Molecular modeling of the 10-Å phase at subduction zone conditions

Molecular dynamics (MD) modeling of the 10-Å phase, Mg₃Si₄O₁₀(OH)₂·xH₂O, with x=2/3, 1.0 and 2.0 shows complex structural changes with pressure, temperature and water content and provides new insight into the structures and stabilization of these phases under subduction zone conditions. The structure(s) of this phase and its role as a reservoir of water in the mantle have been controversial, and these calculations provide specific predictions that can be tested by in situ diffraction studies. At ambient conditions, the computed structures of talc (x=0) and the 10-Å phases with x=2/3 and 1.0 are stable over the 350-ps period of the MD simulations. Under these conditions, the 10-Å phases show phlogopite-like layer stacking in good agreement with previously published structures based on powder X-ray diffraction data for samples quenched from high-pressure and high-temperature experiments. The calculations show that the 10-Å phase with x=2.0 is unstable at ambient conditions. The computed structures at P=5.5 GPa and T=750 K, well within the known stability field of the 10-Å phase, change significantly with water content, reflecting changing H-bonding configurations. For x=2/3, the layer stacking is talc-like, and for x=1.0, it is phlogopite-like. The calculations show that transformation between these two stackings occurs readily, and that the talc-like stacking for the x=2/3 composition is unlikely to be quenchable to ambient conditions. For x=2.0, the layer stacking at P=5.5 GPa and T=750 K is different than any previously proposed structure for a 10-Å phase. In this structure, the neighboring basal oxygens of adjacent magnesium silicate layers are displaced by b/3 (about 3 Å) resulting in the Si atoms of one siloxane sheet being located above the center of the six-member ring across the interlayer. The water molecules are located 1.2 Å above the center of all six-member rings and accept H-bonds from the OH groups located below the rings. The b/3-displaced structure does not readily transform to either the talc-like or phlogopite-like structure, because neither of these stackings can accommodate two water molecules per formula unit. There is likely to be a compositional discontinuity and phase transition between the b/3-displaced phase and the phase with phlogopite-like stacking. The simulations reported here are the first to use the recently developed CLAYFF force field to calculate mineral structures at elevated pressures and temperatures.     

滇西北新生代逆冲推覆构造

滇西北地区新生代逆冲推覆构造较为发育，从西到东可分出走向NS、相互平行的4带：澜沧江带，云岭带，石钟山带和剑川-洱源带。其中，澜沧江带与云岭带组成对冲格局，云岭带又与石钟山带组成反冲格局，石钟山带与剑川-洱源带又组成对冲格局。参与逆冲推覆的地层主要是中生代三叠系、侏罗系、白垩系及新生代云龙组、宝相寺组，推覆体由石炭系、二叠系、上三叠统岩石组成。逆冲推覆时间为喜马拉雅期。     

云南煤层气资源与开发前景

煤层气的开发利用是集开发新的高效洁净能源、有利煤矿生产安全、有利大气环保于一身的崭新的绿色工程。本文概略介绍我省煤层气勘探及研究工作进展情况,强调云南丰富的煤层气资源,应是云南的资源优势。     

会泽超大型铅锌矿床成矿时代研究

云南会泽超大型铅锌矿床由麒麟厂和矿山厂两个独立的铅锌矿床组成。利用两组同源矿物组合Rb Sr等时线方法测定了麒麟厂6号矿体的成矿时代,测定结果分别为(225 1±2 9)Ma和(225 9±3 1)Ma,根据已知的分布于该矿床北部和西南部分布的峨眉山玄武岩成岩时代为250Ma左右,有多个火山喷发旋回,显示多期次的喷发活动,认为川—滇—黔成矿区内铅锌成矿作用与峨眉山玄武岩岩浆活动存在成因联系。     

东吴小筑园林植物应用评价

园林植物配置是园林植物应用的重要内容，对充分发挥园林功能和观赏特性具有重要作用。通过对东吴小筑入口、前庭小院、主景区、山林区、园路、出口等6个功能区园林植物水平配置的现状调查，分析了本景区园林植物的物种多样性、水平结构、垂直结构、色彩变化等特征。结果表明：东吴小筑园林景观营造中．植物配置显示出较高水准。在树种选择、树丛组合、层次搭配、空间组织、色彩表现、季相变化等方面的设计布局十分精细，对今后园林设计及园林绿化水平的提高具有较好的指导作用。     

Studies on wind environment around high buildings in urban areas

High buildings or architectural complex in urban areas remarkably distort the urban surface wind fields. As the air flow approaches,local strong wind may appear around the buildings. The strong wind makes the pedestrians on sidewalks, entrances and terrace very uncomfortable and causes the pedestrian level wind environment problem. In this studies, hot-wire wind measurement, wind scouring in wind tunnel and numerical computation were carried out to evaluate the wind environment of tall buildings in the prevailing flow conditions in Beijing areas. The results obtained by three techniques were compared and mutually verified. The conclusions drawn from three approaches agree with each other. Also the advantages and limitations of each method were analyzed. It is suggested that the combination of different techniques may produce better assessment of wind environment around high buildings.     

