_2。不同阶段石英的δ~(18)O_(V-SMOW)变化范围为15.6‰~17.9‰,对应的δ8OH_2O变化范围为4.5‰~8.3‰,δD_(V-SMOW)变化范围-78‰~-49‰,显示成矿过程中有岩浆水参与。铁白云石的δ~(13)C_(PDB)集中在-10.3‰~-8.6‰,δ~(18)O_(V-SMOW)分布在13.9‰~15.7‰之间,暗示成矿流体中的碳主要来自深部岩浆。流体不混溶、CH_4气体存在、围岩及脉体发生硫化-碳酸盐化等因素是导致古台山矿床Au沉淀富集的重要机制。综合上述分析,推测古台山金矿可能是一个非典型的造山型金矿床。     

卷积神经网络及其在矿床找矿预测中的应用——以安徽省兆吉口铅锌矿床为例

大数据人工智能地质学刚刚起步,基于大数据智能算法的地质研究是非常有意义的探索性实验。利用大数据和机器学习解决矿产预测问题,有助于人们克服不能全面考虑地质变量的困难及评估当前模型在已有数据中的可靠性。元素地表分布特征量主要受原岩成分、成矿作用影响和地表过程的影响,它们携带某些指示矿体就位的信息,即矿体在地下空间就位时在地表的响应,且未在地表过程中消失。以往的地球化学勘查工作仅仅识别异常,但未能发现矿体在地表响应的成矿特征量。本文以安徽省兆吉口铅锌矿床为例,通过机器学习,利用卷积神经网络算法,不断挖掘元素Pb分布特征与矿体地下就位空间的耦合相关性。经过1000次训练后,可以得到准确率0. 93,损失率0. 28的卷积神经网络模型。这种神经网络模型就是矿体在地下就位时元素在地表分布的响应,可以用来进行矿产资源预测。应用该模型对未知区进行预测,结果显示第53号区域具有很大概率存在尚未发现的矿体。     

新疆西昆仑奥尔托喀讷什锰矿地质、地球化学及成因

近年来,西昆仑玛尔坎苏地区富锰矿找矿取得重大突破,新发现奥尔托喀纳什等大型锰矿床。该矿床层位稳定,厚度较大,Mn平均品位达35%以上,为中国最富的碳酸锰矿床,属于典型的海相沉积型锰矿床。锰矿体主要赋存于晚石炭世喀拉阿特河组地层中,该组岩性为一套浅海碳酸盐岩台地相沉积建造组合,可划分为台内浅滩、潮坪、开阔台地、局限台地等4个相类型。成矿分为三个期次,第一期为沉积成岩成矿期,矿石矿物由菱锰矿、锰方解石、硼锰矿组成;第二期为热液改造期,形成锰镁绿泥石、红锰矿、硫锰矿、锰方解石(脉)、重结晶菱锰矿、蔷薇辉石及滑石、石膏等;第三期为表生氧化期,发育少量软锰矿、水锰矿、硬锰矿等。锰矿石具有较低的Fe/Mn比值、V/(V+Ni)比值和强烈的Ce正异常,表明Mn是在氧化环境下,以氧化物或氢氧化物的形式沉积富集。含锰岩系顶、底板岩石中含较多成熟度较差的中酸性火山岩岩屑,以及具有较低Al/(Al+Fe+Mn)、Y/Ho、Co/Ni比值的锰矿石,说明其成矿物质来源于海底热水活动。奥尔托喀纳什锰矿具有"内源外生"的特点,锰矿石及菱锰矿具有负的δ~(13)C值(-23.3‰～-13.2‰),表明锰矿经历了先成锰氧化物或氢氧化物、再被还原转化成菱锰矿的过程。此外,有机质所导致的更为强烈的还原作用是本矿床富锰矿形成的重要机制。后期构造叠加致使矿体发生变形,矿体形态受褶皱控制。矿石受到强烈改造,形成锰镁绿泥石、红锰矿、蔷薇辉石等,晚期经历氧化淋滤作用形成软锰矿、水锰矿等。     

