塔里木盆地寒武-奥陶系烃源岩的分子地球化学特征

对塔里木盆地下古生界样品的地球化学分析表明,上奥陶统良里塔格组、中上奥陶统却尔却克群烃源岩与其他烃源岩具有明显的差异,具有低的C28甾烷、24-降胆甾烷、甲藻甾烷、甲藻三芳甾烷与伽马蜡烷含量以及高的C24四环萜烷、重排甾烷含量等特点。柯坪地区中上奥陶统萨尔干组、印干组页岩伽马蜡烷、C28甾烷相对含量与寒武系、中下奥陶统黑土凹组烃源岩具有相似性。萨尔干组、印干组烃源岩中生物标志物的绝对含量很低。柯坪地区寒武系玉尔吐斯组、中上奥陶统萨尔干组、上奥陶统印干组、满东地区中下奥陶统黑土凹组等较强沉积环境的泥质烃源岩伽马蜡烷、C28甾烷、特殊甾烷的相对含量与海相原油主体有较大差异。上奥陶统印干组烃源岩较高含量的三芳甲藻甾烷、24-降重排胆甾烷和24-降胆甾烷化合物的检出表明,断代生物标志物的提法值得商榷。     

A white mica crystallinity study of the Berwyn Hills, North Wales

Abstract White mica crystallinity studies have been carried out on 90 samples of mudrocks, six of spotted slate, and five of accretionary lapilli tuff from the area around the Berwyn Hills, North Wales. Strain was measured for some of the spotted slate and tuff samples. The metamorphic grade increases from southeast to northwest, with values of the Kübler index varying from 0.64 to 0.20Δ2θ. Metamorphic zonal boundaries follow the strike of bedding and cleavage, but crystallinity values increase into stratigraphically younger rocks on the northwest side of the Berwyn Dome. This effect is attributed mainly to a rapid increase in the thickness of synmetamorphic overburden to the northwest, comprising exposed Silurian turbidites and inferred Lower Devonian non-marine sediments. Strain variations have a more local influence on crystallinity, and lateral variations in the contemporary geothermal gradient cannot be ruled out. However, only with unrealistically high gradients would the need for a thick Lower Devonian component to the overburden be removed. This reasoning implies that the metamorphic peak was coeval with the Acadian (late Caledonian) event, rather than with an early diastathermal event.     

柴达木盆地西南部砂6井第三系沉积相研究

结合前人的研究成果,运用野外地质剖面、测井相标志的研究方法,对柴达木盆地西南第三系沉积相进行了较全面、系统的研究,描述了柴达木盆地砂6井第三系主要发育的三种沉积相及发育的主要类型,指出了研究区内有利于油气生成和储集的沉积相类型。     

Origin of the Mt Ashmore structural dome,west Bonaparte Basin,Timor Sea

New insights into the 3D structure, composition and origin of the Mt Ashmore dome, west Bonaparte Basin, Timor Sea, are enabled by reprocessed seismic-reflection data and by optical microscopic, X-ray diffraction (XRD), scanning electron microscopy (SEM)/energy dispersive spectrometry (EDS) and transmission electron microscopy (TEM) analyses of drill cuttings. The structural dome, located below a major pre-Oligocene post-Late Eocene unconformity and above a ～6 km-deep-seated basement high indicated by marked gravity and magnetic anomalies, displays chaotic deformation at its core and a centripetal kinematic deformation pattern. A study of drill cuttings of Lower Oligocene to Lower Jurassic sedimentary rocks intersected by the Mt Ashmore 1B petroleum-exploration well reveals microbrecciation and extreme comminution and flow-textured fluidisation of altered sedimentary material. The microbreccia is dominated by aggregates of poorly diffracting micrometre to tens of micrometres-scale to sub-millimetre particles, including relic subplanar fractured quartz grains, carbonate, barite, apatite and K-feldspar. A similar assemblage occurs in fragments in basal Oligocene sediments, probably derived from the eroded top section of the dome, which protrudes above the unconformity. SEM coupled with EDS show the micrometre to tens of micrometres-scale particles are characterised by very low totals and non-stoichiometric compositions, including particles dominated by Si, Al–Si, Si–Ca–Al, Si–Al–Ca, Si–Mg, Fe–Mg–Ca, Fe–Mg and carbonate. XRD analysis identifies a high proportion of amorphous poorly diffracting material. TEM indicates internally heterogeneous, fragmented and recrystallised structure of the amorphous grains, which accounts for the low totals in terms of the high-volatile and porous nature of the particles. Another factor for the low totals is the uneven thin-section surfaces which affect the totals. No volcanic material or evaporites were encountered in the drillcore, militating against interpretations of the structure in terms of magmatic intrusion or salt diapirism. Such models are also inconsistent with the strong gravity and magnetic anomalies, which signify a basement high below the dome. An interpretation of the dome in terms of a central rebound uplift of an impact structure can not be proven due to the lack of shock metamorphic effects such as planar deformation features, impact melt or coesite. However, an impact model is consistent with the chaotic structure of the domal core, centripetal sense of deformation, microbrecciation, comminution and fluidisation of the Triassic to Eocene rocks. In this respect, an analogy can be drawn between the Mt Ashmore structural dome and likely but unproven impact structures formed in volatile (H₂O, CO₂)-rich sediments where shock is attenuated by high volatile pressure, such as Upheaval Dome, Utah. In terms of an impact hypothesis the Mt Ashmore dome is contemporaneous with a Late Eocene impact cluster (Popigai: D = 100 km, 35.7 ± 0.2 Ma; Chesapeake Bay: D = 85 km, 35.3 ± 0.1 Ma).     

