西准噶尔成矿带晚古生代花岗岩类岩浆活动及其构造意义

中亚造山带是晚古生代地壳显著生长与大规模成矿的重要地区。本文采集了中亚造山带西部的西准噶尔成矿带哈图-别鲁阿嘎希及其附近地区11个岩体共33件花岗岩类样品,对其开展了岩石地球化学与同位素示踪等研究,厘定了该地区晚古生代岩浆活动的特点与大地构造环境,并与哈萨克斯坦境内的巴尔喀什成矿带晚古生代岩浆活动进行了对比。研究表明,哈图地区晚石炭世花岗岩类主要为后碰撞伸展构造环境的A型花岗岩类,别鲁阿嘎希等地区存在洋内俯冲与岛弧环境的埃达克岩,显示了西准噶尔晚古生代构造环境时空变化的复杂性。该地区花岗岩类εNd(t)值较高(+4.62~+7.53)、εSr(t)值为(-57.61~+18.21),具有中亚造山带花岗岩类的共同特征,为古生代增生的新生陆壳,其源区与亏损地幔组分具有亲缘关系,这与巴尔喀什成矿带东段的花岗岩类具有一致性。花岗岩的~(206)Pb/~(204)Pb、~(207)Pb/~(204)Pb和~(208)Pb/~(204)Pb比值范围分别为18.2776~19.1677、15.5260~15.5796和38.2080~39.0821,为造山带花岗岩类。     

甘肃北山造山带南缘白石坝一带南岭型花岗岩地球化学特征与锡成矿作用浅析

白石坝一带花岗岩具高硅低铝、富钾贫钠、非常低Sr(24.9×10~(-6)~82.9×10~(-6))高Yb(2.61×10~(-6)~5.74×10~(-6))的南岭型花岗岩特征,A/CNK介于0.91~0.98之间,σ在1.92~2.22之间。明显富集Rb、Th、K等大离子不相容元素,亏损Ba、Sr、P、Ti等元素,并具有弱Nb亏损,稀土元素分布曲线呈明显的"燕式"型,其形成可能来源于下地壳底部部分熔融与地壳物质发生混合形成的产物,源区深度较浅、水含量低和氧逸度低,处于还原状态下的伸展构造背景,有利于锡矿的萃取和富集,研究其区域构造-岩浆演化,对指导区域矿产预测和评价均具有重要的理论和实际意义。     

兴蒙造山带—华北克拉通地球化学走廊带沉积物主成分的含量与空间分布研究

选取兴蒙造山带—华北克拉通地球化学走廊带上沉积物的SiO_2、Al_2O_3、CaO、MgO、Na_2O、K_2O、TFe_2O_3、FeO、TiO_2、MnO、P_2O_5、CO_2、H_2O~+、pH十四个指标,研究其在不同二级构造单元、地理景观、土壤类型、降雨量等级下的含量与空间分布特征,并讨论该地球化学走廊带上化学蚀变指数。结果表明:在兴蒙造山带—华北克拉通地球化学走廊带上,作为沉积物主体的SiO_2、Al_2O_3两者含量为明显负相关而空间分布表现出此消彼长的特征;CaO、MgO、CO_2高含量分布区则与碳酸盐岩地层或含碳酸盐矿物的土壤有关,而MgO的高含量还与走廊带上镁铁质基性-超基性岩有一定关系,表明了这三个指标的高含量受特定岩性或矿物的影响较大;Na_2O、K_2O含量除了受继承的基岩影响外,还受到后期的风化作用和气候及自身地球化学性质等复杂因素综合影响,对Na_2O来说尤为如此;TFe_2O_3、MnO、TiO_2、P_2O_5相对于在地质背景复杂地段,经过冲积平原的沉积物混匀后,含量差异更小;相对干冷的内蒙古半干旱草原的气候条件有利于FeO存在,使得其相对燕山地区含量差异较TFe_2O_3要小,在章丘以南相对温暖湿润地区更易被氧化而导致其含量整体较低;北方干冷气候条件下,沉积物H_2O~+含量普遍较低,局部高含量位于碳酸盐岩地层或第四系分布区;走廊带上的pH值反映了沉积物偏碱性的特征,而在章丘以南的地区随着降雨量的增加,相对温暖湿润的气候条件,沉积物pH值表现为中性-偏弱酸性;兴蒙造山带—华北克拉通地球化学走廊带沉积物的CIA值反映出在寒冷、干燥气候条件下低等的化学风化程度,兴蒙造山带沉积物平均风化程度相对华北克拉通沉积物的平均风化程度差异变化相对要小,显示兴蒙造山带的降雨量与温度等风化影响因素变化较小。作为反映元素的地球化学亲和性的量化指标,离子电位可以更好地帮助理解沉积物元素的含量和空间分布差异。     

