Silurian A-type granitoids in the southern margin of the Tongbai-Dabieshan: Evidence from SHRIMP zircon geochronology and geochemistry

The Dabieshan Orogenic belt is well known for the exhumation of early Mesozoic ultrahigh-pressure (UHP) metamorphic rocks and Jurassic–Cretaceous emplacement of voluminous granitoids. However, the tectonic evolution in the orogen during the Paleozoic, especially its magmatic response to tectonism has not received much attention. As indicated by published data, the Dabieshan orogenic belt contains different records of Paleozoic magmatic-tectonic association in different tectonic units. Occ…     

The granite hosted gold deposit of Moulin de Chéni (Saint-Yrieix district,Massif Central,France): petrographic,structural, fluid inclusion and oxygen isotope constraints

The Moulin de Chéni orogenic gold deposit is the only granite-hosted deposit of the Saint-Yrieix district, French Massif Central. It occurs in 338±1.5 Ma-old peraluminous leucogranites and is characterized by intense microfracturing and bleaching of the granite in relation to pervasive sulfide crystallization. Formation of quartz veins and gold deposition occurred in two successive stages: an early mesozonal stage of quartz-sulfide (Fe-As-S) deposition, usually devoid of gold and a late epizonal stage of base metal and gold deposition. Both stages postdate peak metamorphism and granite intrusion. The genesis of the deposit is the result of four successive fluid events: (1) Percolation of aqueous-carbonic metamorphic fluids under an assumed lithostatic regime of 400–450 °C, at a maximum depth of 13 km; (2) Formation of the main quartz lodes with coeval K-alteration and introduction of As and S from aqueous-carbonic fluids percolating along regional faults. Arsenopyrite and pyrite deposition was linked to the alteration of Fe-silicates into K-feldspar and phengite at near-constant iron content in the bulk granite. Temperature was similar to that of the preceding stage, but pressure decreased to 100–50 MPa, suggesting rapid uplift of the basement up to 7.5 km depth; (3) The resulting extensional tectonic leads to the deposition of gold, boulangerite, galena and sphalerite in brecciated arsenopyrite and pyrite from aqueous fluids during a mixing process. Temperature and salinity decrease from 280 to 140 °C and 8.1 wt% eq. NaCl to 1.6 wt% eq. NaCl, respectively; (4) Sealing of the late fault system by barren comb quartz which precipitated from dilute meteoric aqueous fluids (1.6 wt% eq. NaCl to 0.9 wt% eq. NaCl) under hydrostatic conditions at 200–150 °C.Editorial handling: B. Lehmann     

Shoshonite and sub-alkaline magmas from an ultrapotassic volcano: Sr–Nd–Pb isotope data on the Roccamonfina volcanic rocks,Roman Magmatic Province,Southern Italy

