Origin,distribution, and alteration of asphalts at Chapopote Knoll,Southern Gulf of Mexico

Following the discovery of asphalt volcanism in the Campeche Knolls a research cruise was carried out in 2006 to unravel the nature of the asphalt deposits at Chapopote. The novel results support the concept that the asphalt deposits at the seafloor in 3000 m of water depth originate from the seepage of heavy petroleum with a density slightly greater than water. The released petroleum forms characteristic flow structures at the seafloor with surfaces that are ‘ropy’ or ‘rough’ similar to magmatic lava flows. The surface structures indicate that the viscosity of the heavy petroleum rapidly increases after extrusion due to loss of volatiles. Consequently, the heavy petroleum forms the observed asphalt deposit and solidifies. Detailed survey with a remotely operated vehicle revealed that the asphalts are subject to sequential alterations: e.g. volume reduction leading to the formation of visible cracks in the asphalt surface, followed by fragmentation of the entire deposit. While relatively fresh asphalt samples were gooey and sticky, older, fragmented pieces were found to be brittle without residual stickiness. Furthermore, there is evidence for petroleum seepage from below the asphalt deposits, leading to local up-doming and, sometimes, to whip-shaped extrusions. Extensive mapping by TV-guided tools of Chapopote Asphalt Volcano indicates that the main asphalt deposits occur at the south-western rim that borders a central, crater-like depression. The most recent asphalt deposit at Chapopote is the main asphalt field covering an area of ∼2000 m². Asphalt volcanism is distinct from oil and gas seepage previously described in the Gulf of Mexico and elsewhere because it is characterized by episodic intrusions of semi-solid hydrocarbons that spread laterally over a substantial area and produce structures with significant vertical relief. As Chapopote occurs at the crest of a salt structure it is inferred that asphalt volcanism is a secondary result of salt tectonism.     

Why does the Sea Level Difference between Kushimoto and Uragami Show Periods of Large Meander and Non-Large Meander Paths of the Kuroshio South of Japan?

The sea level difference between Kushimoto and Uragami, located to the west and east of the southern tip of the Kii Peninsula, is relatively large in periods of non-large meander path (nLMP) of the Kuroshio south of Japan in comparison with periods of large meander path (LMP). Based on this clear relationship, the sea level difference between Kushimoto and Uragami has been used as an index showing the periods of nLMP and those of LMP of the Kuroshio south of Japan. It has been pointed out that warm and saline Kuroshio water, separated from the main path of the Kuroshio, has a tendency to approach the western area off Kii Peninsula to off Muroto Peninsula in periods of nLMP, while it approaches the eastern area off Kii Peninsula to Omae-zaki in periods of LMP. On the basis of this observational evidences, the dynamic background underlaying the well-known relationship between the Kuroshio path and the sea level difference between Kushimoto and Uragami is examined in the present study, using the temperature and salinity data observed by Wakayama Prefectural Fisheries Experimental Station and Fisheries Research Institute of Mie. It is shown that deviations in vertically integrated specific volume off Kushimoto and Uragami almost equal deviations in observed sea level at Kushimoto and Uragami, respectively. It is also shown that the difference in vertically integrated specific volume between off Kushimoto and off Uragami almost equals the difference in observed sea level between Kushimoto and Uragami. As for the Kuroshio water, the high-temperature contribution is predominant for its specific volume rather than that of high salinity, which yields thermal expansion in comparison with coastal water. Because the difference in vertically integrated specific volume between off Kushimoto and off Uragami almost equals the difference in observed sea level between Kushimoto and Uragami, it is concluded that the relationship between the Kuroshio path and sea level difference between Kushimoto and Uragami is caused by the different approaching of the warm Kuroshio water between in nLMP periods and in LMP periods.     

