伊利石:一种前景广阔的新型粘土矿物材料

伊利石是一种富钾、高铝的层状含水硅酸盐矿物,是近几年来才逐渐受到重视的新型粘土矿物材料。不同品种的伊利石可分别用作陶瓷制品的原材料,造纸用涂布粒等。经改性后的活性伊利石粉可作为橡塑制品的填充料。以优质伊利石为原料制取钾肥,同时还可获得４Ａ沸石、净水剂等多种副产品。伊利石的深层次开发具有广阔的市场前景。     

Oyster patch reefs as indicators of fossil hydrocarbon seeps induced by synsedimentary faults

The Late Jurassic deposits of the Boulonnais area (N-France) represent the proximal lateral-equivalent of the Kimmeridge Clay Formation; they accumulated on a clastic-dominated ramp subject to synsedimentary faulting as a result of the Atlantic Ocean rifting. In the Gris-Nez Cape area, i.e., close to the northern border fault zone of the Jurassic basin, the Late Jurassic sequence contains small-dimensioned oyster patch reefs (<1 m) that are specifically observed at the base of an abrupt deepening trend in the depositional sequence induced by well-defined pulses of normal fault activity. Petrographic analysis of these patch reefs shows that they are exclusively composed of Nanogyra nana embedded in a microsparitic calcite matrix. ™¹³C measurements, carried out within both the matrix and the shells, display significantly lower values in the matrix compared to the oyster shells which suggests that the carbonate matrix precipitation was involving a carbon source different from marine dissolved inorganic carbon, most probably related to sulfate reduction, which is evidenced by light ™³⁴S in pyrites. Similarities but also differences with lucinid-rich bioconstructions, namely, the Late Jurassic pseudo-bioherms of Beauvoisin (SE-France) suggest that the patch reefs developed at hydrocarbon seeps are related to synsedimentary faults. The extensional block-faulting segmentation of the northern margin of the Boulonnais Basin in Late Jurassic times is thus believed to have induced a sort of small-dimension hydrocarbon seepage field, recorded by the patch reef distribution.     

Mineral-forming and diagenetic processes related to Tertiary hydrocarbon seepage at the Bohemian Massif/Outer Western Carpathians interface: Evidence from the Hrabůvka quarry,Moravia, Czech Republic

Ancient hydrocarbon seepage occurred in the Hrabůvka quarry at the boundary between the basement of the Bohemian Massif (represented by folded Lower Carboniferous siliciclastics of the Culm facies) and Tertiary sedimentary cover of the Carpathian Foredeep (formed by Lower Badenian siliciclastics and calcareous clays). The unconsolidated Lower Badenian sediments contain lithified domains composed of limestone and breccias with limestone cement, whereas the basement rocks are cut by subvertical neptunic dykes filled up by limestone and calcite-marcasite-pyrite veinlets representing sealed fluid conduits. The deeply negative δ¹³C values of both vein calcite and limestone (down to −38.1‰ V-PDB) indicate that oxidation of hydrocarbons was the major source of carbon for authigenic mineralization. A fluid inclusion study suggests low fluid temperatures (<50 °C) and low and variable salinities of aqueous fluids associated with hydrocarbons (0.7–6.7 wt. % NaCl eq.). The variability of δ¹⁸O values of authigenic carbonates (−1.7 to −8.2‰ V-PDB) could reflect either slight changes in temperature of escaping fluids (mostly within 15 °C), and/or some mixing with meteoric waters. The low δ³⁴S values of vein marcasite (∼–20‰ V-CDT) are consistent with bacterial reduction of sulfate in the hydrothermal system. Low C₁/(C₂+C₃) ratios in hydrocarbon gas extracted from authigenic carbonates (9.9 and 5.8) as well as the high δ¹³C values of methane (−31.8 and −32.4‰ V-PDB) are compatible with a thermogenic source of hydrocarbons. REE data indicate sequestration of REE from finely dispersed detrital material in the apical part of the hydrothermal system. The available data are compatible with two possible scenarios of fluid origin. The hydrocarbons could have been leached from underlying Paleozoic sedimentary sequence by aqueous fluids that infiltrated into the basement after Tertiary tectonic reactivation. Alternatively, an external source of hydrocarbon-bearing fluids can be found in the adjacent Outer Western Carpathians flysch nappes containing petroleum-producing lithologies. Nevertheless, a regional flow of hydrocarbon-bearing fluids is evidenced by the occurrence of very similar hydrocarbon-bearing vein mineralizations in a wider area.     

