CO_2-H_2O流体不混溶对Au溶解度的影响——以贵州省贞丰县水银洞金矿床为例

运用热力学原理和方法,研究了CO2-H2O流体不混溶作用对Au的溶解度的影响。结果表明,贵州水银洞金矿床的成矿流体是一种富含挥发分（fCO2=70.79MPa）、酸性（pH=3.71）、还原性（fO2=0.50×10-36MPa）、中温（267℃）、具有超压（180MPa）性质的含Au（a∑Au=3.744×10-8mol/L）流体。当超压流体的封闭层——炭质页岩因断裂作用而被破坏时,热液体系的压力发生骤降（28.50～35.30MPa）,CO2-H2O流体发生不混溶作用,并有大量CO2溢出。CO2的流失可使成矿溶液的CO2逸度和O2逸度降低（fCO2=0.80MPa、fO2=2.512×10-42MPa）,酸碱度升高（pH=4.32）,同时伴随温度的下降（224℃）,成矿热液中Au溶解度的降低（a∑Au=3.790×10-9mol/L）,从而快速沉淀下来成矿。     

浅谈三因素方差分析在评价化探数据质量中的应用——以盐源县马思罗金矿土壤化探分析数据为例

三因素方差分析是对分析数据质量合格与否的一种有效检验方法.它可以对元素的自然变化,采样、重复分析的系统误差,偶然误差等进行定量的评价.应用以三因素方差分析基本原理为基础,运用盐源县马思罗金矿土壤化探分析数据为实例,查证了分析数据的可靠性,为正确的指导化探找矿、加速矿权评价奠定了基础.     

云南沧源羊缅金矿成因

羊缅金矿位于昌宁-孟连有色金属贵金属成矿带,金矿受压扭性断裂控制,分布于变余辉长辉绿岩中,典型的低温热液蚀变型金矿床。     

安徽铜陵地区含金硫化物矿床成矿作用

铜陵地区位于华中地洼区,苏鄂地洼系。具工业价值的金矿床多赋存于地洼期次一级构造以及它们的交汇处,这是本区构造控矿的特点。近矿围岩以地台型碳酸盐岩为主,矿体明显受地层层位控制。与矿化有关的侵入岩,主要形成于地洼期(燕山早、中期)。岩体形成后叠加了成矿热液的多次活动。金的成矿作用及金矿床的形成,通常与含金丰度相对较高的地台构造层有密切的成因联系,它们提供了重要的物质来源,可认为是矿源层(Source beds)。本区各主要矿床是以地洼型岩浆期后热液作用为主的多因复成层控含金硫化物矿床。     

云南鹤庆炉坪金多金属矿床地质特征及成因分析

矿床成矿物质源于斑岩及斑岩期后的岩浆热液,经内生成矿阶段的原生富集作用和表生成矿阶段的富集作用,逐步在相对有利的地质和地球化学环境构造部位富集成矿,属斑岩型中低温外接触带沿层破碎带型原生及氧化Fe-Au多金属矿床。     

东川播卡金矿品位统计学特征及与矿化的关系

东川播卡金矿,位于金沙江与小江夹持的三角成矿带上,为昆阳群中迄今发现的唯一独立大型金矿。矿区出露中元古界昆阳群浅变质岩系。结合近年来勘探成果,收集矿石品位进行统计学研究,探讨品位与矿化关系。     

Chemical composition of rock-forming minerals in granitoids associated with Au–Bi–Cu,Cu–Mo,and Au–Ag mineralization at the Freegold Mountain,Yukon, Canada: magmatic and hydrothermal fluid chemistry and petrogenetic implications

