Molecular and isotopic compositions of bitumens in Silurian tar sands from the Tarim Basin,NW China: Characterizing biodegradation and hydrocarbon charging in an old composite basin

Biodegradation and oil mixing in Silurian sandstone reservoirs of the Tarim Basin, one of the largest composite basins in China, were investigated by analyzing the molecular characteristics and stable carbon isotopic signatures of low-molecular-weight (LMW) saturated hydrocarbons and high-molecular-weight (HMW) asphaltenes. Detection of 25-norhopanes and 17-nortricyclic terpanes in most Silurian tar sands from the Tabei Uplift in the Tarim Basin suggests a much greater degree of biodegradation here than in the Tazhong Uplift. This explains the relatively more abundant tricyclic terpanes, gammacerane, pregnane and diasteranes in tar sands from the Tabei Uplift than in those from the Tazhong Uplift. Hence, care must be taken when assigning oil source correlations using biomarkers in tar sands because of the biodegradation and mixing of oils derived from multiple sources in such an old composite basin. Asphaltenes in the tar sands seem to be part of the oil charge before biodegradation, depending on the relative anti-biodegradation characteristics of asphaltenes, the similarity in carbon isotopic signatures for asphaltenes and their pyrolysates, and the consistent product distribution for flash pyrolysis and for regular steranes in asphaltene pyrolysates, regardless of whether the tar sands were charged with fresh oil. According to the relative distributions of regular steranes and the relatively abundant 1,2,3,4-tetramethylbenzene significantly enriched in ¹³C, the oil sources for asphaltenes in the tar sands might be related to lower Paleozoic marine source rocks formed in euxinic conditions. Nevertheless, the relatively low abundance of gammacerane and C₂₈ regular steranes observed in asphaltene pyrolysates and residual hydrocarbons, within limited samples investigated in this work, made a direct correlation of oils originally charged into Silurian tar sands with those Cambrian source rocks, reported so far, seem not to be possible. Comparison of carbon isotopic signatures of n-alkanes in asphaltene pyrolysates with those of LMW saturated hydrocarbons is helpful in determining if the abundant n-alkanes in tar sands are derived from fresh oil charges after biodegradation. The limited carbon isotopic data for n-alkanes in LMW saturated hydrocarbons from the tar sands can be used to classify oils charged after biodegradation in the composite basin into four distinct groups.     

下扬子区下古生界油气有利勘探区带探讨

下扬子区下古生界具有良好的油气地质条件,具备形成大型油气藏的物质基础,但一直未获得油气勘探的突破。本文通过地质、地球物理综合解释,结合部分地质露头、钻井资料及上扬子勘探成果,重点对下扬子区下古生界构造地质特征与油气地质条件等开展了综合分析研究。从构造沉积充填角度将下扬子区分为4个二级构造单元,中部地区的无锡-黄山断隆带构造相对稳定,分析认为其西北部的无锡-黄桥低褶带为油气勘探的有利区带,具有形成下古生界弱改造型油气藏的勘探前景。     

构造-岩浆作用对热液活动的控制机理: 马努斯海盆为例

综述了马努斯海盆热液区构造特征、基底差异, 结合马努斯海盆热液区热液活动与构造-岩浆特征, 探讨了二者的耦合关系, 以及构造-岩浆作用对热液活动的影响和控制。马努斯海盆位于西南太平洋俾斯麦海的东北部, 是世界上扩张速度最快的海盆之一。马努斯海盆西部(马努斯扩张中心, Manus Spreading Center, MSC)主要由海盆扩张成熟期产生的大洋中脊玄武岩组成, 属于成熟弧后扩张中心,发育Vienna Woods热液区; 海盆东部(东南裂谷, Southeast Rift, SER)则是一个拉张裂谷, 处于扩张的早期阶段, 属于不成熟弧后扩张中心, 发育PACMANUS、DESMOS、SuSu Knolls三大热液区。MSC与大洋中脊的热液活动相似, 而SER因受到火山、俯冲作用影响更为显著, 其热液流体具有岩浆流体和俯冲流体的特征。与Vienna Woods热液压相比, PACMANUS、DESMOS以及SuSu Knolls三个热液区的水深相对较浅(1 150～1 740 m), 是地球内部热物质由内向外迁移的结果, 其下部岩浆作用强烈。此外,岩浆脱气作用和数值模拟结果表明, PACMANUS热液系统中具有岩浆流体的输入。与Vienna Woods热液区相比, PACMANUS、DESMOS、SuSu Knolls热液区的热液活动强度及流体组成主要受控于岩浆作用。     

Formation of low permeability reservoirs and gas accumulation process in the Daniudi Gas Field,Northeast Ordos Basin,China

