Ballast water: A threat to the Amazon Basin

Ballast water exchange (BWE) is the most efficient measure to control the invasion of exotic species from ships. This procedure is being used for merchant ships in national and international voyages. The ballast water (BW) salinity is the main parameter to evaluate the efficacy of the mid-ocean ballast water exchange. The vessels must report to the Port State Control (PSC), via ballast water report (BWR), where and how the mid-ocean BWE was performed. This measure allows the PSC to analyze this information before the ship arrives at the port, and to decide whether or not it should berth.Ship BW reporting forms were collected from the Captaincy of Santana and some ships were visited near the Port of Santana, located in Macapá (Amazon River), to evaluate the BW quality onboard. We evaluated data submitted in these BWR forms and concluded that the BWE efficacy might be compromised, because data contained in these BWR indicate that some ships did not change their BW. We found mistakes in filling the BWR forms and lack of information. Moreover, these ships had discharged BW with high level of salinity, Escherichia coli and total coliforms into the Amazon River. We concluded that the authorities of the Amazon Region need to develop more efficient proceedings to evaluate the ballast water reporting forms and BW quality, as there is potential risk of future invasion of exotic species in Brazilian ports.     

Disinfection by-products and ecotoxicity of ballast water after oxidative treatment – Results and experiences from seven years of full-scale testing of ballast water management systems

Since 2005, five different ballast water management systems (BWMSs) based on chlorination treatment have been tested by Norwegian Institute for Water Research (NIVA) according to guidelines from the International Maritime Organization (IMO). 25% and >50% of all the tested discharge samples exhibited acute and chronic toxic effects on algae, respectively. In most cases this toxicity was plausibly caused by a high free residual oxidant (FRO) level (>0.08 mg Cl/l). Of the 22 disinfection by-products (DBPs) that were identified in treated water at discharge, four compounds were at times found at concentrations that may pose a risk to the local aquatic environment. However, there seemed to be no clear indication that the measured DBP concentrations contributed to the observed algal toxicity. The addition of methylcellulose instead of lignin in the test water to comply with IMO requirements seemed to limit the formation of DBP.     

Particulate organic matter and ballast fluxes measured using time-series and settling velocity sediment traps in the northwestern Mediterranean Sea

Prompted by recent data analyses suggesting that the flux of particulate organic carbon sinking into deep waters is determined by fluxes of mineral ballasts, we undertook a study of the relationships among organic matter (OM), calcium carbonate, opal, lithogenic material, and excess aluminum fluxes as part of the MedFlux project. We measured fluxes of particulate components during Spring and Summer of 2003, and Spring of 2005, using a swimmer-excluding sediment trap design capable of measuring fluxes both in a time-series (TS) mode and in a configuration for obtaining particle settling velocity (SV) profiles. On the basis of these studies, we suggest that distinct OM–ballast associations observed in particles sinking at a depth of 200 m imply that the mechanistic basis of the organic matter–ballast association is set in the upper water column above the Twilight Zone, and that the importance of different ballast types follows the seasonal succession of phytoplankton. As in other studies, carbonate appears to enhance the flux of organic matter over opal. Particles must be at least half organic matter before their settling velocity is affected by ballast concentration. This lack of change in ballast composition with SV in particles with <40% OM content suggests that particle SV reaches a maximum because of the increasing importance of inertial drag. Relative amounts of OM and opal decrease with depth due to decomposition and dissolution; carbonates and lithogenic material contribute about the same amount to total mass, or increase slightly, throughout the water column. The high proportion of excess Al cannot be explained by its incorporation into diatom opal or reverse weathering, so Al is most likely adsorbed to particulate oxides. On shorter time scales, dust appears to increase particle flux through its role in aggregation rather than by nutrient inputs enhancing productivity. We suggest that the role of dust as a catalyst in particle formation may be a central mechanism in flux formation in this region, particularly when zooplankton fecal pellet production is low.     