The role of lower continental crust and lithospheric mantle in the genesis of Plio–Pleistocene volcanic rocks from Sardinia (Italy)

The first comprehensive chemical and Sr–Nd–Pb isotopic data set of Plio–Pleistocene tholeiitic and alkaline volcanic rocks cropping out in Sardinia (Italy) is presented here. These rocks are alkali basalts, hawaiites, basanites, tholeiitic basalts and basaltic andesites, and were divided into two groups with distinct isotopic compositions. The vast majority of lavas have relatively high ⁸⁷Sr/⁸⁶Sr (0.7043–0.7051), low ¹⁴³Nd/¹⁴⁴Nd (0.5124–0.5126), and are characterised by the least radiogenic Pb isotopic composition so far recorded in Italian (and European) Neogene-to-Recent mafic volcanic rocks (²⁰⁶Pb/²⁰⁴Pb=17.55–18.01) (unradiogenic Pb volcanic rocks, UPV); these rocks crop out in central and northern Sardinia. Lavas of more limited areal extent have chemical and Sr–Nd–Pb isotopic ratios indicative of a markedly different source (⁸⁷Sr/⁸⁶Sr=0.7031–0.7040; ¹⁴³Nd/¹⁴⁴Nd=0.5127–0.5129; ²⁰⁶Pb/²⁰⁴Pb=18.8–19.4) (radiogenic Pb volcanic rocks, RPV), and crop out only in the southern part of the island. The isotopic ratios of these latter rocks match the values found in the roughly coeval anorogenic (i.e. not related to recent subduction events in space and time) mafic volcanic rocks of Italy (i.e. Mt. Etna, Hyblean Mts., Pantelleria, Linosa), and Cenozoic European volcanic rocks. The mafic rocks of the two Sardinian rock groups also show distinct trace element contents and ratios (e.g. Ba/Nb>14, Ce/Pb=8–25 and Nb/U=29–38 for the UPV; Ba/Nb<9, Ce/Pb=24–28 and Nb/U=46–54 for the RPV). The sources of the UPV could have been stabilised in the Precambrian after low amounts of lower crustal input (about 3%), or later, during the Hercynian Orogeny, after input of Precambrian lower crust in the source region, whereas the sources of the RPV could be related to processes that occurred in the late Palaeozoic–early Mesozoic, possibly via recycling of proto-Tethys oceanic lithosphere by subduction.     

Magmatic source enrichment by slab-derived melts in a young post-collision setting, central Mindanao (Philippines)

Central Mindanao was the locus of a Pliocene (4–5 Ma old) arc–arc collision event followed by basaltic to dacitic magmatism starting at 2.3 Ma, representing the most voluminous volcanic field in the Philippines. Lava compositions range from calc-alkaline to shoshonitic. Adakites and Nb-enriched basalts are among the magmatic products. All the lavas are Na-rich (up to 4.88%), with Na₂O/K₂O ratios from 2.5 to 6.5. Sr, Nd and Pb isotopic compositions are similar to MORB, except for some shoshonitic lavas that have slightly less radiogenic Nd ratios. K-enrichment in basalts can be related to both fractional crystallization (FC) at moderate pressures and to partial melting of an enriched source. Trace element systematics indicate that the sub-central Mindanao mantle is characterized by the presence of garnet, phlogopite, amphibole, and perhaps some titanate phase. The enrichment of this source is attributed to the interaction of slab-derived melts, i.e., adakites, with the arc mantle. This would explain the presence of Nb-enriched basalts, transitional adakites and high-magnesium andesites, as well as the bulk Na-enrichment and relatively unradiogenic character of the central Mindanao lavas. We envision an ion-exchange type of enrichment, in which the HFSE, LILE and LREE, mobilized during slab melting, are preferentially enriched in the metasomatized mantle, resulting in a diversity of post-collision magma compositions. The MORB-like isotopic signatures of the central Mindanao lavas preclude important contributions of slab-derived hydrous fluids, sediments, continental crust or an OIB-type contaminant. Slab melting after cessation of subduction is deemed possible by thermal rebound of previously depressed geotherms. Initial contributions to mantle enrichment in post-collision sites may thus come from slab melts. In most other cases of post-collision magmatism, however, this signature can be easily masked by enrichments coming from other sources, e.g., the continental lithosphere.     

