原子荧光光谱法测定化探样品时有机质对As,Sb,Bi的干扰

通过研究黑龙江省森林沼泽景观区有机水系沉积物（泥炭）、土壤中As,Sb,Bi的测定结果，发现样品中的有机质对王水消解氢化物原子荧光法测定上述元素存在极大的干扰，提出采用低温（＜450℃）灰化处理可完全消除干扰。对比研究还发现，过去森林沼泽景观区的区域化探扫面资料中的As,Sb,Bi数据存在问题，应专门对其进行评价研究。     

Mechanisms of physico-chemical interaction of mercury with river sediments from a gold mining region in Brazil: Relative mobility of mercury species

Mercury accumulation in the food chain, as a consequence of gold recovery in Brazil, has been an issue of concern. Reactions of Hg in the environment are quite complex, and can involve various Hg chemical species. Laboratory experiments were carried out on Hg⁰ solubility, Hg complexation and sorption on river sediments from a gold mining region in Brazil. The reactivity and the mobility of Hg species were considered. Results indicate that methyl mercury is more mobile than ionic mercury, and that the presence of humic acid enhances drastically the solubility of Hg⁰. The soluble complex formed has a relatively lower interaction at the sediment/water interface and is more prone to spread through the aquatic environment.     

Mobility of heavy metals as a function of pH of samples from an overbank sediment profile contaminated by mining activities

Parts of the flood plains north of the Harz Mountains are contaminated with heavy metals, such as Pb, Cu, Zn and Cd derived from mining, which has been carried out in the Harz Mts. since the Middle Ages. It is important to know the mobility of the heavy metals in these overbank sediments in order to estimate the danger to the environment arising from this source. This paper deals with the effect of pH on heavy-metal mobility, using a constant-pH method. The investigations were carried out on an overbank sediment profile near Salzgitter Bad, north of the Harz Mts. The mobility of the heavy metals in the overbank sediment profile is described as a function of pH and depth. Besides the mobile heavy-metal fraction at a certain pH, the buffering capacity of the sediment at this pH must be taken into consideration. The different layers of the overbank sediment profile show distinct differences in buffering capacity and a natural pH harrier could be identified in the upper part of the profile. Therefore, to avoid increasing heavy-metal mobility the natural layering of the overbank sediment profile should not be disturbed. Two different kinds of desorption experiments at constant pH are also discussed, as well as the conversion of the heavy-metal species in the ore minerals into the species in the sediment.     

A mixed finite element method for Hele-Shaw cell equations

A new numerical method to solve the system of equations describing two phase flow in a Hele-Shaw cell is presented. It combines a mixed finite element method, the method of subtraction of the singularity and a front tracking grid in a single computational strategy. This choice of discretization techniques is well motivated by the difficulties present in the system of equations and the physics of the problem. The new method was tested against analytical solutions and also by solving the Saffman–Taylor viscous fingering problem for finite and infinite mobility ratios. In both cases convergence under mesh refinement is achieved for the fingers developed from an initial sinusoidal interface. Finger splitting is observed for low values of the surface tension and high mobility ratio. Different explanations, based in our results, are provided for this phenomenon. This revised version was published online in July 2006 with corrections to the Cover Date.     

Constraints of Housing Age and Migration on Residential Mobility

This paper investigates the role of housing age in constraining residential mobility, measured as the percent of households that have moved into their homes in the past 15 months. The leading explanation for why mobility rates differ so much among regions of the United States has been the overall level of growth. The present analysis shows that the growth effect operates through both the newness of population (migration) and the newness of housing available for occupancy by all local residents. The posited explanation for this housing age effect is that progressively older units contain increasingly settled occupants, yielding fewer opportunities for in-movers in areas with older housing. It is empirically demonstrated that households in older housing have lower likelihood of recent mobility even after controlling for age, tenure, migration status, and state location of residence. The analysis reveals the temporal interdependency of mobility, migration, person age, and housing age.     

Stability of arsenopyrite and As(III) in low-temperature acidic solutions

Arsenopyrite is one of the most important pri-mary arsenic mineral. In the Eh-pH diagram of the As-O2-S-H2O system, if the total arsenic concentration (TAs) is taken to be 0.75 mg/L, the total sulfur con-centration, 32 mg/L, the temperature, 25℃and the pressure, one atmosphere pressure for the discrimina-tion of arsenic species, it may be found that under hy-pergene conditions, arsenopyrite is a moderately stable mineral. Only in the strongly alkaline and reducing environment can arsenopy…     

Mechanism of arrested charnockite formation at Nemmara, Palghat region, southern India