300 BC-1900 AD无定河流域城镇时空格局演变

通过分析和整理从战国中晚期（约300 BC）至清末（约1900 AD）无定河流域历代县级及以上城址的位置、兴废年代数据,结合行政区划沿革、经济社会发展、政权更迭等资料,分析流域城镇格局的时空演变过程。研究表明：① 受气候周期性波动影响,无定河流域城镇的兴起与衰废具有明显的周期性特征,城镇几何中心的移动轨迹具有明显的“西北—东南”向潮汐性运动特征;② 城址存续年限普遍较短,具有明显的阶段性特征,流域内曾存在过4个阶段性中心城镇,中心城镇移动的方向和过程与城镇几何中心的潮汐性移动过程趋势一致;③ 流域城镇空间格局可分为3种类型,即秦汉与隋唐时期的沿河流谷地分布,宋、明两代的沿边境线与长城分布,以及元、清两代集中于流域下游分布。流域城镇未来的发展布局应重视气候变化对城镇分布的长期影响,关注区域环境的脆弱性,合理安排城镇体系发展规模与布局。     

黑河中上游气象要素单调变化趋势分析

分析水文气象要素的长期变化趋势,对于理解气候变化和人类活动对水文过程的影响起着重要的指导和启示作用。本文采用Mann-Kendall非参数检验方法对黑河中上游分布均匀的8个气象站点5个气象要素的长期变化趋势进行分析。结果表明：各个站点的多年年平均气温、日最高气温及日最低气温均呈现显著的上升趋势;对于多年年降水量序列,只...     

四川盆地西缘地区中侏罗统沙溪庙组地球化学特征及其环境意义

沉积岩的微量元素及稀土元素蕴含了大量的地质信息,它对沉积环境的水文变化有着较高的敏感度,是研究沉积物沉积时的古气候、古环境的有效手段。选取四川盆地西缘地区中侏罗统上、下沙溪庙组的17件样品进行了详细的微量元素及稀土元素的测定,应用了能够敏感反应沉积环境的微量元素指标及特征微量元素、稀土元素比值,对四川盆地西缘地区中侏罗统上、下沙溪庙组沉积时期的古环境、古气候进行了研究。结果表明:研究区上、下沙溪庙组Sr/Ba比值均小于1,说明沙溪庙组沉积期湖水为淡水;V、U、Mo、V/Cr、Ni/Co、U/Th、（Cu+Mo）/Zn、V/（V+Ni）、δCe、δEu、∑REE、La/Yb微量元素及稀土元素特征值及比值,说明整个沙溪庙组沉积时期湖泊底层水体总体上为中等分层的含氧环境;根据Sr/Cu比值及前人研究成果认为下沙溪庙组沉积期整体表现为温暖干旱,局部时期转凉,此后上沙溪庙组沉积期又转变为类似于下沙溪庙沉积期的温暖干旱的气候环境,且干旱程度逐渐加强。     

