Employment mobility in high-technology agglomerations: the cases of Oxfordshire and Cambridgeshire

This paper examines labour market behaviour of the highly skilled in high-tech local economies, taking the UK examples of Oxfordshire and Cambridgeshire as case studies. It reports on data from a survey of members of three scientific institutes to compare rates of employee mobility in the two locations and considers the likely explanations and implications of those patterns.     

Element mobility during pyrite weathering: implications for acid and heavy metal pollution at mining-impacted sites

Based on back scattered electron images and electron micro-probe analysis results, four alteration layers, including a transition layer, a reticulated ferric oxide layer, a nubby ferric oxide layer and a cellular ferric oxide layer, were identified in the naturally weathering products of pyrite. These layers represent a progressive alteration sequence of pyrite under weathering conditions. The cellular ferric oxide layer correlates with the strongest weathering phase and results from the dissolution of nubby ferric oxide by acidic porewater. Leaching coefficient was introduced to better express the response of element mobility to the degree of pyrite weathering. Its variation shows that the mobility of S, Co and Bi is stronger than As, Cu and Zn. Sulfur in pyrite is oxidized to sulfuric acid and sulfate that are basically released into to porewater, and heavy metals Co and Bi are evidently released by acid dissolution. As, Cu and Zn are enriched in ferric oxide by adsorption and by co-precipitation, but they would re-release to the environment via desorption or dissolution when porewater pH becomes low enough. Consequently, Co, Bi, As, Cu and Zn may pose a substantial impact on water quality. Considering that metal mobility and its concentration in mine waste are two important factors influencing heavy metal pollution at mining-impacted sites, Bi and Co are more important pollutants in this case.     

智能卡和出租车轨迹数据中蕴含城市人群活动模式的差异性分析

当前采用交通流数据量化城市人群活动模式研究已经取得了丰硕的研究成果,但是对于同一区域、同一时段不同类型交通流数据反映城市人群活动模式的共性与差异性仍然知之甚少,直接影响了城市人群活动模式挖掘结果的可解释性与实际应用效果。为此,本文旨在对目前广泛采用的智能卡数据（公交和地铁刷卡）和出租车轨迹数据2种重要的交通流数据,从时空分布模式的差异性、行程距离及距离衰减效应的差异性、空间社团结构的差异性3个方面,探索二者反映城市人群活动模式的差异性：① 采用北京市六环以内区域2016年5月9日至15日的智能卡和出租车轨迹数据进行实验分析,研究发现：① 2种交通流反映出行需求的空间分布呈现出高度相关性,但是在同一空间单元上,2种交通流反映出行需求的时间相关性较低;② 2种交通流的使用率在不同空间位置存在明显差异,仅在城市中心区域使用率较为均衡;③ 2种交通流反映人群行程距离的空间分布、距离衰减效应存在明显差异,公共交通对于促进长距离出行更为重要;④ 从2种交通流发现的空间社团结构都显示了城市的多中心结构特征,但是二者发现社团结构存在的差异性表明两种交通方式对城市空间交互起着不同的作用。本研究有助于深入理解多源交通流反映城市人群活动的内在机理,提升城市人群活动模式在城市规划、交通管理等领域的应用效果。     

Insights into the complexity of crustal differentiation: K2O‐poor leucosomes within metasedimentary migmatites from the Southern Marginal Zone of the Limpopo Belt,South Africa

Differentiation of the continental crust is the result of complex interactions between a large number of processes, which govern partial melting of the deep crust, magma formation and segregation, and magma ascent to significantly higher crustal levels. The anatectic metasedimentary rocks exposed in the Southern Marginal Zone of the Limpopo Belt represent an unusually well‐exposed natural laboratory where the portion of these processes that operate in the deep crust can be directly investigated in the field. The formation of these migmatites occurred via absent incongruent melting reactions involving biotite, which produced cm‐ to m‐scale, K₂O‐poor garnet‐bearing stromatic leucosomes, with high Ca/Na ratios relative to their source rocks. Field investigation combined with geochemical analyses, and phase equilibrium modelling designed to investigate some aspects of disequilibrium partial melting show that the outcrop features and compositions of the leucosomes suggest several steps in their evolution: (1) Melting of a portion of the source, with restricted plagioclase availability due to kinetic controls, to produce a magma (melt + entrained peritectic minerals in variable proportions relative to melt); (2) Segregation of the magma at near peak metamorphic conditions into melt accumulation sites (MAS), also known as future leucosome; (3a) Re‐equilibration of the magma with a portion of the bounding mafic residuum via chemical diffusion (H₂O, K₂O), which triggers the co‐precipitation of quartz and plagioclase in the MAS; (3b) Extraction of melt‐dominated magma to higher crustal levels, leaving peritectic minerals entrained from the site of the melting reaction, and the minerals precipitated in the MASs to form the leucosome in the source. The key mechanism controlling this behaviour is the kinetically induced restriction of the amount of plagioclase available to the melting reaction. This results in elevated melt H₂O and K₂O and chemical potential gradient for these components across the leucosome/mafic residuum contact. The combination of all of these processes accurately explains the composition of the K₂O‐poor leucosomes. These findings have important implications for our understanding of melt segregation in the lower crust and minimum melt residency time which, according to the chemical modelling, is <5 years. We demonstrate that in some migmatitic granulites, the leucosomes constitute a type of felsic refractory residuum, rather than evidence of failed magma extraction. This provides a new insight into the ways that source heterogeneity may control anatexis.     