The Daniudi Gas Field is a typical large-scale coal-generated wet gas field located in the northeastern Ordos Basin that contains multiple Upper Paleozoic gas-bearing layers and considerable reserves of gas. Based on integrated analysis of reservoir petrology, carbonate cement C–O isotope, geochemistry of source rocks and HC gas and numerical basin modeling, a comprehensive study focusing on the formation of low permeability reservoirs and gas generation process uncovers a different gas accumulation scene in Daniudi Gas Field. The gas accumulation discovered was controlled by the reservoir permeability reduction and gas generation process, and can be divided into two distinct stages by the low permeability reservoir formation time: before the low permeability reservoir formation, the less matured gas was driven by buoyancy, migrated laterally towards NE and then accumulated in NE favorable traps during Late Triassic to early Early Cretaceous; after the low permeability reservoir formation, highly matured gas was driven by excessive pressure, migrated vertically and accumulated in-situ or near the gas-generating centers during early to late Early Cretaceous. The coupling relationship between reservoir diagenetic evolution and gas generation process controlled on gas accumulation of the Daniudi Gas Field. This study will aid in understanding the gas accumulation process and planning further E&D of the Upper Paleozoic super-imposed gas layers in the whole Ordos Basin and other similar super-imposed low permeability gas layer basins.     

Mesozoic rift to post-rift tectonostratigraphy of the Sverdrup Basin,Canadian Arctic

Jurassic-Cretaceous rift successions and basin geometries of the Sverdrup Basin are reconstructed from a review and integration of stratigraphy, igneous records, outcrop maps, and subsurface data. The rift onset unconformity is in the Lower Jurassic portion of the Heiberg Group (approximately 200–190 Ma). Facies transgress from early syn-rift sandstones of the King Christian Formation to marine mudstones of the Jameson Bay Formation. The syn-rift succession of marine mudstones in the basin centre, Jameson Bay to Deer Bay formations, ranges from Early Jurassic (Pleinsbachian) to Early Cretaceous (Valanginian). Early post-rift deposits of the lower Isachsen Formation are truncated by the sub-Hauterivian unconformity, which is interpreted as a break up unconformity at approximately 135–130 Ma. Cessation of rift subsidence allowed for late post-rift sandstone deposits of the Isachsen Formation to be distributed across the entire basin. Marine deposition to form mudstone of the Christopher Formation throughout the Canadian Arctic Islands and outside of the rift basin records establishment of a broad marine shelf during post-rift thermal subsidence at the start of a passive margin stage. The onset of the High Arctic Large Igneous Province at approximately 130 Ma appears to coincide with the breakup unconformity, and it is quite typical that magma-poor rifted margins have mainly post-rift igneous rocks. We extend the magma-poor characterization where rifting is driven by lithospheric extension, to speculatively consider that the records from Sverdrup Basin are consistent with tectonic models of retro-arc extension and intra-continental rifting that have previously been proposed for the Amerasia Basin under the Arctic Ocean.     

Late Miocene–early Pliocene planktonic foraminifer event-stratigraphy of the Bajo Segura basin: A complete record of the western Mediterranean

The Bajo Segura basin (eastern Betic Cordillera) has one of the most complete late Miocene–early Pliocene marine records of the western Mediterranean. An updated planktonic foraminifer zonal scheme based on recent astronomically tuned biozones is presented for this interval, documenting a complete succession of biostratigraphic markers, from biozone MMi9 (earliest Tortonian) to MPl3 (latest early Pliocene), of likely significance for regional-scale correlation throughout the Mediterranean. The findings reveal a series of intrazonal events (some unreported until now in the Mediterranean Neogene basin), including the particularly interesting two influxes of the Globorotalia miotumida group during the Tortonian. These biostratigraphic findings are the basis for a framework of the major allostratigraphic units in the basin based on planktonic foraminifer event-stratigraphy: synthems Tortonian I, Tortonian II, Tortonian-Messinian I, Messinian II, and Pliocene. In addition, the timing of the main tectono-sedimentary and palaeogeographic events throughout the basin's evolution has been further constrained. Our results suggest that, at least in the Bajo Segura basin, the late-Messinian barren interval (non-distinctive zone) can be considered an ecobiostratigraphic zone (cenozone) characterized by dwarf fauna of planktonic foraminifera. Consequently, the Bajo Segura composite section can be regarded as a biostratigraphic reference section for Neogene basins in the Betic Cordillera and hence also in the Western Mediterranean.     

Organic geochemistry of marine source rocks and pyrobitumen-containing reservoir rocks of the Sichuan Basin and neighbouring areas,SW China