The Roccamonfina volcano is characterised by two stages of volcanic activity that are separated by volcano-tectonic caldera collapses. Ultrapotassic leucite-bearing rocks are confined to the pre-caldera stage and display geochemical characteristics similar to those of other volcanoes in the Roman Province. After the major sector collapse of the volcano, occurred at ca. 400 ka, shoshonitic rocks erupted from cinder cones and domes both within the caldera and on the external flanks of the pre-caldera Roccamonfina volcano. On the basis of new trace element and Sr–Nd–Pb isotope data, we show that the Roccamonfina shoshonitic rocks are distinct from shoshonites of the Northern Roman Province, but are very similar to those of the Neapolitan volcanoes. The last phases of volcanic activity erupted sub-alkaline magmas as enclaves in trachytic domes, and as lavas within the Monte Santa Croce dome. Ultrapotassic rocks of the pre-caldera composite volcano are plagioclase-bearing leucitites characterised by high levels of incompatible trace elements with an orogenic signature having troughs at Ba, Ta, Nb, and Ti, and peaks at Cs, K, Th, U, and Pb. Initial values of ⁸⁷Sr/⁸⁶Sr range from 0.70926 to 0.70999, ¹⁴³Nd/¹⁴⁴Nd ranges from 0.51213 to 0.51217, while the lead isotope rations vary between 18.788–18.851 for ²⁰⁶Pb/²⁰⁴Pb, 15.685–15.701 for ²⁰⁷Pb/²⁰⁴Pb, and 39.048–39.076 for ²⁰⁸Pb/²⁰⁴Pb. Shoshonites show a similar pattern of trace element depletions and enrichments to the earlier ultrapotassic leucite-bearing rocks but have a larger degree of differentiation and lower concentrations of incompatible trace elements. On the other hand, shoshonitic rocks have Sr, Nd, and Pb isotopes consistently different than pre-caldera ultrapotassic leucite-bearing rocks. ⁸⁷Sr/⁸⁶Sr ranges from 0.70665 to 0.70745, ¹⁴³Nd/¹⁴⁴Nd ranges from 0.51234 to 0.51238, ²⁰⁶Pb/²⁰⁴Pb ranges from 18.924 to 19.153, ²⁰⁷Pb/²⁰⁴Pb ranges from 15.661 to 15.694, and ²⁰⁸Pb/²⁰⁴Pb ranges from 39.084 to 39.212. High-K calc-alkaline samples have intermediate isotopic values between ultrapotassic plagioclase leucitites and shoshonites, but the lowest levels of incompatible trace element contents. It is argued that ultrapotassic magmas were generated in a modified lithospheric mantle after crustal-derived metasomatism. Interaction between the metasomatic agent and lithospheric upper mantle produced a low-melting point metasomatised veined network. The partial melting of the veins alone produced pre-caldera leucite-bearing ultrapotassic magmas. It was possibly triggered by either post-collisional isotherms relaxation or increasing T°C due increasing heat flow through slab tears. Shoshonitic magmas were generated by further melting, at higher temperature, of the same metasomatic assemblage with addition 10–20% of OIB-like astenospheric mantle material. We suggest that addition of astenospheric upper mantle material from foreland mantle, flowing through slab tearing after collision was achieved. Electronic supplementary material  The online version of this article (doi:) contains supplementary material, which is available to authorized users.     

Retardation capacity of altered granitic rock distributed along fractured and faulted zones in the orogenic belt of Japan

There are wide areas of granitic rocks in the Japanese orogenic belt. These granitic bodies inevitably contain fracture and fault systems associated with alteration zones. However, relatively little attention has been given to the possible influence of such widely distributed alteration zones on the migration of radionuclides from any radioactive waste repository that might in future be sited within granitic rock. In particular, the influences of alteration products and micro-fractures, due to chemical sorption and/or physical retardation require further consideration. In order to understand the retardation capacity of the altered deep granitic rocks, detailed geometrical characterization of pores, geochemical analysis, and batch sorption and flow-through experiments have been carried out. Those results show that the altered granite has a large volume of accessible pores, particularly in potassium-feldspar grains, which would influence nuclide retardation more than the accessible porosity in other minerals present, such as biotite. The distribution coefficients, Kd estimated from batch sorption tests and flow-through experiments suggest that altered granite has a high capability to retard the migration of nuclides. The retardation would probably be due to sorption on altered minerals such as sericite and iron hydroxides formed along grain boundaries and in pores created by dissolution, in addition to sorption on primary sorptive minerals. These results provide confidence that even altered and fractured parts of any granitic rock that might be encountered in a site for the disposal of high level radioactive waste may still retard radionuclide migration and thereby help the geosphere to function as a barrier.     