新疆北山小常山铁矿矿物电子探针分析及矿床成因探讨

小常山铁矿位于新疆北山裂谷带西段,矿体赋存于辉长岩、辉长岩和大理岩接触带中,部分赋存于花岗闪长岩和大理岩接触带。前人研究辉长岩年龄为276±1.2Ma,与坡北铜镍硫化物岩浆矿床形成年龄一致,同属早二叠世。小常山铁矿中可见有明显的岩浆贯入现象。矿体主要呈透镜状、块状、脉状、薄层状。金属矿物主要为磁铁矿,含极少量的褐铁矿和黄铁矿;近矿围岩蚀变较弱,主要有石榴子石化、绿帘石化、大理岩化。电子探针研究表明,磁铁矿FeOT含量范围较大,主要分布在85%范围以上,Al_2O_3含量相对较高,TiO_2-Al_2O_3-(MgO+MnO)图解、TiO_2-Al_2O_3-MgO图解均显示热液接触交代成因特点,表明小常山铁矿的形成和岩浆热液的交代作用有关。石榴子石属于钙铝榴石-钙铁榴石系列,与典型矽卡岩矿床的石榴子石端员组分组成有一定差别。结合小常山铁矿体地质特征以及电子探针分析测试等研究,认为小常山铁矿是多成因的复合型矿床,具有岩浆成因和热液成因特征,但后者是主要成因。     

西天山Muruntau金矿床地质和S-Pb同位素示踪

Muruntau金矿床位于乌兹别克斯坦卡拉库姆板块北缘,是世界规模最大的金矿床。赋矿地层为一套发生绿片岩相浅变质作用的含炭复理石建造。矿区主要经历了四期变形变质作用(D1-D4),矿体受构造控制明显,就位于桑格龙套-塔姆德套与穆龙套-道古兹套剪切带的构造交汇部位,金矿化主要产于次级韧脆性断裂中。对矿床的矿石硫化物及地层开展了系统S、Pb同位素研究,结果表明石英脉型及蚀变岩型矿石中硫化物的δ34S变化范围较大,集中于2.2‰~6.1‰,其中蚀变岩型矿石中毒砂样品δ34S值集中于2.2‰~4.6‰,含金石英脉中硫化物样品δ34S值集中于3.0‰~6.1‰,方解石-石英脉中硫化物样品δ34S值集中于3.5‰~4.0‰,表明矿石中硫主要来源于地层,可能有少量岩浆硫加入。2件黑色页岩中毒砂206Pb/~(204)Pb为19.906~20.378,~(207)Pb/~(204)Pb为15.730~15.750,208Pb/~(204)Pb为38.388~39.894;3件含金石英脉中黄铁矿206Pb/~(204)Pb为18.848~19.431,~(207)Pb/~(204)Pb为15.669~15.736,208Pb/~(204)Pb为38.346~38.879;2件方解石脉中毒砂206Pb/~(204)Pb为18.715~19.563,~(207)Pb/~(204)Pb为15.639~15.740,208Pb/~(204)Pb为38.640~39.295。6件地层岩石样品的铅同位素组成206Pb/~(204)Pb为19.416~20.600,~(207)Pb/~(204)Pb为15.675~15.746,208Pb/~(204)Pb为38.876~39.431。矿石铅与地层铅均落于上地壳与造山带之间,矿石铅显示较大的跨度,且与地层岩石铅具有部分重合,显示成矿物质具有双重来源,与赋矿地层及造山期变质流体均表现出密切成因联系。结合矿床地质特征总结分析,沉积地层的物质准备+多期构造运动驱动变质流体运移(D1-D4)+岩浆热液的后期叠加应该是Muruntau巨量金属富集的关键控制因素。     

Metallogenic Mechanism and Tectonic Setting of Tungsten Mineralization in the Yangbishan Deposit in Northeastern China