Settling velocity spectra and the ballast ratio hypothesis

Recently it has been observed that a strong quantitative relationship exists between asymptotic fluxes of particulate organic carbon (POC) to the deep ocean and asymptotic fluxes of “ballast” minerals (opal; calcium carbonate; dust). It has further been suggested that this relationship might provide a mechanistic basis for improved representations of remineralization in ocean carbon models. Since the depth scale of remineralization z* is the ratio k/v of a remineralization rate k and a settling velocity (SV) v, a mechanistic understanding of settling velocities will be crucial in developing such models.Historically, there have been two approaches to estimating the speed with which POC is transported to the deep ocean. First, settling speeds of single particles have been observed directly in both field and laboratory settings; estimates of fecal pellet sinking velocities tend to be higher and more variable than those of aggregates. Second, estimates have been made of the velocity at which temporal patterns in flux propagate between pairs of sediment traps separated in depth (the “benchmark approach”); recent studies have shown these results to be variable and to depend on mineral ballasting. Here we present SV estimates using a relatively new technology: indented rotating sphere (IRS) sediment traps run in settling velocity (SV) mode. In this approach, particles are separated into SV classes during settling to collection cups. In MedFlux, SV data were collected concurrently with time-series (TS) data; the latter were used to construct benchmark estimates for comparison to the SV estimates. From the SV data, the range of modal settling velocities (sinking velocities having the largest time-averaged mass flux densities on a logarithmic scale of SV) in the fast-sinking fraction was estimated to be 287–503 m/d; the average of these modal values is 353 m/d, with standard deviation 76 m/d. In contrast, mean settling velocities of the fast-sinking fraction depend on the range of settling velocity classes included in the estimate. If only SV classes settling at >50 m/d are included, the range of SVs at MedFlux was 214–298 m/d, with average mean value 242 m/d and standard deviation 31 m/d. These mean-velocity results are in excellent agreement with benchmark estimates of signal propagation velocities at Medflux (220±65 m/d); they are also well within the range of other recent benchmark studies. The agreement between the benchmark estimates and mean settling velocity estimates at MedFlux, but not with modal velocities, argues that the benchmark method estimates mean settling velocities.     

Vessel traffic patterns in the Port of Kaohsiung and the management implications for preventing the introduction of non-indigenous aquatic species

Data on shipping traffic in one of the busiest seaports in the world, the Port of Kaohsiung, were analyzed to evaluate the implications for ballast water management. Results show that 67% of the arriving vessels were registered to a flag of convenience, which typically have a lower degree of environmental records. The top five donor countries historically suffer from harmful algal bloom problems. The short journey and busy trading between these countries and Taiwan lead to a higher risk of inoculation. In addition, only 1.4% of all vessels visited more than once every year during the 9-year span, indicating that the port authority encounters many new vessels each year. These findings could influence the design and application of ballast water management strategies as well as highlight the challenges in their implementation. We suggest that an analysis of vessel traffic patterns should be coupled with other useful vessel information to make risk assessment successful.     

DEM analysis of angular ballast breakage under cyclic loading

Railway ballast particles undergo significant amount of breakage under repeated train load. Breakage of ballast particles, especially highly angular fresh ones, causes an increase in settlement, contributing to track degradation. The quantitative analysis of the influence of breakage on the stress-strain properties of ballast can be performed either experimentally or numerically. Numerical modeling has the advantage of simulating ballast breakage subject to various types of loading and different boundary conditions for a range of material properties. In this paper, ballast breakage under cyclic loading is simulated using a 2D discrete element method (DEM) utilizing the software PFC^2D . A new subroutine is developed and incorporated in the PFC^2D analysis to study ballast breakage and to quantify breakage in relation to particle size distribution. The influence of confining pressure on both breakage and permanent deformation is also studied and compared with laboratory observations. The findings of this paper provide an insight into the true ballast behavior under cyclic loading and are expected to assist railway practitioners in developing suitable design criteria for track stability.