The heat capacity of two natural chlorite group minerals derived from differential scanning calorimetry

The heat capacity of natural chamosite (X_Fe=0.889) and clinochlore (X_Fe=0.116) were measured by differential scanning calorimetry (DSC). The samples were characterised by X-ray diffraction, microprobe analysis and Mössbauer spectroscopy. DSC measurements between 143 and 623?K were made following the procedure of Bosenick et?al. (1996). The fitted data for natural chamosite (CA) in J?mol^?1?K^?1 give: C _p,CA = 1224.3–10.685?×?10³?×?T ^??0.5???6.4389?× 10⁶?×T ^??2?+?8.0279?×?10⁸?×?T ^??3 and for the natural clinochlore (CE): C _p,CE = 1200.5–10.908?×?10³?×T ^??0.5?? 5.6941?×?10⁶?×?T ^??2?+?7.1166?×?10⁸?×?T ^??3. The corrected C _p-polynomial for pure end-member chamosite (Fe₅Al)[Si₃AlO₁₀](OH)₈ is C _p,CAcor = 1248.3–11.116?× 10³?×?T ^??0.5???5.1623?×?10⁶?×?T ^??2?+?7.1867?×?10⁸×T ^??3 and the corrected C _p-polynomial for pure end-member clinochlore (Mg₅Al)[Si₃AlO₁₀](OH)₈ is C _p,CEcor = 1191.3–10.665?×?10³?×?T ^??0.5???6.5136?×?10⁶?×?T ^??2?+ 7.7206?×?10⁸?×?T ^??3. The corrected C _p-polynomial for clinochlore is in excellent agreement with that in the internally consistent data sets of Berman (1988) and Holland and Powell (1998). The derived C _p-polynomial for chamosite (C _p,CAcor) leads to a 4.4% higher heat capacity, at 300?K, compared to that estimated by Holland and Powell (1998) based on a summation method. The corrected C _p-polynomial (C _p,CAcor) is, however, in excellent agreement with the computed C _p-polynomial given by Saccocia and Seyfried (1993), thus supporting the reliability of Berman and Brown's (1985) estimation method of heat capacities.     

南极菲尔德斯半岛南部近岸水域中粪大肠菌群分布的初步研究

本文采用发酵法对菲尔德斯半岛南部近海水域表层中粪大肠菌群数量进行了初步调查。结果表明 ,在近岸表层海水中 ,粪大肠菌群检出数密度最大的 40个 /升 ,一般是 2 0个 /升 ,密度最小的小于 2 0个 /升 ,后者占多数站位。排污口潮间带 1月份粪大肠菌群检出数 40个 /升 ,3月份 2 80 0个 /升。粪大肠菌群的分布 ,离岸越近数量越高 ,同频繁的人类活动有密切关系。由此看来菲尔德斯半岛南部近岸水体已受生活污水污染 ,尚属轻度污染。但排污口潮间带的污染趋势应引起我们重视     

太行山中北段褶皱构造序列

太行山中北段中－深变质岩区的褶皱构造变形复杂，不同期次间叠加改造强烈，构造置换作用明显，作者采用变质岩区构造解析方法，在观察，测量，分析了大量构造面，线组构的基础上，划分出５期褶皱构造，建立了本区的构造变形序列，并认为构造变形经历了从强塑性变表到韧脆性变形的演化过程，反映出地壳从纵向增厚作用转变为变质核杂岩隆升的演化过程。     

板溪群研究的动向与亟待解决的问题

按多重地层划分原则,板溪群作为雪峰一武陵山区上元古界的一个岩石地层单位,已为多数学者所接受。但80年代以来,许靖华教授提出了中生代板溪蛇绿混杂岩的观点,引起国内外学者的关注。产生分歧的根本原因是对板溪群地层学涵义的认识不一致;当前板溪群研究存在如下亟待解决的问题:1)板溪群地层学涵义的混乱;2)关于板溪地层性质的认识分歧;3)关于板溪群时代归属的不同认识。     

Three-dimensional structure of the crust and upper mantle beneath the south China area from long period surface waves