甘肃北山地区古亚洲南缘古生代岛弧带位置的讨论

综合研究得出结论:"甘肃北山红石山断裂带以北的雀儿山-英安山地区为一种与俯冲洋壳板块相关的岛弧带,它记录了古亚洲大洋向南缘东天山古陆系统下俯冲消减的整个地史过程".主要依据:①该地区缺少古老基底陆壳;②发育于区内的中奥陶世-泥盆纪不同时代地层中的火山岩和石炭-三叠纪的中酸性侵入岩,主要以钙碱性或TTG或埃达克成分系列为主要标志,揭示深部有消减洋壳板片或岩源的存在;③从中奥陶世和志留纪火山岩的玄武岩、安山岩和英安岩组合,到泥盆纪以安山岩、英安岩为主的流纹岩、玄武岩组合,至三叠纪马鞍山、小草湖中酸性侵入岩序列的部分高钾钙碱性岩石类型组合,反映古亚洲大洋在南侧消减带之上从一种不成熟岛弧到成熟岛弧和大陆边缘弧发育演化的过程;文章提出代表古亚洲大洋南缘消减带的实际位置应在雀儿山-英安山一线以北的蒙古境内,而北山岛弧带实属南侧东天山古陆陆缘增生地体的一部分.     

Geochemical, Sr–Nd and zircon U–Pb–Hf isotopic studies of Late Carboniferous magmatism in the West Junggar, Xinjiang: Implications for ridge subduction?

Voluminous granitic intrusions are distributed in the West Junggar, NW China, and they can be classified as the dioritic rocks, charnockite and alkali-feldspar granite groups. The dioritic rocks (SiO₂ = 50.4–63.8 wt.%) are calc-alkaline and Mg enriched (average MgO = 4.54 wt.%, Mg^# = 0.39–0.64), with high Sr/Y ratios (average = 21.2), weak negative Eu (average Eu/Eu = 0.80) and pronounced negative Nb–Ta anomalies. Their Sr–Nd and zircon Hf isotopic compositions ((⁸⁷Sr/⁸⁶Sr)_i = 0.7035–0.7042, ε_Nd(t) = 4.5–7.9, ε_Hf(t) = 14.1–14.5) show a depleted mantle-like signature. These features are compatible with adakites derived from partial melting of subducted oceanic crust that interacted with mantle materials. The charnockites (SiO₂ = 60.0–65.3 wt.%) show transitional geochemical characteristics from calc-alkaline to alkaline, with weak negative Eu (average Eu/Eu = 0.75) but pronounced negative Nb–Ta anomalies. Sr–Nd and zircon Hf isotopic compositions ((⁸⁷Sr/⁸⁶Sr)_i = 0.7037–0.7039, ε_Nd(t) = 5.2–8.0, ε_Hf(t) = 13.9–14.7) also indicate a depleted source, suggesting melts from a hot, juvenile lower crust. Alkali-feldspar granites (SiO₂ = 70.0–78.4 wt.%) are alkali and Fe-enriched, and have distinct negative Eu and Nb–Ta anomalies (average Eu/Eu = 0.26), low Sr/Y ratios (average = 2.11), and depleted Sr–Nd and zircon Hf isotopic compositions ((⁸⁷Sr/⁸⁶Sr)_i = 0.7024–0.7045, ε_Nd(t) = 5.1–8.9, ε_Hf(t) = 13.7–14.2). These characteristics are also comparable with those of rocks derived from juvenile lower crust. Despite of the differences in petrology, geochemistry and possibly different origins, zircon ages indicate that these three groups of rocks were coevally emplaced at ~ 305 Ma.A ridge subduction model can account for the geochemical characteristics of these granitoids and coeval mafic rocks. As the “slab window” opened, upwelling asthenosphere provided enhanced heat flux and triggered voluminous magmatisms: partial melting of the subducting slab formed the dioritic rocks; partial melting of the hot juvenile lower crust produced charnockite and alkali-feldspar granite, and partial melting in the mantle wedge generated mafic rocks in the region. These results suggest that subduction was ongoing in the Late Carboniferous and, thus support that the accretion and collision in the Central Asian Orogenic Belt took place in North Xinjiang after 305 Ma, and possibly in the Permian.     

