西琛1井碳酸盐岩的矿物成分、地化特征及地质意义

西沙群岛晚新生代碳酸盐岩是南海形成演化的产物,它的矿物组成、化学成分和Sr同位素组成可以较好地反映其形成时的古海洋环境.西沙群岛西琛1井是南海最深的全取心钻井,揭示3层白云岩和4层石灰岩.其中.白云岩层具有MgO含量高、Sr总量低的特点,同时出现岩盐、赤铁矿和菱锰矿等指相矿物,反映了古海水盐度较高的氧化环境,对应着三个冰期事件;石灰岩层具有MgO含量低、Sr总量高的特点,同时出现菱铁矿和黄铁矿等指相矿物,反映了古海水盐度较低的还原环境,对应着四个间冰期事件.整体上看,西沙群岛晚新生代碳酸盐岩中Sr的总量和87Sr/86Sr自下而上表现为递增趋势,受控于欧亚和印度板块碰撞引起的青藏高原隆升大的构造背景.但又具有明显的分层性,其中,中-上中新统白云岩层Sr含量偏低,而87Sr/86Sr增加趋势明显,与最大一次冰期事件引起的海退和强烈的白云岩化作用有关;上上新统-全新统石灰岩层Sr总量骤增,87Sr/86Sr明显减小,且变化幅度大,与中新世的白云岩化作用和第四纪幔源岩浆强烈喷发有关.     

Source-controlled carbonates in a small Eocene half-graben lake basin (Shulu Sag) in central Hebei Province, North China

Carbonate deposits, which unconformably overlie the Palaeozoic bedrocks, extensively occur in the base of the Tertiary lake succession in the half‐graben Shulu Sag, central Hebei Province, North China. This study focuses on the basal carbonate successions on the hinged western slope. Based on seismic, borehole and core data, nine facies are identified in the carbonate successions, and are further grouped into five facies associations: mid‐proximal alluvial fan, distal alluvial fan, fan fringe, moderately deep lake and deep lake. The first two facies associations constitute alluvial fans formed by debrisflows at the edge of lake and are dominated by mounded‐ to lobate‐shaped, matrix‐ to clast‐supported carbonate rudstones with minor calcretes in the lowermost rudstone units and basinward increase in interfingering with lacustrine carbonate facies. The fan fringe, moderately deep lake and deep lake associations are dominated by pebbly carbonate arenites (or rare carbonate arenites), calcisiltite‐calcilutites, and varve‐like calcilutites, calcareous shales and oil shales, respectively. Widespread occurrences of fine‐grained limestone packages containing varve‐like organic‐rich laminations, minor authigenic glauconite and pyrite, and planktonic and plant fossils suggest a meromictic, anoxic deep lake under a semi‐humid to humid climate, probably with a connection to marine basins. Similarities in lithology and fossil assemblages (e.g. trilobites) of lithoclasts with those of the Mid‐Upper Cambro‐Ordovician bedrock carbonates suggest that the clastic and dissolved carbonate loads were sourced from this Lower Palaeozoic catchment, and shed off the surrounding highlands into the basin. These carbonate facies associations represent the lake lowstand and transgressive deposits of the basal third‐order sequence (Ia) in which the highstand deposits are composed of lacustrine siliciclastics. During the lake lowstand stage (or initiation of basin‐filling) under an intermediate climate, carbonate alluvial fans occurred mostly subaerially at the bottom of the hinged slope with a narrow, shallow lake zone basinwards, and locally were perched within the palaeovalley on the mid‐upper slope. During the transgressive (deepening) stage under a semi‐humid to humid climate, carbonate alluvial fans became smaller in size and episodically stepped backwards upon the slope, with greatly expanded and deepened lake. Nevertheless, the carbonate system was switched to an exclusively siliciclastic system during the highstand stage. The exhumation and erosion of the Mid‐Lower Cambrian bedrock dominated by siliciclastics was probably the cause due to further uplift of the drainage basin. All these facts indicate that the carbonate deposition in the Shulu Sag was mostly controlled by the interactions of tectonics, climate and provenance.     