The Yangbishan iron–tungsten deposit in the Shuangyashan area of Heilongjiang Province is located in the center of the Jiamusi Massif in northeastern China. The rare earth element and trace element compositions of the scheelite show that it formed in a reducing environment and inherited the rare earth element features of the ore-forming fluid. The geochemical characteristics of the gneissic granite associated with the tungsten mineralization show that the magma formed in this reducing environment and originated from the partial melting of metamorphosed shale that contained organic carbon and was enriched with tungsten. In addition, in situ Hf isotopic analysis of zircons from the gneissic granite indicates that they probably originated from the partial melting of a predominantly Paleo–Mesoproterozoic crustal source. According to LA-ICP-MS zircon dating, the Yangbishan orerelated gneissic granite has an Early Paleozoic crystallization age of 520.6 ± 2.8 Ma. This study, together with previous data, indicates that the massifs of northeastern China, including Erguna, Xing'an, Songliao, Jiamusi, and Khanka massifs, belonged to an orogenic belt that existed along the southern margin of the Siberian Craton during the late Pan-African period. The significant continental movements of this orogeny resulted in widespread magmatic activity in northeastern China from 530 Ma to 470 Ma under a tectonic setting that transitioned from compressional syn-collision to extensional postcollision.     

Geochemical and Petrological Studies on the Early Carboniferous Sidingheishan Mafic–Ultramafic Iintrusion in the Southern Margin of the Central Asian Orogenic Belt, NW China

The Sidingheishan mafic-ultramafic intrusion is located in the eastern part of the Northern Tianshan Mountain, along the southern margin of the Central Asian Orogenic Belt in northern Xinjiang autonomous region of China. The Sidingheishan intrusion is mainly composed of wehrlite, olivine websterite, olivine gabbro, gabbro and hornblende gabbro. At least two pulses of magma were involved in the formation of the intrusion. The first pulse of magma produced an olivine-free unit and the second pulse produced an olivine-bearing unit. The magmas intruded the Devonian granites and granodiorites.An age of 351.4±5.8 Ma(Early Carboniferous) for the Sidingheishan intrusion has been determined by U-Pb SHRIMP analysis of zircon grains separated from the olivine gabbro unit. A U-Pb age of 359.2±6.4 Ma from the gabbro unit has been obtained by LA-ICP-MS. Olivine of the Sidingheishan intrusion reaches 82.52 mole% Fo and 1414 ppm Ni. On the basis of olivine-liquid equilibria, it has been calculated that the MgO and FeO included in the parental magma of a wehrlite sample were approximately10.43 wt% and 13.14 wt%, respectively. The Sidingheishan intrusive rocks are characterized by moderate enrichments in Th and Sm, slight enrichments in light REE, and depletions in Nb, Ta, Zr and Hf. The ε_(Nd)(t) values in the rock units vary from +6.70 to +9.64, and initial ~(87)Sr/~(86)Sr ratios range between 0.7035 and0.7042. Initial ~(206)Pb/~(204)Pb, ~(207)Pb/~(204)Pb and ~(208)Pb/~(204)Pb values fall in the ranges of 17.23-17.91,15.45-15.54 and 37.54-38.09 respectively. These characteristics are collectively similar to the Heishan intrusion and the Early Carboniferous subduction related volcanic rocks in the Santanghu Basin, North Tianshan and Beishan area. The low(La/Gd)_(PM) values between 0.26 and 1.77 indicate that the magma of the Sidingheishan intrusion was most likely derived from a depleted spinel-peridotite mantle.(Th/Nb)_(PM)ratios from 0.59 to 20.25 indicate contamination of the parental magma in the upper crust.Crystallization modeling methods suggest that the parental magma of the Sidingheishan intrusion was generated by flush melting of the asthenosphere and subsequently there was about 10 vol%contamination from a granitic melt. This was followed by about 5 vol% assimilation of upper crustal rocks. Thus, the high-Mg basaltic parental magma of Sidingheishan intrusion is interpreted to have formed from partial melting of the asthenosphere during the break-off of a subducted slab.     