The chemical compositions of rock-forming minerals have been determined for both altered and least-altered igneous rocks spatially associated with numerous mineralized zones (Nucleus Au–Bi–Cu–As deposit, Revenue Au ± Cu and Stoddart Cu–Mo ± W mineral occurrences, and Laforma Au–Ag deposit) across the Freegold Mountain area, Yukon, Canada. Within the study area, K-feldspar has a narrow compositional range (89.4–91% Or), whereas plagioclase spans a wide range (4.4–70.07% An). In all of the investigated samples, T _Ab = T _An = T _Or, suggesting that magmatic equilibrium between the coexisting plagioclase and K-feldspar was maintained. Igneous amphibole phenocrysts from hypabyssal dikes are typically calcic, whereas the Stoddart Cu–Mo ± W, Laforma Au–Ag, and Goldy Au mineralization are associated with Mg-enriched primary amphibole of edenite composition, and Au–Bi–Cu–As mineralization from Nucleus is related to Al-enriched primary amphibole of ferropargasite composition. Primary biotite phenocrysts across the Freegold Mountain area re-equilibrated with oxidized magma (f(O₂) values between 10–13 and 10–11.5 bars, lying between the Ni/NiO and the magnetite/haematite buffers). However, biotite and amphibole phenocrysts from Stoddart, Goldy, Laforma, and the Highway zones crystallized from a more oxidized magma, as indicated by their elevated X _Mg up to 0.65, relative to biotite and hornblende from Nucleus and Revenue characterized by a lower X _Mg (typically < 0.50). This suggests that various sources and (or) rapid emplacement were involved in magma genesis, as further supported by the considerable variation of pressure (1.8–7.3 kb) of amphibole crystallization and of the total Al content in least-altered biotite (2.6–2.9 afu) within the Freegold Mountain area. Biotite and apatite equilibrated within the T range of 520–780°C, consistent with temperatures of equilibration between ilmenite and magnetite, and their compositions indicate that they formed from an oxidized I-type magma. Magma differentiated by fractional crystallization (indicated by the presence of normally zoned plagioclase with Ca-rich cores and Na-enriched outer rims) and multiple magma mixing (supported by the presence of reversed zoned plagioclase and coexistence of normally and reversely zoned plagioclase). Lower X _Mg biotite associated with the mineralized (Cu–Mo ± W) potassic alteration incorporated more F and Cl relative to least-altered biotite with higher X _Mg. In both Nucleus and Revenue Au–Cu mineralizations, secondary biotite composition varies with respect to the associated alteration mineral assemblages. Although secondary biotite in the skarn re-equilibrated with F-poor fluids, secondary biotite from the pervasive biotitization is related to F- and Cl-enriched fluids, and secondary biotite from the phyllitic zone is related to F-, Cl-, and Mg-depleted fluids, thus consistent with a change in mineralizing fluid composition during mineralization.     

Adsorption of Au(III) and Au(I) complexes on δ-MnO2

The sorption of AuCl₄ ⁻,AuCl₂ ⁻ and Au(S₂O₃)^3- on δ-MnO₂ was investigated at pH2–11.6, 0.01 mol/L and 0.1 mol/L NaNO₃ solutions. At pH 4 in two electrolyte strength solutions, Au sorption densities on δ-MnO₂ are 0.18–0.21 and 0.28μmoL/m² for AuCl₄ ⁻ and Au(S₂O₃)₂ ^3-, respectively, and the Au surface coverage is approximate to or lower than 1%. This adsorption of the two Au complexes decreases as the solution pH increases, which conforms to the sorption regularity of the anion on δ-MnO₂. The Au sorption decreases in the sequence of Au(S₂O₃)₂ ^3- >AuCl₄ ⁻ >AuC1₂ ⁻. The intrinsic equilibrium constants (logK ^int) of the three Au complexes are 1.17–2.7, much higher than those of Cu and Cd. The hydrolysis products of AuCl₄ ^- are preferentially adsorbed by δ-MnO₂ and the inner-sphere Au-surface complexes are formed on the surface. Project supported by the National Studying-abroad Foundation, the National Natural Science Foundation of China (Grant No. 49573200) and the Australian Mining Industry.     

安徽池州铜山铜矿深部找矿实践与启示

铜山铜矿资源储量日益枯竭。危机矿山接替资源勘查中,采用地质、物探综合手段圈定异常区,经深部钻探验证,取得突破。     

四川西昌菜子地金矿床的地质特征及资源前景

通过对该区成矿地质背景、矿床地质特征的分析和阐述,总结了其成矿条件及富集规律,研究表明该矿区具有广阔的资源前景。