New findings on the tectono-metamorphic history of the western Rhenish Massif (Germany) by K–Ar dating of metasedimentary illite

Metapelites, clay-rich sandstones and volcanics from Cambrian, Ordovician and Lower Devonian strata of the western Rhenish Massif underwent a complex regional Variscan tectono-thermal evolution, as shown by mineralogical and K–Ar isotopic analyses of the illite to mica components from three NW-SE transects. The metamorphic degree extended from an anchimetamorphic to an epimetamorphic intensity during two major episodes of illite crystallization at 328 ± 6 and 282 ± 12 Ma. A further late orogenic or post-orogenic extensional activity could also be detected, but not precisely, around 270 Ma, probably recorded by the precipitation of illite in new or reactivated extensional faults with upward moving heat flows.     

Porosity preservation due to grain coating illite/smectite: Evidence from Buchan Formation (Upper Devonian) of the Ardmore Field,UK North Sea

The Buchan Formation sandstone reservoirs from the Ardmore Field in the UK Central North Sea are fluvial-aeolian deposits and provide examples of porosity preservation in deeply-buried reservoirs (2.7–3.2?km) caused by grain-coating illite/smectite (I/S). Here, high reservoir quality commonly correlates with the occurrence of grain-coating I/S and consequent inhibition of quartz cementation in the aeolian dune and interdune sandstones. Porosity is lower in fluvial sandstones lacking grain coating I/S but with intense quartz overgrowths. We propose that the presence of I/S reflects concentration of the smectitic-rich clay bearing water which would have been the deposits of the interdune and/or distal sector of fluvial distributary system, and were introduced into aeolian deposits by mechanical infiltration. Petrographic relationships indicate that these coatings grew mainly before the mechanical compaction as the clays occur at grain contacts. The use of empirical model suggested that about 6–7% porosity have been preserved. The burial-thermal history of the Ardmore area contributed to the high quality reservoir because throughout much of the time since deposition, the Devonian sandstones have been little buried. Only from the Palaeogene the reservoir temperatures exceeded about 70?°C and rapidly buried to today’s maximum depth, which have minimized the negative effect generally ascribed to smectitic clays on reservoir quality. The circumstances of porosity preservation shown in this study may be unusual, but nonetheless have profound consequences for exploration. It is possible to identify new Buchan Formation prospects in areas hitherto dismissed because they were generally assumed to be poor reservoir.     

伊利石结晶度Kübler指数的校正与近变质带的确定

就像用"砝码"标定"称"来测量物质质量一样,伊利石结晶度的测量也需要这样的"砝码"标定它的测量工具——衍射仪,从而能够进行伊利石结晶度的测量和对比。这个砝码就是伊利石结晶度标样或称伊利石结晶度国际标样。第2届Kübler-Frey国际研讨会伊利石结晶度圆桌会议就伊利石结晶度标样和近变质带的确定的问题进行了深入的讨论。会议一致认为,用伊利石结晶度标样校正X射线衍射仪是极为重要和必要的,没有进行标样校正的伊利石结晶度数据将被拒绝发表,经过伊利石结晶度国际标样校正后的伊利石结晶度数据才可用于近变质带的划分和国际对比。本文就伊利石结晶度测量的有关衍射仪类型与差别,衍射仪系统,测量条件,样品的影响和国际标样对仪器的校正等问题进行了分析研究。结果表明不同型号仪器,同型号仪器不同测量条件与状态,样品的不同制备方法都将影响伊利石结晶度Kübler指数的测量。指出只有使用国际标样才可校正测量的伊利石结晶度Kübler指数,从而达到消除偏差准确划分近变质带的标准和进行国际对比的目的。     