Detailed Study of Three Contiguous Segments of the Mid-Atlantic Ridge,South of the Azores (37° N to 38°30′ N), Using Acoustic Imaging Coupled with Submersible Observations

Using a new tool of seafloor characterisation (sonar images from FARA-SIGMA cruise; Needham et al., 1992), coupled with submersible observations (DIVA1 cruise) we compare, at different scales of observation, three contiguous segments of the Mid-Atlantic Ridge, South of the Azores Triple Junction, between 37° N and 38°30 N.The two northernmost segments (38°20 N and Menez-Gwen) show unusual morphological features for the MAR; the rift valley is absent and the present-day magmatism is focused on shallow axial volcanoes. On the third segment (Lucky Strike), the morphology is the one usually found on the MAR. On the Menez-Gwen and 38°20 N segments, volcanic constructional activity can obliterate, during periods of high magmatic supply, the morphology inherited from tectonic activity. The dive results constrain the recent evolution of each segment and show that a temporal variability in volcanic dynamics exists. On the three segments, outcrops of eruptive lavas alternate with large areas of explosive volcanic ejecta. This cycle in volcanic activity is influenced by changes in water depth, both spatially (i.e. between segments) and temporally (i.e. for the same segment through time).Each segment has known a specific history in its accretionary processes with a succession of tectonic and volcanic predominance and changes in its volcanic phases between volcanic ejecta and effusive dynamics.The hydrothermal activity is focused at the central part of each segment and is controlled by the presence of fresh lava and major tectonic features.     

Magnetotelluric images of the crustal structure of Chyulu Hills volcanic field, Kenya

Electromagnetic experiments were conducted in 1995 as part of a multidisciplinary research project to investigate the deep structure of the Chyulu Hills volcanic chain on the eastern flank of the Kenya Rift in East Africa. Transient electromagnetic (TEM) and broadband (120–0.0001 Hz) magnetotelluric (MT) soundings were made at eight stations along a seismic survey line and the data were processed using standard techniques. The TEM data provided effective correction for static shifts in MT data. The MT data were inverted for the structure in the upper 20 km of the crust using a 2-D inversion scheme and a variety of starting models. The resulting 2-D models show interesting features but the wide spacing between the MT stations limited model resolution to a large extent. These models suggest that there are significant differences in the physical state of the crust between the northern and southern parts of the Chyulu Hills volcanic field. North of the Chyulu Hills, the resistivity structure consists of a 10–12-km-thick resistive (up to 4000 Ω m) upper crustal layer, ca. 10-km-thick mid-crustal layer of moderate resistivity (50 Ω m), and a conductive substratum. The resistive upper crustal unit is considerably thinner over the main ridge (where it is ca. 2 km thick) and further south (where it may be up to 5 km thick). Below this cover unit, steep zones of low resistivity (0.01–10 Ω m) occur underneath the main ridge and at its NW and SE margins (near survey positions 100 and 150–210 km on seismic line F of Novak et al. [Novak, O., Prodehl, C., Jacob, A.W.B., Okoth, W., 1997. Crustal structure of the southern flank of the Kenya Rift deduced from wide-angle P-wave data. In: Fuchs, K., Altherr, R., Muller, B., Prodehl, C. (Eds.), Structure and Dynamic Processes in the Lithosphere of the Afro-Arabian Rift System. Tectonophysics, vol. 278, 171–186]). These conductors appear to be best developed in upper crustal (1–8 km) and middle crustal (9–18 km) zones in the areas affected by volcanism. The low-resistivity anomalies are interpreted as possible magmatic features and may be related to the low-velocity zones recently detected at greater depth in the same geographic locations. The MT results, thus, provide a necessary upper crustal constraint on the anomalous zone in Chyulu Hills, and we suggest that MT is a logical compliment to seismics for the exploration of the deep crust in this volcanic-covered basement terrain. A detailed 3-D field study is recommended to gain a better understanding of the deep structure of the volcanic field.     

