多孔结构矿物（岩石）及其环境修复材料的实用性

具有多孔结构的矿物(岩石)作为一类特殊的工业原材料，在环境修复领域的应用前景正在成为研究热点。本文从微孔的尺度、结构、形态、成分等表面固体特征出发，概括性地论述了凹凸棒石、海泡石、蒙脱石、沸石、硅藻土等十几种多孔结构矿物(岩石)在环境修复工程中用作过滤材料、吸附剂、离子交换剂和催化剂等材料时的基本特征和使用时应注意的问题。     

巴彦浩特盆地火成岩的综合地球物理解释

采用综合地球物理方法识别巴彦浩特盆地火成岩,首先利用高精度重磁资料和大地电磁测深资料,初步确定火成岩的平面位置和深度,然后利用钻遇火成岩的已知测井资料,建立人工合成地震记录,在地震剖面上标定出火成岩并分析其波组特征,采用BP神经网络进行火成岩的精细识别.研究表明,综合地球物理解释是提高反演解释精度的有效途径.     

岩石受压破裂的ULF和LF电磁前兆信号

实验观测到了4类岩性、18块样品在单轴压力下直至破裂发生全过程中的ULF和LF电磁前兆信号。这些不同频率的信号是零散出现的，其形态为一组组脉冲，宽度为4ms～16ms，幅度为0．1mV～1．4mV。实验发现具同一谐振频率的天线收到的信号频次与其相对于裂缝的位置和方位有关。结果还表明，电磁前兆信号的频度与岩样强度有关，抗压强度高的岩样电磁前兆信号多。微破裂可能产生了偶电层，在破裂过程中向外辐射，产生了LF频段的磁信号，ULF磁信号则主要由压磁效应产生。     

Petrogenesis of the Ulsan carbonate rocks from the south-eastern Kyongsang Basin, South Korea

Abstract The petrogenesis of the Ulsan carbonate rocks in the Mesozoic Kyongsang Basin of South Korea, which have previously been interpreted as limestone of Paleozoic age, is reconsidered in the present study. Within the Kyongsang Basin, a small volume of carbonate rocks, containing a magnetite deposit and spatially associated ultramafic rocks, is surrounded by sedimentary, volcanic and granitic rocks of the Mesozoic age. The simple cross‐cutting relationships and other outcrop features of the area indicate that the carbonate rocks are an intrusive phase and younger than the other surrounding Mesozoic rocks. The Ulsan carbonates have low concentrations of rare earth elements (REE) and trace elements with the carbon and oxygen isotope values in the range of δ¹³C_PDB = 2.4 to 4.0‰ and δ¹⁸O_SMOW = 17.0 to 19.5‰. Outcrop evidence and geochemical signatures indicate that the Ulsan carbonates were formed from crustal carbonate melts, which were generated by the melting/fluxing of crustal carbonate materials, caused by the emplacement‐related processes of alkaline A‐type granitic rocks. Compared to typical mantle‐derived carbonatites associated with silica‐undersaturated, strongly peralkaline systems, the relatively small size and geochemical characteristics of the Ulsan carbonates reflect carbonatite genesis in a silica‐saturated, weakly alkali intrusive system. Major deep‐seated tectonic fractures formed by the collapse of the cauldron or the rift system associated with the opening of the East Sea (Japan Sea) might have facilitated the ascent of the crustal carbonate melts.     

试论碳酸盐岩上覆红土的形成模式及演化趋势

据长期对岩溶及红土化作用等的研究成果,本文全面系统地分析了碳酸盐岩上覆红土的形成及演化规律,提出了一个新的碳酸盐岩上覆红土的形成模式,进而深入阐明了碳酸盐岩上覆红土的演化规律及其在现代气候条件下的演化趋势等,在解决岩溶及红土学术界存在的碳酸盐岩上覆红土的形成、碳酸盐岩与上覆红土之间的相互关系及其发展演化规律等一系列重大疑难问题上向前迈进了一步,对相关学科的发展将产生积极的推动作用.     

羌塘岩带碰撞后超钾质火山岩地球化学特征及成因探讨

羌塘超钾质火山岩为板块碰撞后的产物,地球化学特征表明,其同时具有板内火山岩和俯冲带岛弧火山岩的双重地球化学特性。化学组成上富含轻稀土和大离子亲石元素而亏损Cr、Ni等相容元素。在成因上受分离结晶作用和源区混合作用共同制约。源区为受古俯冲上地壳物质和下地幔上升流体交代混合的EMII型富集地幔端元,可能富含角闪石和金云母等矿物。     

Paléoenvironnements et caractérisation des roches mères pétrolières des séries pré-salifères du bassin intérieur du Gabon

The Interior Basin of Gabon, created during the break-up between South America and Africa, displays thick Neoproterozoic to Aptian p.p. fluvio-lacustrine deposits overlain by Aptian to Albian marine facies. Rock–Eval analyses from outcrop and drillhole samples show high content in organic matter (up to 25%) related to types I and II. These intervals are encountered within Permian, Neocomian–Barremian as well as Aptian siliciclastic succession. They constitute fairly good to excellent potential petroleum source rocks, which are most probably at the origin of oil indices recognized both in drillholes and in surface.     

