Determination of cadmium(II), copper(II), manganese(II) and nickel(II) species in Antarctic seawater with complexing resins

The strong species of cadmium(II), copper(II), manganese(II) and nickel(II) in an Antarctic seawater sample are investigated by a method based on the sorption of metal ions on complexing resins. The resins compete with the ligands present in the sample to combine with the metal ions. Two resins with different adsorbing strengths were used. Very stable metal complexes were investigated with the strong sorbent Chelex 100 and weaker species with the less strong resin, Amberlite CG-50. Strong species were detected for three of the considered metal ions, but not for Mn(II). Cu(II) is completely linked to species with a side reaction coefficient as high as log α_M(I) = 11.6 at pH = 7.3. The ligand concentration was found to be similar to that of the metal ion, and the conditional stability constant was around 10²⁰ M^− 1. In the considered sample, only a fraction of the metal ions Cd(II) and Ni(II) is bound to the strong ligands, with side reaction coefficients equal to log α_M(I) = 5.5 and 6.5 at pH = 7.3 for Cd(II) and Ni(II), respectively. These findings were confirmed by the test with the weaker sorbent Amberlite CG-50. It can be calculated from the sorption equilibria that neither Mn(II) nor Ni(II) is adsorbed on Amberlite CG-50 under the considered conditions and, in fact, only a negligible fraction of Mn(II) and Ni(II) was adsorbed. A noticeable fraction of Cd(II) was adsorbed on Amberlite CG-50, meaning that cadmium(II) is partially linked to weak ligands, possibly chloride, while no copper(II) was adsorbed on this resin, confirming that copper(II) is only combined in strong species. These results are similar, but not identical, to those obtained for other seawater samples examined in previous investigations.     

Modelling linear wave transformation induced by dissipative structures—Random waves

The relevant theory is presented and numerical results are compared with the analytical solution for the interaction of non-breaking waves with an array of vertical porous circular cylinders on a horizontal bed. The extension to the cases of unidirectional and multidirectional waves is obtained by means of a transfer function. The influence of the mechanical properties of porous structures and wave irregularity on wave transformation is analysed. Results for unidirectional and multidirectional wave spectra are compared to those obtained for regular waves. The model presented reproduces well the analytical results and provides a tool for analysing several engineering problems.     

柴达木盆地新构造运动主要特征与成因机制

研究表明，在壳幔结构、地球物理背景、沉积物结构、多层关地幔和构造样式等方面，达木盆地与中国东部新生代裂谷类伸展盆地具有可比性，应该归属 展性盆 。盆地伸展和收缩作用相间进行，伸展起因于地幔底辟；而收缩受两人因素影响；（１）盆地伸展作用受相邻造山带反作用诱导的挤压应力；（２）板块碰撞传递的远程板内应力。在此基础邮新的构造期达木盆地演化的“双层模式”，即地幔上隆－地壳伸展；被动挤压＋板内应力－地壳收缩     

对虾体内氯霉素含量测定方法的研究

应用ＨＰＬＣ技术建立常用药物氯霉素的虾体动力学研究方法。该方法的特点是：与微生物法、比色法、气相色谱法、荧光法及免疫法比较．测试准确、快速且灵敏度高。应用该方法可以从虾体内的血液、肌肉、肝胰脏、肠胃中分离出被虾吸收的氯霉素，并定量测定。在１—５０μｇ／ｍｌ范围内线性关系相关系数为０．９９９５。     

胶州湾泛亚码头疏浚方案优选及悬浮物影响预测

采用有限元分步杂交方法,在已建潮流场的基础上,建立了胶州湾疏浚物悬浮泥沙的二维输运-扩散模型,并应用于胶州湾前湾港区泛亚码头工程疏浚区的疏浚物输运扩散的数值模拟预测。根据预测结果分析了泛亚码头疏浚区施工期间悬浮泥沙对附近海域水环境和生态环境的影响,并对不同的疏浚方案进行了优选。     

水中矿物油荧光特性实验研究

为了实现现场测量地表水中矿物油含量的全光纤荧光计的研制。采用荧光光谱测量分析方法 ,于 1 999年 1 0月— 2 0 0 0年 5月 ,采集了国内外不同的地区原油和成品油共 2 3种 ,用1 4种不同波长的激发光激励 ,进行荧光光谱特性测量实验研究。同时 ,对不同浓度的矿物油、水混合液也进行了测量实验 ,得出其最低检测浓度为 0 .0 0 5mg/L ;测量了青岛近岸海域表层受油污染海水的含油量为 0 .0 1～ 0 .2 2mg/L ;此外对水中矿物油受激荧光发射原理也作了简述。并对水中矿物油荧光光谱特性、浓度与荧光强度的关系 ,以及为研制现场测量水中矿物油浓度的全光纤荧光计的可能性作出了结论性的意见     

渭河下游河道调整过程中的复杂响应现象

应用系统复杂响应的原理研究三门峡水库上游渭河河道调整过程,表明上游河道河床形态对基面上升所作出的响应是复杂的,弯曲系数的变化为先减小而后增大,宽深比的变化是先增大后减小,比降由先减小而后增大,最后均趋于稳定.     

滇西地区地壳上地幔电性结构与地壳构造活动的关系

本文根据滇西地区18个大地电磁测深点资料的数据处理和分析结果,对测区深部导电率在纵、横向上的变化特征进行了研究。结果表明:滇西地区深部电性为多层结构,大致可分四至五个电性结构层;深部电性结构横向变化大,明显受区域构造控制;该区上部地壳内普遍存在低阻层;上地幔高导层明显存在两个隆起区,一个以剑川—鹤庆为中心呈北北西向展布的隆起区,另一个以腾冲—潞西为轴呈南北向展布的隆起区。 本文还讨论了地壳上地幔电性结构与大地构造的关系,滇西北裂陷区盆地的形成,以及该区地震活动与深部构造的关系