Authigenic dolomite cementation in the Upper Cretaceous Phosphate Formation, Western Desert, Egypt

The Upper Cretaceous Phosphate Formation in the Western Desert of Egypt displays a characteristic facies association that includes marine phosphorites interbedded with black shales and glauconitic sandstones. The upper part of the formation is characterized by the presence of thin phosphatic beds, which are filled-extensively-with disordered and non stoichiometric (mean MgCO₃ = 41.4 ± 0.34 mol%) authigenic dolomite cement. SEM and the back scattered images of these coarse crystalline dolomite cements reveal that they display planar euhedral crystal boundaries, polymodal crystal size distribution and variable inclusion pattern. The relatively low and wide ranged δ¹⁸O (− 0.87 to − 4.15‰ VPDB) values of the dolomite cements coupled with their depleted Sr (mean = 187 ± 26 ppm) and high iron and manganese values (mean = 6851 ± 554 ppm and 11599 ± 229 ppm respectively) invoke that they were formed from mixed hypo-saline fluids within a mixing marine-meteoric zone probably during a low stand period at the vicinity of the Maastrichtian/Early Tertiary unconformity. Meanwhile, their negative δ¹³C (− 1.31 to − 3.56‰ VPDB) values argue for a possible involvement of isotopically light carbon, derived from degradation of organic matter, during their precipitation.     

Surface carbonate and land-derived clastic marine sediments from southern Chile: mineralogical and geochemical investigation

Surface carbonate and land-derived deposits in the sea off southern Chile were investigated for their mineralogical and geochemical composition. The data were related to environmental features and compared with those of similar temperate and polar carbonate deposits from Tasmania, New Zealand, Arctica, and Antarctica. The mineralogy of the siliciclastic fraction is typical of cold areas and is mainly composed of chlorite, mica, quartz, feldspars and amphibole. The CaCO₃ content varies from 30 to 90%; carbonate mineralogy is made up of low-Mg calcite, high-Mg calcite and minor amounts of aragonite. The Ca, Mg, Sr, Fe, and Mn contents of bulk carbonates and some selected skeletal hard parts are comparable to those of carbonates from Tasmania. The elemental composition is mainly related to carbonate mineralogy, skeletal components, and seawater conditions. The δ¹³C and δ¹⁸O values of carbonates are positive, and their field falls between the “seafloor diagenesis” and “upwelling water” trend lines, because the sediments are likely to be in equilibrium with waters of Antarctic origin. The mineralogical, elemental, and isotopic compositions of carbonates from southern Chile show better similarities with the “temperate” carbonates from Tasmania and New Zealand than with the “polar” carbonates from Arctica and Antarctica. Carbonate deposition is allowed by the low terrigenous input, the low SPM concentration and, probably, the upwelling of seawater from Antarctica.     

Diamond-bearing and diamond-free metacarbonate rocks from Kumdy–Kol in the Kokchetav Massif, northern Kazakhstan

Abstract Dolomite marble from the Kumdy–Kol area of the Kokchetav Massif contains abundant microdiamond, mainly in garnet and a few in diopside. The mineral assemblage at peak metamorphic condition consists of dolomite + diopside + garnet (+ aragonite) ± diamond. Inclusions of very low MgCO₃ calcite and almost pure calcite occur in diopside and are interpreted as aragonite and/or aragonite + dolomite. Single-phase Mg–calcite in diopside with a very high MgCO₃ component (up to 21.7 mol%) was also found in diamond-free dolomitic marble, and is interpreted as a retrograde product from aragonite + dolomite to Mg–calcite. The dolomite stability constrains the maximum pressure (P) at < 7 GPa using previous experimental data, whereas the occurrence of diamond yields the minimum peak pressure–temperature (P–T) condition at 4.2 GPa and 980 °C at X co ₂ = 0.1. The highest MgCO₃ in Mg–calcite constrains the minimum P–T condition higher than 2.5 GPa and 800 °C for the exhumation stage. As these marbles were subjected to nearly identical P–T metamorphic conditions, the appearance of diamond in some carbonate rocks was explained by high X co ₂. A low X co ₂ condition refers to high oxidized conditions and diamond (and/or graphite) becomes unstable. Difference in X co ₂ for marble from the same area suggests local heterogeneity of fluid compositions during ultrahigh-pressure metamorphism.     

Vertical and lateral organization of a carbonate deep-water slope marginal to a submarine fan system, Miocene, southern Turkey

Organization is recognized in the forereef–deep water slope–submarine fan system of the Burdigalian-Langhian Kaplankaya Formation. A basinwards transition from a prograding shelfal reef complex, through forereef talus, deep-water slope and laterally encroaching bypass deep-water clastic system is described, although the deep-water slope makes up the bulk of the succession. Considerable thickness variations occur between the reef and deep-water clastic complexes; these are controlled by sea-floor topography, carbonate foreslope gradient and degree of mass wasting off the platform and foreslope. The vertical and lateral heterogeneity of the Kaplankaya deep-water slope system is described from a number of localities along a 40-km-long and up to 3-km-wide exposed section of the northern margin of the Miocene Adana Basin, a foreland basin setting resulting from thrust sheet loading from the north during the Tauride Orogeny. Detailed field mapping is supplemented with vertical sedimentary logs, photomosaics, palaeontological and petrological data to investigate stratal variation, diagnostic architectural elements, controls on slope progradation, differential timing of basinward encroachment of the reefal complex and lateral onlap of the deep-water clastic system onto the slope. Three-dimensional models are presented showing the vertical and lateral facies associations in different parts of the deep-water slope system, and provide a basis for architectural prediction of geometry and relative position in such environments.     