Geochemistry of Santo Antônio da Barra Kamafugites, Goiás, Brazil

This work focuses on the kamafugites from Santo Antônio da Barra, Minas–Goiás Alkaline Province. These rocks contain olivine, clinopyroxene, titanomagnetite, perovskite, leucite (pseudomorphs), kalsilite, nepheline, and phlogopite.The rocks investigated are ultrabasic, with high contents of CaO, FeO, and TiO₂, high to moderate contents of Al₂O₃, alkalis, and P₂O₅, and low contents of MgO. The alkaline characteristic of the rocks is reflected in TiO₂, K₂O, and Na₂O contents and in the frequent presence of normative nepheline and leucite. K₂O contents are not primary since most of the leucite was replaced by analcime.The negative K anomaly verified in the extended incompatible element distribution diagram for kamafugites seems to be mainly related to alteration. Kamafugites are characterized by a marked enrichment in incompatible and large ion lithophile elements together with other typical compatible elements.The Santo Antônio da Barra kamafugites are less enriched in titanium, niobium, zirconium, and REE than the Mata da Corda and most of the Toro-Ankole ones. San Venanzo–Cupaello rocks have much lower titanium contents.     

Complexity Theory of Natural Disasters; Boundaries of Self-Structured Domains

Disasters are often represented as complete breakdowns of quasi-stationary states in a landscape, but may also be part of the normal evolution of such states. A landscape is, in fact, an open, nonlinear, dynamic system where the tectonic uplift and the seismic activity represent the input, the mass wastage and the relief degradation the output. The apparent 'stability' is due to the fact that open, nonlinear dynamic systems tend to develop into relatively stable, self-organized ordered states 'at the edge of chaos', with a fractal attractor. Short of complete breakdown, such systems re-establish order in steps of various magnitudes which have a power-law distribution. Because of the fractal structure of the basic attractor, all subsets follow a power law which accounts for the distribution of the steps of recovery. As the domains of quasi-stationarity at the edge of chaos are represented by finite windows, the power-law does not cover all magnitudes. The stationarity windows are not only limited in range, but also in space and time. This should be taken into account in the assessment of hazards. Examples are given from seismology (earthquake frequency), volcanology (eruption frequency), river hydrology (flood frequency) and geomorphology (landslides).     

Explosive silicic volcanism in Iceland and the Jan Mayen area during the last 6 Ma: sources and timing of major eruptions

Fifty-three major explosive eruptions on Iceland and Jan Mayen island were identified in 0–6-Ma-old sediments of the North Atlantic and Arctic oceans by the age and the chemical composition of silicic tephra. The depositional age of the tephra was estimated using the continuous record in sediment of paleomagnetic reversals for the last 6 Ma and paleoclimatic proxies (δ¹⁸O, ice-rafted debris) for the last 1 Ma. Major element and normative compositions of glasses were used to assign the sources of the tephra to the rift and off-rift volcanic zones in Iceland, and to the Jan Mayen volcanic system. The tholeiitic central volcanoes along the Iceland rift zones were steadily active with the longest interruption in activity recorded between 4 and 4.9 Ma. They were the source of at least 26 eruptions of dominant rhyolitic magma composition, including the late Pleistocene explosive eruption of Krafla volcano of the Eastern Rift Zone at about 201 ka. The central volcanoes along the off-rift volcanic zones in Iceland were the source of at least 19 eruptions of dominant alkali rhyolitic composition, with three distinct episodes recorded at 4.6–5.3, 3.5–3.6, and 0–1.8 Ma. The longest and last episode recorded 11 Pleistocene major events including the two explosive eruptions of Tindfjallajökull volcano (Thórsmörk, ca. 54.5 ka) and Katla volcano (Sólheimar, ca. 11.9 ka) of the Southeastern Transgressive Zone. Eight major explosive eruptions from the Jan Mayen volcanic system are recorded in terms of the distinctive grain-size, mineralogy and chemistry of the tephra. The tephra contain K-rich glasses (K₂O/SiO₂>0.06) ranging from trachytic to alkali rhyolitic composition. Their normative trends (Ab–Q–Or) and their depleted concentrations of Ba, Eu and heavy-REE reflect fractional crystallisation of K-feldspar, biotite and hornblende. In contrast, their enrichment in highly incompatible and water-mobile trace elements such as Rb, Th, Nb and Ta most likely reflect crustal contamination. One late Pleistocene tephra from Jan Mayen was recorded in the marine sequence. Its age, estimated between 617 and 620 ka, and its composition support a common source with the Borga pumice formation at Sør Jan in the south of the island.