Sea-floor sediment distribution in the Gulf of Mexico

Carbonate content, smear-slide analysis and diffuse reflectance spectrophotometry were utilized to determine modern sediment composition and distribution throughout the Gulf of Mexico. In all, 186 core top and grab samples distributed throughout the Gulf were analyzed. Reflectance spectra were taken from thick smear slides from the near ultraviolet, through the visible, and into the near infrared. The first derivatives of the percent reflectance data were subjected to factor analysis producing factors that grouped covarying first-derivative wavelengths. Factors were interpreted by comparison to first-derivative curves for known sediment components and minerals. Interpretation was aided by the mapping of both calcium carbonate content and smear-slide sediment classes. The most easily interpreted factor solution was produced by analyzing only the visible region of the spectrum and extracting seven factors which explained 98% of the cumulative variance. These factors, in order of their relative importance, are interpreted as (1) marl and calcareous clay, (2) glauconite, (3) kaolinite, (4) organic matter, (5) phosphorite, (6) hematite, and (7) goethite. Some factor maps are consistent with known sources of fluvial sediment input; for example, kaolinite is deposited off rivers draining the southeastern US. Other factor maps are related to the origin of the material in the factor, glauconite, for example, being confined to low sedimentation regions of the outer shelf. The most unusual observation concerns the distribution of hematite, which appears to be transported from the rivers of south Texas, primarily the Rio Grande, across the shelf then eastward downslope along the base of the Sigsbee Escarpment. This eastward transport seems to be explainable only by transport in bottom currents flowing along the base of the Sigsbee Escarpment.     

Illite Crystallinity Mapping of Very Low Grade Metamorphism of Triassic Metapelites in the Zoigê Area, Western China

X-ray diffraction methods for estimating the metamorphic grade of diagenetic, anchizone and epizone in metapelites are reviewed and applied to samples from a 7000?m+ borehole in western China and surface samples from the surrounding Zoigê area. Kübler’s illite crystallinity (IC) measurements provide more consistent results than calculated values of percentage of illite in the I/S mixed layers and percentage of I/S mixed layers. Down-borehole IC values display a typical burial metamorphic relationship between stratigraphic level and IC. A method for preparing very low grade metamorphic maps is described, and isograds plotted on a regional geological map at selected values of IC, delineating a high temperature diagenetic zone, an anchizone, and an epizone. The map shows that IC values are controlled by stratigraphic level in the north of the study area (i.e. burial metamorphism), and proximity to an igneous intrusive body in the south (i.e. contact metamorphism).     

Erratum

The Monts de Lacaune belong to the south-eastern (external) part of the French Massif Central. They constitute the lowermost unit in the Albigeois Nappe Pile, which is juxtaposed to the S against the gneiss dome (“Zone Axiale”) of the Montagne Noire. The Monts de Lacaune are composed of Cambrian to Silurian sediments, which show very low-grade metamorphic conditions. A multi-method investigation of phyllosilicates (illite and chlorite crystallinity, b cell dimension, K-Ar dating of fine fractions and electron microprobe analysis) permits to distinguish three metamorphic events: M1 (acquired during early folding and nappe stacking, 342-333 Ma), M2 (caused by the rise of the hot Zone Axiale) and M3 (probably caused by post-Variscan intrusions, Permian). The age range obtained for the nappe stacking is intermediate between deformation ages dated in the northern part of the Albigeois Nappe Pile and in the Southern Palaeozoic Nappes (southern Montagne Noire). This conforms to the classical concept of S-ward propagating tectonic accretion in the French Massif Central with a rate of shortening of c. 1.5 cm/year.     

Methane-derived authigenic carbonates from the Ulleung basin sediments,East Sea of Korea

Authigenic carbonates were sampled in methane-enriched piston core sediments collected from gas venting sites on the western continental slope of the Ulleung Basin, East Sea of Korea. Multidisciplinary investigations on these carbonates, including the scanning electronic microscope (SEM) observations and mineralogical-geochemical compositions, were carried out to identify the carbon and oxygen sources and the forming mechanism of these carbonates. The authigenic carbonates from the study area correspond to semi-consolidated, compact concretions or nodules ranging from 2 to 9 cm in size. X-ray diffraction and electron microprobe analyses showed that most of the sampled carbonate concretions were composed of almost purely authigenic high-Mg calcite (10.7–14.3 mol% MgCO₃). Characteristically, microbial structures such as filaments and rods, which were probably associated with the authigenic minerals, were abundantly observed within the carbonate matrix. The carbonates were strongly depleted in δ¹³C (−33.85‰ to −39.53‰ Peedee Belemnite (PDB)) and were enriched in δ¹⁸O (5.16–5.60‰ PDB), indicating that the primary source of carbon is mainly derived from the anaerobic oxidation of methane. Such methane probably originated from the destabilization of the underlying gas hydrates as strongly supporting from the enriched ¹⁸O levels. Furthermore, the strongly depleted δ¹³C values (−60.7‰ to −61.6‰ PDB) of the sediment void gases demonstrate that the majority of the gas venting at the Ulleung Basin is microbial methane by CO₂ reduction. This study provides another example for the formation mechanism of methane-derived authigenic carbonates associated with gas-hydrate decomposition in gas-seeping pockmark environments.