新疆南天山阿沙哇义金矿床的成因与找矿启示:来自流体和硫化物成分的限定

阿沙哇义金矿位于中国新疆南天山造山带,属于著名的中亚南天山锑-汞-金成矿带的东延部分。该矿床严格受断裂所控制,以浸染状黄铁矿化、毒砂化为特征。矿化可分为三个阶段:早期无矿或贫矿石英阶段,中期石英多金属硫化物阶段,晚期石英-碳酸盐阶段。其中,中期是主要成矿阶段。成矿流体气相成分以H_2O为主,摩尔含量为75%～93%,其次为CO_2,摩尔含量为6%～25%,其余为CH_4、C_2H_6、H_2S、N_2和Ar;液相成分阳离子以Na~+为主,含少量K~+、Ca~(2+)离子,阴离子以Cl~-为主,SO~(2-)次之;矿石的Au含量与其流体的CO_2含量呈反相关,与K~+含量呈正相关。硫化物成分分析结果表明:(1)围岩地层和矿石中的黄铁矿和毒砂是重要的载金矿物,黄铁矿Au含量为0～0. 09%,平均值0. 03%;毒砂Au含量为0～0. 28%,平均值0. 07%;(2)黄铁矿和毒砂Au含量与其自形程度没有明显的相关性;(3)环带状黄铁矿较均质结构黄铁矿具有更高的Au含量;(4)岩体中的黄铁矿几乎不含Au。在成矿构造环境、成矿流体特征及演化、金矿富集机制、成矿温压条件等方面,该矿床与世界上大多数造山型金矿显示出一致性,成矿类型应属于剥蚀程度较浅的造山型金矿。断层阀作用控制的断层愈合-破裂导致的流体不混溶作用是本区金富集、沉淀的最重要机制,但流体混合机制对金的富集沉淀也发挥了作用。黄铁矿、毒砂发育及较多的含炭物质三者共存是本区寻找富矿的关键标志。     

Final Closure Time of the Paleo‐Asian Ocean: Implication from the Provenance Transformation from the Yangjiagou Formation to Lujiatun Formation in the Jiutai Area,NE China

The Jiutai area is tectonically situated at the eastern segment of the Central Asian Orogenic Belt(CAOB) and is close to the North China Craton(NCC) to the south, serving as an ideal place to investigations of the closure of the PaleoAsian Ocean(PAO). Sandstone samples collected from the Yangjiagou Formation and the Lujiatun Formation in this area have been studied in detail in terms of petrology, geochronology and geochemistry. The maximum depositional time of the Yangjiagou and Lujiatun formations has been constrained to early Middle Triassic(ca. 245 Ma) and middle Late Triassic(ca. 219 Ma), respectively. The Yangjiagou Formation, with a major provenance of dissected island arcs, is dominantly composed of Phanerozoic sediments from Northeastern China(NE China) massifs. The Lujiatun Formation, with major sediments from active continental margins, has a relatively larger proportion of Precambrian sediments, in which the ～1.85 Ga and ～2.5 Ga sediments are typical of the crystalline basements of the NCC and NE China massifs, which were uplifted and eroded during the closure of the PAO. Besides, both formations show the enrichment in LREEs and the depletion in HREEs, the common Eu negative anomalies, and trace element contents similar to that of the upper continental crust. Based on the provenance analysis of these two formations, the final closure time of the PAO in this area is constrained as from the early Middle Triassic(ca. 245 Ma) to the middle Late Triassic(ca. 219 Ma).     