内蒙古西乌旗罕乌拉地区下二叠统寿山沟组碎屑锆石LA-ICP-MS U-Pb年龄及其地质意义

中亚造山带南缘二叠纪的构造背景一直存在争议。以内蒙古西乌旗罕乌拉地区发育的寿山沟组为研究对象,开展了野外地质、岩石学、碎屑锆石LA-ICP-MS U-Pb年龄研究。2个样品锆石阴极发光图像和Th/U值指示,锆石为岩浆成因锆石。103颗碎屑锆石年龄测试结果显示,年龄信息可划分为5组:285~328Ma,峰期年龄302Ma;338~361Ma;455~490Ma;757Ma;1278Ma、2380Ma。最年轻的年龄为285Ma,结合侵入其中的花岗岩同位素年龄,指示西乌旗罕乌拉地区寿山沟组沉积时限介于285~280Ma之间,主体沉积时代应为早二叠世Sakmarian期—Artinskian期。寿山沟组碎屑锆石反映出近源、快速沉积的特点,沉积物源中含有较多的火山碎屑物,可能代表弧后盆地沉积,为早二叠世古亚洲洋闭合前洋壳俯冲消减作用的沉积响应。结合区域资料,寿山沟组碎屑锆石的年龄对应于东北地区的变质基底及其后的构造岩浆事件,物源区物质主要来自于苏尼特左旗—锡林浩特—西乌旗一带早石炭世末—晚石炭世岩浆弧及贺根山—东乌旗一带,并进一步限制了华北与西伯利亚两大板块的缝合线应位于寿山沟组发育地区的南部,即索伦缝合带,拼合时代最可能为晚二叠世—早三叠世。     

北山南部敦煌岩群铁矿化磁铁石英岩的变质成因①

北山南部地区敦煌岩群广泛分布着铁矿化磁铁石英岩,这些铁矿化磁铁石英岩沿片岩顺层分布,长度几米到一百多米不等,宽几十厘米到两米左右,浅灰色到肉红色,具强磁性。为了研究这种石英岩的成因,笔者对新疆与甘肃的交界处白山西南侧这套地层的斜长角闪片岩中具有代表性的磁铁石英岩完整采集样品,样品具石英、磁铁矿、白云母、黑云母和绿泥石五种矿物,TFe为12.60%~12.70%。根据野外磁铁石英岩产出地质特征、室内显微镜薄片鉴定结果和电子探针检测各矿物特征,结合化学简项分析和岩石化学分析结果,发现本文研究的磁铁石英岩与国内外BIF(Banded iron formation)型磁铁石英岩不同,不具有沉积特征,可能为单纯变质成因。北山地区敦煌岩群这套古老变质地层可能经历了晚太古代、古元古代两次重要的变质事件,本文研究的铁矿化磁铁石英岩可能是在其中一次变质事件过程中形成的。这套变质地层是铁、铜、金等金属元素富集的含矿地层,具有极其重要的研究意义和找矿意义。     

东昆仑志留纪辉长岩地球化学特征及与铜镍成矿关系探讨

东昆仑造山带新发现的夏日哈木超大型岩浆铜镍矿床、石头坑德大型岩浆铜镍矿床及冰沟南小型岩浆铜镍矿床,其矿体均赋存于橄榄辉石岩内,而辉长岩又是该含矿橄榄辉石岩的直接围岩,并且辉长岩的形成时代相近(夏日哈木辉长岩431Ma、石头坑德辉长岩425Ma、冰沟南辉长岩427Ma),产出位置属于同一大的构造单元,均邻近昆北及昆中断裂。通过对辉长岩的地球化学特征研究,发现明显富集轻稀土元素和明显的Nb-Ta负异常,亏损高场强元素。Sr-Nd同位素研究,表明东昆仑夏日哈木和石头坑德辉长岩岩体的母岩浆来自一个曾经被交代富集的地幔源区,可能揭示了由于从洋壳释放出的流体交代地幔楔的岩石成因。结合区域构造演化和辉长岩形成时代,认为东昆仑夏日哈木和石头坑德辉长岩形成于碰撞后伸展环境。辉长岩岩浆源区性质与赋矿辉石岩存在明显不同,并非同一岩浆活动的产物。辉长岩在东昆仑造山带地区直接充当了含矿辉石岩的直接围岩,与岩浆铜镍硫化物矿体的形成没有关系,富含橄榄石的超镁铁质岩石更有利于形成具有较大经济价值的铜镍矿体。这为指导东昆仑找矿实践和岩浆铜镍矿床成矿理论研究提供了基础。