Three bitumen fractions were obtained and systematically analysed for the terpane and sterane composition from 30 Paleozoic source rocks and 64 bitumen-containing reservoir rocks within the Upper Sinian, Lower Cambrian, Lower Silurian, Middle Carboniferous, Upper Permian and Lower Triassic strata in the Sichuan Basin and neighbouring areas, China. These bitumen fractions include extractable oils (bitumen I), oil-bearing fluid inclusions and/or closely associated components with the kerogen or pyrobitumen/mineral matrix, released during kerogen or pyrobitumen isolation and demineralization (bitumen II), and bound compounds within the kerogen or pyrobitumen released by confined pyrolysis (bitumen III). In addition, atomic H/C and O/C ratios and carbon isotopic compositions of kerogen and pyrobitumen from some of the samples were measured. Geochemical results and geological information suggest that: (1) in the Central Sichuan Basin, hydrocarbon gases in reservoirs within the fourth section of the Upper Sinian Dengying Formation were derived from both the Lower Cambrian and Upper Sinian source rocks; and (2) in the Eastern Sichuan Basin, hydrocarbon gases in Middle Carboniferous Huanglong Formation reservoirs were mainly derived from Lower Silurian source rocks, while those in Upper Permian and Lower Triassic reservoirs were mainly derived from both Upper Permian and Lower Silurian marine source rocks. For both the source and reservoir rocks, bitumen III fractions generally show relatively lower maturity near the peak oil generation stage, while the other two bitumen fractions show very high maturities based on terpane and sterane distributions. Tricyclic terpanes evolved from the distribution pattern C₂₀ < C₂₁ < C₂₃, through C₂₀ < C₂₁ > C₂₃, finally to C₂₀ > C₂₁ > C₂₃ during severe thermal stress. The concentration of C₃₀ diahopane in bitumen III (the bound components released from confined pyrolysis) is substantially lower than in the other two bitumen fractions for four terrigenous Upper Permian source rocks, demonstrating that this compound originated from free hopanoid precursors, rather than hopanoids bound to the kerogen.     

Evaluating the mechanical compaction of quartzarenites: The importance of sorting (Llanos foreland basin,Colombia)

Mechanical compaction is the main porosity-reducing process in sandstones, including high-reservoir-quality rigid-grain sandstones. For such sandstones, the extrapolation of theoretical or experimental compaction algorithms needs calibration with rocks having well constrained burial histories. Evaluating the compaction of these rocks is achieved by comparing current intergranular volume (IGV) with depositional IGV, which is strongly dependent on sorting. However, because sandstone sorting is difficult to measure accurately, its impact on depositional porosity and compaction state is largely underestimated. We use the quartzarenites of the Oligocene Carbonera Formation in the subsurface of the hydrostatically-pressured Llanos basin to illustrate the importance of sorting when evaluating the compaction of rigid-grain sandstones. IGV and sorting were measured in core samples using a combination of transmitted-light and cathodoluminescence images, resulting in improved accuracy over standard procedures. The compaction state of clean quartzarenites at given depths is best described using IGV-versus-sorting plots, which are used to derive compaction curves for specified sorting values. The IGV-versus-sorting trends are displaced to lower IGV values with increasing burial depth. The differences in IGV caused by differences in sorting exceed the differences in IGV resulting from 1000 m of burial, illustrating the high impact of sorting when evaluating compaction. Contrasting with published experimental results, the compaction of the Llanos basin ductile-grain-poor quartzarenites is independent of grain size, and grain rearrangement is the main compaction mechanism during the first ∼1.6 km of burial. Based on the Llanos data, we have generated IGV-versus-depth curves for clean pure quartzarenites of specific sorting, which can be used to predict their maximum primary porosity up to moderate burial depths. Differences with other published burial curves are probably related to unaccounted variations in sorting, ductile-grain content and framework-strengthening cements. However, the Llanos basin quartzarenites contain virtually no cements, explaining their high degree of compaction relative to other rigid-grain sandstones, and making them ideal to isolate the effects of compaction on the IGV of quartzarenites. The Llanos basin data suggest that, below ∼2.5 km of depth, clean well- to moderately well sorted quartzarenites continue reducing their IGV by mechanical compaction below the 26% limit, which should apply only to extremely well sorted, rigid grain, uncemented sandstones.     

New style of honeycomb structures revealed on 3D seismic data indicate widespread diagenesis offshore Great South Basin,New Zealand

In the Great South Basin, within the Eocene section, at time-depths around 700–900 ms two way time below the seafloor, unusual features are observed on 3D seismic data closely associated with polygonal faults. The features, referred to as honeycomb structures (HS), cover an area of ∼600 km², are packed circular, oval, to polygonal depressions 150–400 m across in plan view and several to 10 + m in amplitude. Polygonal faults rapidly die out at the Marshall Paraconformity, which is overlain by the Oligocene Penrod Formation. Hence the polygonal faults are inferred to have formed prior to the Marshall Paraconformity, and they cross-cut HS features. Consequently the top of the HS probably formed at burial depths of around 375–500 m, which is their decompacted depth below the paraconformity. The interval containing HS is about 125 m vertical thick. There are several possible origins for the HS. The most probable is related to bulk contraction of the sediment volume accompanied by fluid expulsion, which suggests a diagenetic origin, in particular the opal-A/CT transition. There are actually two polygonal fault systems (PFS) present in the area. The Southern Tier 1 PFS lies laterally to the HS and overlaps with it. The Northern PFS (Tier 2) lies above the HS, appears to be independent of the HS, and formed in the upper 200–300 m of the sediment column. The Tier 1 PFS probably formed by shear failure related to the same diagenetic effects that caused the HS.