Industrial and geographical mobility of workers during industry decline: The Swedish and German shipbuilding industries 1970–2000

This article follows the industry employment histories of all individuals who at some point have been affiliated with the declining German or the dismantling Swedish shipbuilding industry during 1970–2000. We analyse the situation of the individual workers leaving shipbuilding, investigating the extent to which they were employed at all, tended to move to related sectors within or outside the region, and whether such moves were beneficial for the individuals. Combining insights from labour geography and redundancy studies with evolutionary economic geography, we find remarkably similar results for the West German and Swedish cases. Our findings indicate a notable impact of the regional industry structure on the labour market outcomes for workers leaving shipbuilding. This suggests that more attention should be devoted to the specific structures of the absorptive capacity of regional labour markets. The findings are discussed within the context of a mature industry.     

Estimating attendance from cellular network data

An automatic estimate of the number of attendees to events happening in the city can provide valuable information to geographic information systems and geo-located applications. We present a methodology to estimate the number of events’ attendees from cellular network data. In this work, we used anonymized Call Detail Records (CDRs) comprising data on where and when users access the cellular network. Our approach is based on two key ideas: (1) we identify the network cells associated with the event location. (2) We verify the attendance of each user, as a measure of whether (s)he generates CDRs during the event, but not during other times. We evaluate our approach to estimate the number of attendees to a number of events ranging from football matches in stadiums to concerts and festivals in open squares. Comparing our results with the best groundtruth data available, our estimates provide a median error of less than 15% of the actual number of attendees.     

Youth Mobility and Territorial Disparities: An Analysis of Urban and Rural Barcelona

Travel behavior of the present generation of youths is being increasingly explored due to their relevance in shaping future accessibility needs and mobility habits. The present study offers an original perspective on this topic by identifying territorial disparities that emerge in youth mobility patterns in rural and urban areas. Unlike most previous research, we propose taking a global view on mobility by analyzing all trip purposes and transportation modes. This is conducted by analyzing a comprehensive mobility survey in the Barcelona Metropolitan Region, which provides data on mobility engagement, trip purposes, modal split, travel times and territorial differences. In general, youngsters account for larger daily travel times than older adults, present a higher attachment to public transportation and walk less on a daily basis. These differences are enhanced in rural territories, where while older adults overcome accessibility issues with higher use of the private vehicle, youngsters are more likely to invest larger travel times on transit.     

A high-precision heuristic model to detect home and work locations from smart card data

Smart card-automated fare collection systems now routinely record large volumes of data comprising the origins and destinations of travelers. Processing and analyzing these data open new opportunities in urban modeling and travel behavior research. This study seeks to develop an accurate framework for the study of urban mobility from smart card data by developing a heuristic primary location model to identify the home and work locations. The model uses journey counts as an indicator of usage regularity, visit-frequency to identify activity locations for regular commuters, and stay-time for the classification of work and home locations and activities. London is taken as a case study, and the model results were validated against survey data from the London Travel Demand Survey and volunteer survey. Results demonstrate that the proposed model is able to detect meaningful home and work places with high precision. This study offers a new and cost-effective approach to travel behavior and demand research.     

赣中周潭群变质脉体的微量元素及氧同位素地球化学研究

笔者等对周潭群沉积变质岩及其中脉体的微量元素、氧同位素地球化学进行了研究,结果表明,变质石英脉继承了其围岩的稀土元素及氧同位素地球化学特征,表明形成石英脉的流体来源于围岩;脉体的微量元素对Zr-Hf、U-Th、Nb-Ta和Y-Ho与变质岩有一定的差异,且有一定的分异,指示脉体是流体作用的产物。变质流体通过侧向扩散作用形成了周潭群变沉积岩中的变质脉体。     

Mineralogical and Geochemical Constraints on Arsenic Mobility in a Philippine Geothermal Field

Arsenic is usually associated with sulphide minerals formed in the geothermal environment. However, sulphide minerals are prone to dissolution after contact with meteoric water under surface oxidizing conditions. Secondary precipitates that form from the dissolution of the primary sulfides exert a greater influence on arsenic mobility in the geothermal environment. Fe-hydroxides have very good affinity with dissolved arsenate and are stable under most surface oxidizing conditions. Both amorphous silica directly precipitated from geothermal fluids and possibly a kaolinite alteration can host a small significant amount of arsenic. These silicates are also more stable under a wide range of pH and redox conditions.