The electrical structure of the Slave craton

The Slave craton in northwestern Canada, a relatively small Archean craton (600×400 km), is ideal as a natural laboratory for investigating the formation and evolution of Mesoarchean and Neoarchean sub-continental lithospheric mantle (SCLM). Excellent outcrop and the discovery of economic diamondiferous kimberlite pipes in the centre of the craton during the early 1990s have led to an unparalleled amount of geoscientific information becoming available.

Over the last 5 years deep-probing electromagnetic surveys were conducted on the Slave, using the natural-source magnetotelluric (MT) technique, as part of a variety of programs to study the craton and determine its regional-scale electrical structure. Two of the four types of surveys involved novel MT data acquisition; one through frozen lakes along ice roads during winter, and the second using ocean-bottom MT instrumentation deployed from float planes.

The primary initial objective of the MT surveys was to determine the geometry of the topography of the lithosphere–asthenosphere boundary (LAB) across the Slave craton. However, the MT responses revealed, completely serendipitously, a remarkable anomaly in electrical conductivity in the SCLM of the central Slave craton. This Central Slave Mantle Conductor (CSMC) anomaly is modelled as a localized region of low resistivity (10–15 Ω m) beginning at depths of 80–120 km and striking NE–SW. Where precisely located, it is spatially coincident with the Eocene-aged kimberlite field in the central part of the craton (the so-called “Corridor of Hope”), and also with a geochemically defined ultra-depleted harzburgitic layer interpreted as oceanic or arc-related lithosphere emplaced during early tectonism. The CSMC lies wholly within the NE–SW striking central zone defined by Grütter et al. [Grütter, H.S., Apter, D.B., Kong, J., 1999. Crust–mantle coupling; evidence from mantle-derived xenocrystic garnets. Contributed paper at: The 7th International Kimberlite Conference Proceeding, J.B. Dawson Volume, 1, 307–313] on the basis of garnet geochemistry (G10 vs. G9) populations.

Deep-probing MT data from the lake bottom instruments infer that the conductor has a total depth-integrated conductivity (conductance) of the order of 2000 Siemens, which, given an internal resistivity of 10–15 Ω m, implies a thickness of 20–30 km. Below the CSMC the electrical resistivity of the lithosphere increases by a factor of 3–5 to values of around 50 Ω m. This change occurs at depths consistent with the graphite–diamond transition, which is taken as consistent with a carbon interpretation for the CSMC.

Preliminary three-dimensional MT modelling supports the NE–SW striking geometry for the conductor, and also suggests a NW dip. This geometry is taken as implying that the tectonic processes that emplaced this geophysical–geochemical body are likely related to the subduction of a craton of unknown provenance from the SE (present-day coordinates) during 2630–2620 Ma. It suggests that the lithospheric stacking model of Helmstaedt and Schulze [Helmstaedt, H.H., Schulze, D.J., 1989. Southern African kimberlites and their mantle sample: implications for Archean tectonics and lithosphere evolution. In Ross, J. (Ed.), Kimberlites and Related Rocks, Vol. 1: Their Composition, Occurrence, Origin, and Emplacement. Geological Society of Australia Special Publication, vol. 14, 358–368] is likely correct for the formation of the Slave's current SCLM.     

A Linear Programming Approach to Determine the Normative Composition of Sedimentary Rocks

The analysis of modal and normative composition of sedimentary rocks is widely used for studying their sources and tectonic settings. The normative calculation of the mineral composition of rocks in this study is formulated as a linear programming problem and is solved by means of the simplex method. This enables both simultaneous and successive subtraction of a set of basic minerals from a rock sample represented by its chemical composition {SiO₂...LOI}. Such an approach provides a more exact calculation of the contribution of basic minerals in the rock. This mathematical approach is used to study two representative sets of sandstones and fine-grained rocks from a Meso- to Neoproterozoic marginal basin of southeastern Siberia (Uchur–Maya region, Yakutia) and a Pennsylvanian-Lower Permian uplifted continental block in Colorado, USA. The calculated normative mineral compositions of the Siberian sandstones are consistent with the observed modal compositions. These sandstones vary from K- Feldspar rich arkoses at the base of the sequence (the Uchur Group, lower Riphean) to quartz arenites or lithic sandstones and wacke in transgressive successions of the middle-upper Riphean. Arkoses and quartz arenites are dominant in Meso- to Neoproterozoic Siberia. These samples represent craton interior uplifted basement and quartzose, recycled orogen provenance of a stable craton in Rodinia. There are higher but consistent discrepancies between the calculated and observed compositions for the Pennsylvanian to Lower-Permian arkoses and quartz arenites (Sangre de Cristo, Belden, and Maroon Formations). The differences between the predicted and observed mineralogy may be due to uncertainties in the modes in the matrix and cement of the sandstones. This normative program should supplement modal calculations and provide better genetic constructions, especially in case of matrix-rich sandstones.