In the present study the long period surface wave records of 238 wave-paths from 79 earthquakes within China and its adjacent regions received by 30 seismic network stations are measured by using the improved match-filtering frequency-time analysis technique and the grid dispersion inversion method to obtain the rayleigh pure-path dispersion values for 147 slant grids of 4° × 4° in this area, then a three-dimensional shear wave velocity model of the crust and upper mantle beneath south China area to a depth of 170 km is inversed. It is found that there are obvious differences among the main structural units, and there are also certain differences among the subordinate elements even in the individual unit. The crustal thickness of this area is ranging from 30 to 43 km, and is getting thicker gradually from the east to the west. The average shear velocity of crust is ranging form 3.48 to 3.68 km/s with the lowest in the northeast part and highest in the west part. No obvious crustal low velocity layer of large scale is detected. There exist upper mantle low velocity zones in the most of south China area with the starting depth ranging from 75 to 106 km. The lowest shear velocity within the low velocity zones is about 4.28–4.38 km/s. Despite of the existing of upper mantle low velocity zones beneath the most of south China area, the interfaces between the important layers are quite clear, the variation of the bedding surfaces is very gentle, and the lateral changes measured in a larger scale of the underground structure are rather small. It may indicate that the crustal and upper mantle structure of the main part of south China area belongs to the relatively stable structure of the continental blocks except for the fringe areas such as the fold-faulted region in the west part and the fault system along the southeastern coast which may belong to the tectonically active area. The Chinese version of this paper appeared in the Chinese edition ofActa Seismologica Sinica,15, 159–167, 1993. This subject is supported by the National Science Foundation of China.     

地质灾害的非线性数据处理与建模技术

本文简略地介绍了几种地质灾害数据处理与建模的非线性方法,主要包括GMDH自组织建模技术、神经网络方法。GMDH是一种高阶非线性回归建模方法,它是以简单的二元二次回归方程为基础,通过"代复一代"的"生产"过程,客观、自动地求得实际资料的非线性模型。而神经网络则是用工程技术手段模拟生物神经网络的结构特征和功能特征的一类人工系统。与常规统计方法相比,神经网络最突出的优点为它是通过对网络的学习和训练,来掌握变量之间的非线性关系。因此,其处理复杂问题的能力更强大。实例检验效果表明,这些非线性数据处理与建模技术考虑了地质灾害问题的非线性特性,其比基于常规统计理论的数据处理方法的精度要高得多。     

地质公园三维电子地图的设计与实现

结合三维建模和电子地图的基本理论,根据地质公园的特点,利用ERDAS实现大面积区域三维可视化,并结合3DS MAX丰富的建模技术及强大的动画制作功能,在地质景观演化方面做了初步探讨。采用“超地图”的形式来组织各种地图数据以及超媒体相关信息,从内容结构设计及特点进行论述,实现了伊通火山群的三维电子地图,展示出“伊通型火山”的特点。为科研、科普和旅游提供了方便、直观的信息表现形式,拓宽了电子地图的应用领域,同时也丰富了电子地图的研究内容。     

马斯京根法洪水演进反演计算方法的探讨

从计算理论上系统分析和认识了马斯京根法洪水演进反演计算算法产生的坏条件,通过引入样条函数辅助进行修匀处理和对于x数值小的情况采用反演正算的算法,使得马斯京根法洪水演进反演计算可以进行多段连续演算并具有好的效果,在工程水文设计计算中具有实用价值。     

关于上海地区金山群大地构造属性的思考

根据上海地区金山群的岩石组合、原岩及原岩建造、变质作用、构造形变特征,以及已有的同位素年龄值,认为金山群与浙东南陈蔡群基本一致,是华厦古陆块的基底组分。参照华厦古板块与扬子古板岩多期聚合的观点,推断分布在(?)径——川沙断裂南东侧的金山群块断体,是晋宁期末二古板块碰撞对接、于结合带内形成的构造推叠岩片。     

中国大陆及邻区、川滇成组强震活动特征初步研究

将中国大陆及其邻区1902年以来MS≥7地震的成组活动划分出7组,其首发大震分别为1902年阿图什8.2级,1911年阿拉木图8.2级,1920年海原8.5级,1931年富蕴8.0级,1946年缅甸7.8级,1966年邢台7.2级,1988年缅甸7.2级。川滇MS≥6.7地震成组活动划分出5组,其首发强震为1913年峨山7.0级,1933年茂县7.5级,1948年理塘7.3级,1966年东川6.5级、6.2级,1988年澜沧7.4级。其中,川滇MS≥7的首发大震滞后中国大陆首发大震几个月至4年不等。按成组大震的界定,目前中国大陆处于1998~2007年(估计)的大震少发时段。川滇未来1~2年的大震形势为川滇西部存在发生大震的可能性。中国大陆新一轮强震成组活动中的大地震将可能在2007~2009年前后发生,主体危险区可能为天山地震带中段及川滇东部。2007~2008年可能出现5~6级地震的增强过程。巧家—东川一带可能最先发生6级地震。