The formation of arrested charnockite is an excellent example of structurally controlled channellised fluid flow along specific sites accompanied by selective elemental mobility and mineralogical changes. The present paper recognises and focuses study on three types of arrested charnockite formation from Palghat region, namely, shear-controlled, foliation parallel and boudin-neck types, and address their spatio-temporal relations to regional-scale charnoenderbite. The shear-controlled and foliation parallel types post-date deformation and migmatisation. The boudin-neck type, on the contrary, is coeval with partial melting and followed the path of cooling and decreasing water activity in the gneiss. K-feldspar veining around plagioclase and quartz, symplectitic intergrowth of biotite+quartz after orthopyroxene and K-feldspar, and fluid inclusion data suggests the presence of alkalic supercritical brine and low-density CO₂-rich fluid during charnockite formation. Charnockite domains developed following the breakdown of hornblende, biotite and quartz are characterised by a more or less pronounced depletion of Fe, Ca, Mg and Ti and trace elements Y and Zr, compared to their counterpart gneiss. REE spectra indicate a subtle depletion in the HREE near the centre of the charnockite domain. Although close-pair samples of gneiss–charnockite are isochemical, on a scale of a few millimetres, bi-directional element movement, related to the formation of new mineral was noted. It is postulated that arrested charnockite formation developed in situ on local scale within the granitic domains of the hornblende-biotite gneiss, in the presence of CO₂-rich fluids and alkalic supercritical saline brine. This process post-dated the time of regional granulite (charnoenderbite) and large regional scale retrogression and migmatisation.     

Channel Bed Mobility Downstream from the Elwha Dams,Washington*

Dams are a major source of fragmentation and degradation of rivers. Although substantial research has been conducted on the environmental impacts of large structures in the United States, smaller dams have received less attention. This study evaluated the impact of two dams of moderate size, the Elwha Dams, on the downstream channel system using field data collection at river cross‐sections. The relationship of average boundary shear stress (τ_o) to critical shear stress (τ_cr) served as the basis for determining channel bed material mobility under the two‐year and ten‐year flood events. The channel had the greatest channel bed mobility at the natural cross‐section upstream from the dams, low bed mobility between the structures, and an increase in channel bed mobility in the low gradient river segment near the mouth of the river. Low bed mobility tended to be associated with a lack of channel system complexity, including reduction or loss of bars and low alluvial terraces and their associated young riparian communities. Although these run‐of‐the‐river dams do not modify streamflow greatly, the loss of sediment from the channel system has had a substantial impact on bed mobility and geomorphic and biotic complexity of the Elwha River.     

The use of heavy metal concentrations and dendrochronology in the reconstruction of sediment accumulation, Ma a Panew River Valley, southern Poland

Heavy metal concentrations were investigated in overbank sediments of the Mala Panew River, southern Poland. Samples were collected from seven vertical profiles located within channel infills of a 20th century floodplain at three sites, each up to 50 m wide. In each profile, 15–24 samples were collected and analysed for Ba, Cd, Cu, Pb, and Zn. Sequential extraction of these elements was carried out in the 0.063-mm fraction of selected samples. Additionally, the age of the oldest trees growing close to the profiles has been used to estimate the initiation of sediment accumulation there. Ba, Cu, and Pb, which occur mostly in less mobile, moderately reducible, and residual fractions, were used for sediment dating. Zn and Cd, which in 50–75% occur in the mobile exchangeable fraction, were not suitable for dating. Correlation of Ba, Cu, and Pb concentrations in vertical profiles with changes in the load of effluents discharged to the river showed abrupt changes in the thickness of the strongly polluted sediments across the floodplains. A comparison of the relative changes between heavy metal peaks in sediments of similar age in the different profiles suggests a variable rate of downward metal migration. In general, none of the heavy metals investigated seems to have been mobilised within the stratigraphic layers above the water table. In layers located at stratigraphically lower levels, the Zn and Cd peaks seem to migrate several centimetres to several decimetres down in the profile. In profiles inundated for several weeks every year, Zn and Cd, as well as the relatively less mobile Ba, Cu, and Pb, have migrated downward by several decimetres. The investigation shows that frequent fluctuations of the water table have blurred the original depositional metal patterns of metal concentrations within a period of less than 40 years.     

The effect of bed mobility on resistance to overland flow

When sediment grains are transported as bed load in overland flow, there is a net transfer of momentum from the flow to the grains. When these grains collide with other grains, whether on the bed or in the flow, streamwise flow velocity decreases and resistance to flow increases. Resistance to flow generated in this manner is termed bed‐load transport resistance. Resistance to flow f over a plane bed may be partitioned into grain resistance f_g and bed‐load transport resistance f_bt. We use the symbols f_btf and f_btm to denote f_bt for flows over fixed beds and over mobile beds, respectively, and we compute the effect of bed mobility on flow resistance f_mob by subtracting f_btf from f_btm. The data for this study come from 54 flume experiments with fixed beds and 38 with mobile beds. On average f_mob is approximately equal to half of f_btm, which is about one‐quarter of f. Hence, f_mob is about one‐tenth of f. Predictive equations are developed for f_btf, f_btm and f_mob using dimensional analysis to identify the relevant independent variables and regression analysis to evaluate the coefficients associated with these variables. Values of f_mob are always positive which implies that mobile beds offer greater resistance to flow than do fixed beds. Evidently bed‐load grains colliding with mobile beds lose more momentum to the bed than do grains colliding with fixed beds. In other words, grain collisions with mobile beds are less elastic than those with fixed beds. Copyright © 2005 John Wiley & Sons, Ltd.