Counting Beans: Agrobiodiversity,Indigeneity, and Agrarian Reform

In‐field conservation of locally domesticated crop varieties ameliorates agrobiodiversity losses, but the interaction among nationally regulated socioeconomic factors at the local scale tends to discourage this. Analyses of household surveys conducted in Ecuador demonstrate that state and nongovernmental institutions interact to discourage cultivation of locally domesticated varieties of beans (Phaseolus spp.). Land privatization, agricultural extension, and credit programs favor market production of introduced modern bean varieties, and locally domesticated varieties are noted for favorable nutrition, culinary, and agroecological qualities. Resolving disconnections between the market and social values for landrace beans may provide agrobiodiversity conservation opportunities.     

Analysis of pressuremeter geometry effects in clay using critical state models

The conventional interpretation methods of pressuremeter testing effectively approximate pressuremeter membranes as infinitely long. As a result, the effects of the two‐dimensional geometry of pressuremeters are ignored, leading to an overestimation of soil shear strength by pressuremeter testing, as demonstrated in several previous studies. This paper presents results of a numerical study of two‐dimensional geometry effects on self‐boring pressuremeter tests in undrained clay. The results are obtained using critical state soil models with an effective stress formulation. This is in contrast to most (if not all) existing studies on pressuremeter geometry effects, which were based on perfectly plastic soil models (e.g. Yu (Cavity expansion theory and its application to the analysis of pressuremeters. DPhil Thesis, The University of Oxford, 1990), Yeung and Carter (Proc. 3rd Int. Symp. on Pressuremeters, 1990), and Houlsby and Carter (Géotechnique, 1993; 43 (4):567–576)). The present study suggests that the overestimation of soil strength due to the neglect of finite pressuremeter length is significantly affected by the soil model used in the calculations. It is found that for clays with a high overconsolidation ratio (OCR) the strength overestimation predicted using critical state soil models could be considerably smaller than that predicted using perfectly plastic soil models. The main conclusion of this numerical study is that care must be exercised before directly applying any numerically determined pressuremeter geometry correction factors in practice. Copyright © 2005 John Wiley & Sons, Ltd.     

三江并流世界自然遗产地旅游地质景观成景地质作用初步分析

三江并流世界自然遗产地丰富独特的旅游地质景观是多种地质作用与不同成景岩组交互叠加作用的结果。其发育的地层基础主要为碳酸盐成景岩组、变质岩成景岩组、碎屑岩成景岩组以及岩浆岩成景岩组等,典型内力成景地质作用为板块缝合作用、断裂成景作用、变质成景作用,外力作用则主要有河流、冰川、丹霞、地热、喀斯特作用等。     

云南镍钴矿成矿规律及找矿方向

镍、钴是我国重要的紧缺战略性矿产, 其保障程度对国家稳定和发展具有重要意义。云南省作为有色金属王国, 已发现了镍矿床(点)42处, 钴矿床(点)48处, 查明资源量位于全国前列, 具有较好的镍、钴矿找矿潜力。本文在前人研究工作基础上, 梳理了云南省镍、钴矿床的成因类型、时空分布和成矿作用, 总结成矿规律, 并探讨找矿方向。云南省镍、钴矿床可划分为岩浆型、岩浆热液型、海相火山岩型、受变质型、中-低温热液型和风化型6种矿床类型。镍、钴矿主要集中于扬子陆块及三江造山带, 镍矿床主要形成于印支期及喜马拉雅期, 钴矿床主要形成于喜马拉雅期、晋宁期及印支期。岩浆型和风化型镍、钴矿床与印支期扬子陆块的基性-超基性岩侵入活动关系密切, 中-低温热液型钴矿与喜马拉雅期的构造活动相关, 海相火山岩型和受变质型钴矿则是位于扬子陆块内与晋宁期火山活动相关的昆阳群和大红山岩群中。通过对全省镍、钴矿成矿作用分析和成矿规律总结, 结合潜力评价工作成果, 全省共圈定8处找矿远景区。为云南省新一轮找矿突破战略行动镍、钴矿勘查部署提供思路。