新疆奇台县黄羊山石墨矿床特征、物质来源及成因

黄羊山石墨矿床位于新疆东准噶尔造山带南部的卡拉麦里地区东南段,是近年来新发现的国内外首个产于花岗岩体中的超大型石墨矿床。成矿地质条件、矿床地质特征研究表明,该矿床与黄羊山碱性花岗岩体具有密切的时空及成因联系,矿石具独特的球状构造,球体中石墨与长英质矿物及磁黄铁矿、黄铜矿等金属硫化物密切共生。为确定黄羊山石墨矿床的成因和成矿物质来源,本文开展了球状矿石中的石墨拉曼光谱分析和C同位素测试,对与石墨密切共生的金属硫化物开展S-Pb同位素分析。结果表明,黄羊山矿床球状矿石不同部位石墨的拉曼谱峰相似,显示具有很高的结晶程度,估算结晶温度为750～800℃;7件石墨样品的δ~(13)C值在-19.27‰～-19.90‰,分布非常集中,介于岩浆碳值和有机碳值之间,表明具有两者的混合来源。4件磁黄铁矿样品的δ~(34)S值集中在-2.3‰～-2.9‰之间,接近原始地幔值;在Pb同位素构造环境判别图解上,Pb同位素比值(~(206)Pb/~(204) Pb=18.114～19.040,~(207)Pb/~(204) Pb=15.448 ～ 15.543,~(208) Pb/~(204)Pb=38.253～38.915)显示较好的线性关系,延伸方向与地幔演化曲线的延伸方向基本一致;S-Pb同位素测试结果表明,与石墨共生金属硫化物具有幔源特征。综合黄羊山矿床成矿地质条件、成矿特征、石墨及共生硫化物的物质来源等研究结果,本文初步认为,黄羊山石墨矿床形成于碱性花岗岩的岩浆作用阶段,矿石中的金属硫化物来自岩浆混合作用中的幔源基性端元,碳质由于岩浆同化混染作用达到饱和,在硫化物的催化下沉积形成石墨。     

云南香格里拉市热林铅锌银矿特征及找矿标志

云南香格里拉市热林铅锌银矿,矿体呈似层状赋存于三叠系上统曲嘎寺组三段(T3q3)之大理岩与板岩的层间构造破碎带中,矿体明显受断层构造及特定的岩性控制.该矿床属断层破碎带控制的热液型铅锌银矿床,断层破碎带和地球化学异常是直接的找矿标志,沿断层带出现的硅化、碳酸盐化、黄铁矿化和角岩化是间接的找矿标志.     

福建德化县九户林陶瓷土(瓷石)成矿地质条件及找矿方向

九户林陶瓷土(瓷石)矿床为碱长花岗岩脉型矿床,矿体赋存在晚白垩世碱长花岗岩体中,严格受张性断裂构造控制,矿体两侧具钾长石化带-纳长石化带-云英岩化带等蚀变分带,矿体与岩体、断裂构造组成了三位一体的成矿条件,属岩浆期后结晶分异作用形成的热液型矿床,成矿条件独特,晚白垩世碱长花岗岩(κργK2)岩体中,是该区瓷土(瓷石)找...     

云南鹤庆县小天井锰矿地质特征及找矿标志

云南鹤庆县小天井锰矿矿体呈层状、似层状,局部透镜状赋存于上三叠统松桂组第三段(T3sh3)灰岩、钙质泥岩中,矿体产状与围岩一致.矿体顶板的硅钙质层是该矿的直接找矿标志.矿床成因属沉积-改造型锰矿.     