Reaction‐induced nucleation and growth v. grain coarsening in contact metamorphic,impure carbonates

The understanding of the evolution of microstructures in a metamorphic rock requires insights into the nucleation and growth history of individual grains, as well as the coarsening processes of the entire aggregate. These two processes are compared in impure carbonates from the contact metamorphic aureole of the Adamello pluton (N‐Italy). As a function of increasing distance from the pluton contact, the investigated samples have peak metamorphic temperatures ranging from the stability field of diopside/tremolite down to diagenetic conditions. All samples consist of calcite as the dominant matrix phase, but additionally contain variable amounts of other minerals, the so‐called second phases. These second phases are mostly silicate minerals and can be described in a KCMASHC system (K₂O, CaO, MgO, Al₂O₃, SiO₂, H₂O, CO₂), but with variable K/Mg ratios. The modelled and observed metamorphic evolution of these samples are combined with the quantification of the microstructures, i.e. mean grain sizes and crystal size distributions. Growth of the matrix phase and second phases strongly depends on each other owing to coupled grain coarsening. The matrix phase is controlled by the interparticle distances between the second phases, while the second phases need the matrix grain boundary network for mass transfer processes during both grain coarsening and mineral reactions. Interestingly, similar final mean grain sizes of primary second phase and second phases newly formed by nucleation are observed, although the latter formed later but at higher temperatures. Moreover, different kinetic processes, attributed to different driving forces for growth of the newly nucleated grains in comparison with coarsening processes of the pre‐existing phases, must have been involved. Chemically induced driving forces of grain growth during reactions are orders of magnitudes larger compared to surface energy, allowing new reaction products subjected to fast growth rates to attain similar grain sizes as phases which underwent long‐term grain coarsening. In contrast, observed variations in grain size of the same mineral in samples with a similar T–t history indicate that transport properties depend not only on the growth and coarsening kinetics of the second phases but also on the microstructure of the dominant matrix phase during coupled grain coarsening. Resulting microstructural phenomena such as overgrowth and therefore preservation of former stable minerals by the matrix phase may provide new constraints on the temporal variation of microstructures and provide a unique source for the interpretation of the evolution of metamorphic microstructures.     

中国小克拉通构造分异与古老海相碳酸盐岩油气富集规律

以古生界为主的海相碳酸盐岩是我国陆上油气勘探的重点领域,勘探开发成效显著。随着勘探不断发展,超深层、更古老海相层系油气成藏富集规律的认识面临挑战。本文从古老小克拉通盆地构造分异的角度,剖析油气成藏富集规律。通过对四川、塔里木和鄂尔多斯等克拉通盆地演化过程中的构造分异作用研究,认为克拉通盆地构造分异对沉积、成储与成藏组合有显著的控制作用。构造分异控制的三类油气聚集带是未来超深层海相碳酸盐岩油气勘探的重点领域。     

Oyster patch reefs as indicators of fossil hydrocarbon seeps induced by synsedimentary faults

The Late Jurassic deposits of the Boulonnais area (N-France) represent the proximal lateral-equivalent of the Kimmeridge Clay Formation; they accumulated on a clastic-dominated ramp subject to synsedimentary faulting as a result of the Atlantic Ocean rifting. In the Gris-Nez Cape area, i.e., close to the northern border fault zone of the Jurassic basin, the Late Jurassic sequence contains small-dimensioned oyster patch reefs (<1 m) that are specifically observed at the base of an abrupt deepening trend in the depositional sequence induced by well-defined pulses of normal fault activity. Petrographic analysis of these patch reefs shows that they are exclusively composed of Nanogyra nana embedded in a microsparitic calcite matrix. ™¹³C measurements, carried out within both the matrix and the shells, display significantly lower values in the matrix compared to the oyster shells which suggests that the carbonate matrix precipitation was involving a carbon source different from marine dissolved inorganic carbon, most probably related to sulfate reduction, which is evidenced by light ™³⁴S in pyrites. Similarities but also differences with lucinid-rich bioconstructions, namely, the Late Jurassic pseudo-bioherms of Beauvoisin (SE-France) suggest that the patch reefs developed at hydrocarbon seeps are related to synsedimentary faults. The extensional block-faulting segmentation of the northern margin of the Boulonnais Basin in Late Jurassic times is thus believed to have induced a sort of small-dimension hydrocarbon seepage field, recorded by the patch reef distribution.