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简述了瑞士ARL 9400型X荧光光谱仪探测器高压部分的故障现象、分析与处理及维修方法,并给出了维修实例。 相似文献
23.
应用AFS 820型双道原子荧光仪测定芦荟中砷和硒,方法检出限分别为As0.51μg/L;Se0.42μg/L。经国家一级植物标准物质分析验证,结果与标准值相符。5次测定相对标准偏差As<2.3%;Se<3.1%。 相似文献
24.
原子荧光光谱法测定化探样品时有机质对As,Sb,Bi的干扰 总被引:1,自引:0,他引:1
通过研究黑龙江省森林沼泽景观区有机水系沉积物(泥炭)、土壤中As,Sb,Bi的测定结果,发现样品中的有机质对王水消解氢化物原子荧光法测定上述元素存在极大的干扰,提出采用低温(<450℃)灰化处理可完全消除干扰。对比研究还发现,过去森林沼泽景观区的区域化探扫面资料中的As,Sb,Bi数据存在问题,应专门对其进行评价研究。 相似文献
25.
Advances in energy-dispersive X-ray fluorescence 总被引:1,自引:0,他引:1
Utz Kramar 《Journal of Geochemical Exploration》1997,58(1):73-80
Recently, two new instruments for X-ray fluorescence analysis (XRF) with interesting features for geochemical applications came to the market. Both instruments were designed to improve the peak to background ratio, the principal factor limiting the sensitivity of XRF. Total reflection XRF (TXRF) was designed to analyse extremely small sample amounts. An instrument, using polarised X-rays (P-XRF) for excitation, is designed to reduce scattered background in spectra of bulk samples. The performance of both instruments was compared with conventional XRF-methods and ICP/MS. Results for GXR-1, GXR-2, GXR-3, GXR-4 and GXR-6 obtained with TXRF and P-XRF are in good agreement with literature data. The effective amount of sample, analysed by TXRF was 200 μg only and detection limits of ~ l μg/g were achieved. P-XRF shows considerable improved detection limits (0.25–0.5 μg/g) for bulk samples for elements with atomic numbers 42–51 (Mo-Sb) compared with conventional XRF-methods. 相似文献
26.
The annual and semi-annual variations of the ionosphere are investigated in the present paper by using the daytime F2 layer peak electron concentration (NmF2) observed at a global ionosonde network with 104 stations. The main features are outlined as follows. (1) The annual variations are most pronounced at magnetic latitudes of 40–60° in both hemispheres, and usually manifest as winter anomalies; Below magnetic latitude of 40° as well as in the tropical region they are much weaker and winter anomalies that are not obvious. (2) The semi-annual variations, which are usually peak in March or April in most regions, are generally weak in the near-pole regions and strong in the far-pole regions of both hemispheres. (3) Compared with their annual components, the semi-annual variations in the tropical region are more significant.In order to explain the above results, we particularly analyze the global atomic/molecular ratio of [O/N2] at the F2 layer peak height by the MSIS90 model. The results show that the annual variation of [O/N2] is closely related with that of NmF2 prevailing in mid-latitudes and [O/N2] annual variation usually may lead to the winter anomalies of NmF2 occurring in the near-pole region. Moreover, NmF2 semi-annual variations appearing in the tropical region also have a close relationship with the variation of [O/N2]. On the other hand, the semi-annual variations of NmF2 in the far-pole region cannot be simply explained by that of [O/N2], but the variation of the solar zenith angle may also have a significant contribution. 相似文献
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石墨炉原子吸收分光光度法测定土壤样品中痕量镉 总被引:2,自引:0,他引:2
研究了土壤样品中痕量镉的石墨炉原子吸收分光光度法测定最佳条件以及磷酸二氢铵与硝酸镁作基体改进剂对测定镉的基体改进效应,并比较了两种试样分解体系。方法检出限为0.01pg/L,精密度(RSD,n=8)为3.29%-7.69%,经国家一级标准物质分析验证,结果与标准值符合。 相似文献
29.
Yin Xiulan China Institute of Geo-environmental Monitoring Beijing China Hu Ping Faculty of Earth Sciences China University of Geosciences Wuhan China Northeastern Illinois University Chicago IL USA Li Dien Division of Earth Environmental Sciences Los Alamos National Laboratory Los Alamos NM USA 《中国地质大学学报(英文版)》2004,15(4):355-360
The sorption of Eu species onto nano-size silica-water interfaces was investigated using fluorescence spectroscopy for Ph ranges of 1-8.5 and an initial Eu concentration (Ceu) of 2×10-4 M. The sorption rate of Eu was initially low, but significantly increased at Ph>4. The sorption density of Eu species on a silica surface was ~1.58×10-7 mol/m2 when the dissolved Eu species were completely sorbed onto silica-water interfaces at Ph=~5.8. The sorbed Eu species at Ph<6 is aquo Eu3 , which is sorbed onto silica-water interfaces as an outer-sphere complex at Ph<5, but may be sorbed as an inner-sphere bidentate complex at 5相似文献
30.
HU Ping YIN Xiulan ZHAO Linghu & LI Dien . Department of Earth Sciences China University of Geosciences Wuhan China . Northeastern Illinois University Chicago IL USA . China Institute of Geo-Environmental Monitoring Beijing China . Division of Chemistry Los Alamos National Laboratory Los Alamos NM USA 《中国科学D辑(英文版)》2005,48(11)
A large amount of nuclear wastes has been pro-duced due to nuclear weapon development and nuclear electricity generation. One possible resolution for the disposal of the nuclear wastes is to seal them in an underground repository, which requires detailed knowledge on the mobility, chemical behavior and immobilization of radionuclides in underground water. In addition, toxic heavy metals are extensively present in ground and underground water, how to immobilize and remedy these toxic heavy meta… 相似文献