Research achievements of the Qinghai-Tibet Plateau based on 60 years of aeromagnetic surveys

The Qinghai-Tibet Plateau (also referred to as the Plateau) has long received much attention from the community of geoscience due to its unique geographical location and rich mineral resources. This paper reviews the aeromagnetic surveys in the Plateau in the past 60 years and summarizes relevant research achievements, which mainly include the followings. (1) The boundaries between the Plateau and its surrounding regions have been clarified. In detail, its western boundary is restricted by West Kunlun-Altyn Tagh arc-shaped magnetic anomaly zone forming due to the arc-shaped connection of the Altyn Tagh and Kangxiwa faults and its eastern boundary consists of the boundaries among different magnetic fields along the Longnan (Wudu)-Kangding Fault. Meanwhile, the fault on the northern margin of the Northern Qilian Mountains serves as its northern boundary. (2) The Plateau is mainly composed of four orogens that were stitched together, namely East Kunlun-Qilian, Hoh-Xil-Songpan, Chamdo-Southwestern Sanjiang (Nujiang, Lancang, and Jinsha rivers in southeastern China), and Gangdese-Himalaya orogens. (3) The basement of the Plateau is dominated by weakly magnetic Proterozoic metamorphic rocks and lacks strongly magnetic Archean crystalline basement of stable continents such as the Tarim and Sichuan blocks. Therefore, it exhibits the characteristics of unstable orogenic basement. (4) The Yarlung-Zangbo suture zone forming due to continent-continent collisions since the Cenozoic shows double aeromagnetic anomaly zones. Therefore, it can be inferred that the Yarlung-Zangbo suture zone formed from the Indian Plate subducting towards and colliding with the Eurasian Plate twice. (5) A huge negative aeromagnetic anomaly in nearly SN trending has been discovered in the middle part of the Plateau, indicating a giant deep thermal-tectonic zone. (6) A dual-layer magnetic structure has been revealed in the Plateau. It consists of shallow magnetic anomaly zones in nearly EW and NW trending and deep magnetic anomaly zones in nearly SN trending. They overlap vertically and cross horizontally, showing the flyover-type geological structure of the Plateau. (7) A group of NW-trending faults occur in eastern Tibet, which is intersected rather than connected by the nearly EW trending that develop in middle-west Tibet. (8) As for the central uplift zone that occurs through the Qiangtang Basin, its metamorphic basement tends to gradually descend from west to east, showing the form of steps. The Qiangtang Basin is divided into the northern and southern part by the central uplift zone in it. The basement in the Qiangtang Basin is deep in the north and west and shallow in the south and west. The basement in the northern Qiangtang Basin is deep and relatively stable and thus is more favorable for the generation and preservation of oil and gas. Up to now, 19 favorable tectonic regions of oil and gas have been determined in the Qiangtang Basin. (9) A total of 21 prospecting areas of mineral resources have been delineated and thousands of ore-bearing (or mineralization) anomalies have been discovered. Additionally, the formation and uplift mechanism of the Plateau are briefly discussed in this paper.©2021 China Geology Editorial Office.     

鲁北新生代隐伏火山岩及其石油地质意义

鲁北新生代隐伏火山岩可划分为3个喷发期6个亚期,9种火山岩岩石类型和同期侵入的辉绿岩。它们形成在近大陆边缘的板内裂谷型盆地,对于富有机质生油岩的沉积、各种储集体的形成、多种含油圈闭类型的形成以及有机质成熟向烃类转化都是非常有利的。作为储集岩主要有玄武安山岩、辉绿岩和湖底玄武质凝灰岩。储油空间主要为次生孔隙和裂缝。火山岩及其有关岩石在本区不仅形成了特殊的油气藏,而且还可作为盖层、封堵层、披复构造的基岩,因此对石油地质勘探有重要意义。     

大气降水热液成矿——西秦岭某硅、灰、泥岩型铀矿床成矿模式探讨

西秦岭某硅、灰、泥岩型层控铀矿床是在矿源层(中志留统)的基础上,由地下水热液渗滤改造而成。铀的工业富集发生在矿源层褶皱成陆之后,成矿高峰则发生在中、新生代交替时期。成矿溶液是受大气降水补给的地下水热液;成矿物质主要来自矿源层本身。矿源层长期遭受地下水热液作用,溶液中大量的铀酰离子形成稳定的碳酸铀酰络合物,并被运移至岩性和构造的圈闭部位,通过吸附和共沉淀等作用富集,或通过还原、水解和过饱和沉淀等作用形成沥青铀矿或再生铀黑。该层控铀矿床的整个成矿过程具有典型的逐级增量特点,属于塔式累积成矿的基本模式,后生富集是成矿的关键。