北山南部二叠纪海相玄武岩地球化学特征及其构造意义

基于北山南部晚古生代构造演化争议较大,本文对该区4条下—中二叠统代表剖面中的玄武岩进行了岩相学、元素地球化学、及全岩Sr- Nd同位素等研究;并对地层中的中酸性火山岩进行了锆石U- Pb定年。获得英安岩与安山岩的锆石U- Pb年龄分别为289. 5±2. 3Ma和267. 8±3. 1Ma,结合已发表年龄数据及古生物资料,明确了火山岩的喷发时代介于早二叠世亚丁斯克期—中二叠世沃德期。该套玄武岩产于海相地层中,主体为拉斑玄武岩系列;氧化物含量变化较大,TiO 2 含量中等(0. 9%~2. 53%);轻重稀土分馏不明显［(La/Yb) N=1. 6~6. 2］,且无显著Eu异常( δ Eu为0. 79~1. 19);不同程度亏损Nb、Ta、Ti、P等元素,富集La、Ce、Nd、Zr等元素;ε Nd ( t ) 值介于1. 4~10. 9,( 87 Sr/ 86 Sr) i 值为0. 703365~0. 707285。玄武岩源区为受俯冲物质改造的软流圈地幔,经不同程度熔融所形成;既与岛弧或陆缘弧所产生的火山岩有所差别,又不同于地幔柱或热点所产生的玄武岩,在各判别图解中,大多投入板内玄武岩(WPB)或洋脊玄武岩(MORB)。结合该区域其他地质资料,推测该套玄武岩的产生与北山南部加厚岩石圈的拆沉作用有关。     

东昆仑古特提斯后碰撞阶段伸展作用:来自晚三叠世岩浆岩的证据

通过对东昆仑造山带晚三叠世岩浆岩的岩石类型、形成时代、岩石地球化学和同位素地球化学资料综合分析,对岩浆岩的岩石组合、分布特征和岩石成因进行研究,探讨东昆仑造山带晚三叠世构造演化的地球动力学背景。东昆仑造山带晚三叠世是古特提斯演化过程中重要的构造转换期,岩浆岩岩石类型多样,主要包括辉长岩、花岗闪长岩、二长花岗岩和正长花岗岩,并且广泛出露具埃达克质特征的岩浆岩和A型花岗岩。晚三叠世岩浆岩的出露规模与俯冲阶段相比,规模较小,一般以小岩体、岩株和岩脉侵入于早期岩体和地层中。东昆仑晚三叠世岩浆岩主体为准铝-弱过铝质高钾钙碱性-钾玄岩系列,轻重稀土元素具有一定分异,富集大离子亲石元素,亏损高场强元素,岩石类型不同时分异程度、富集和亏损程度有一定差异。大部分晚三叠世花岗质岩浆岩的同位素特征与晚二叠世-三叠纪镁铁质岩浆岩近似,部分具有更高的εNd(t)和εHf(t)值。镁铁质岩浆岩、普通花岗岩、埃达克质岩浆岩在东昆仑各个构造带皆有分布,A型花岗岩主要分布在祁漫塔格构造带(东昆北)的阿牙克库木湖-香日德断裂附近。东昆仑晚三叠世镁铁质岩浆岩具有弧岩浆岩特征,为俯冲流体交代的地幔楔部分熔融产物。普通花岗岩和埃达克质岩浆岩多为新生下地壳部分熔融产物,少量埃达克质岩浆岩由于与地幔的交代作用,具有幔源特征。A型花岗岩为残留下地壳部分熔融的产物。部分普通花岗岩、埃达克质岩浆岩和A型花岗岩由于岩浆混合作用,具幔源特征。构造环境研究表明,东昆仑在晚三叠世进入古特提斯演化的后碰撞阶段。巴颜喀拉地块同东昆仑地块的持续碰撞导致地壳加厚,密度增大,使岩石圈重力不稳定发生拆沉作用,引发岩石圈地幔减压熔融,产生大量的镁铁质岩浆岩;镁铁质岩浆底侵不同类型地壳熔融及拆沉地壳部分熔融而形成的岩浆交代地幔,以及岩浆混合和岩浆后期演化,形成了东昆仑造山带晚三叠世丰富多样的岩浆岩。