环境规制能否促进黄河流域要素效能发挥？

黄河流域生态保护与高质量发展已上升为国家战略。作为经济高质量发展的微观基础,在环境约束下要素效能充分发挥就显得至关重要。根据马克思主义政治经济学,要素效能由要素质量与要素效率有机构成,前者是要素效能发挥的必然前提,后者是要素效能发挥的内在要求。基于环境规制影响要素质量与要素效率的作用机理,采用面板固定效应模型与中介效应模型实证分析了2008—2019年黄河流域环境规制对要素效能发挥的影响。结果表明：（1）环境规制通过人口集聚实现要素质量升级,通过产业结构优化促进要素效率提高,并在二者的共同作用下促进要素效能发挥。（2）环境规制与要素质量升级、要素效率提高、要素效能发挥均呈现先抑制后促进的“U型”关系。（3）环境规制对要素效能发挥的促进作用存在经济发展水平与城市规模异质性。在经济发展水平高的地区,环境规制显著促进要素效能发挥;经济发展水平较低或城市规模较小的地区,环境规制先抑制后促进要素效能发挥,二者呈“U”型关系;在城市规模较大的地区,二者关系不显著。研究结果为黄河流域从微观要素层面促进经济高质量发展指明方向,对落实黄河流域生态保护与高质量发展战略具有积极意义。     

云南小中甸盆地湖相沉积记录的最近5 次Heinrich事件

通过对小中甸盆地厚15.3 m的湖相沉积进行系统的粒度、孢粉和地球化学元素分析,结合 ¹⁴C年代测定,发现小中甸盆地在最近40 ka 以来经历了5 次湖泊收缩事件,其形成年代可以同北大西洋的Heinrich 事件H₀-H₄逐一对比,指示西南季风不仅在其水汽源区,而且在其控制的内陆腹地对最近40ka 以来的Heinrich 事件都存在敏感的响应。与在水汽源区所表现不同的是,Heinrich 事件在内陆地区主要表现为干旱。通过与西南季风水汽源地之一的阿拉伯海深海沉积记录和格陵兰冰芯记录进一步对比发现,小中甸盆地仅对千年尺度的Heinrich 冷事件信号敏感而对D/O (Dansgaard-Oescher) 暖事件缺乏明显记录,这与阿拉伯海的响应模式有较大差异。分析周边环流形势认为,冰期青藏高原对西南季风“抽吸”作用的减弱是造成小中甸盆地D/O暖信号记录不明显的重要原因。     

气候变化与人类活动联合影响下东江流域非一致性洪水频率

一致性假设一直是洪水频率分析的基本假设条件,但在气候变化与人类活动综合影响下,水文极值序列的一致性假设受到极大挑战。基于此,以东江流域为例,运用GAMLSS模型(广义可加模型),将时间、气候指标(北极涛动AO、北太平洋涛动NPO、太平洋年代际振荡PDO和南方涛动SOI)以及水库指标(Reservoir Index)统一纳入洪水频率分析中,并对东江流域1954―2009年年最大流量序列(AMS)进行频率分析,结果表明:1)龙川、河源和岭下站年最大流量序列均值与时间呈线性关系,方差为常量,而博罗站均值和方差与时间均呈非线性关系;2)水库对各水文站点AMS均值有显著线性影响;3)NPO对各站点AMS均值有显著线性影响,NPO值较高时,东江流域可能面临着较低的洪水风险,在一致性假设前提下,可能高估洪水设计值,反之亦然;而PDO对各站点方差有显著线性(岭下、博罗)/非线性(龙川、河源)影响;4)以时间为协变量构建非一致性模型,研究得出:龙川、河源和岭下3站T年一遇洪水设计值均呈单调下降趋势,博罗站1954―1995年左右洪水设计值呈下降趋势,而在1996―2009年呈上升趋势;以气候与水库为协变量构建非一致性模型,研究表明:龙川、河源和岭下3站T年一遇洪水设计值均因水库影响呈向下跃变;5)以气候和水库为协变量的非一致性模型对洪水频率具有良好的预测能力,为非一致条件下设计洪水的预测提供了新的预测方法。