早元古代滹沱群玄武岩Rb-Sr、Sm-Nd同位素体系初论

本文给出的滹沱群下亚群青石村组玄武岩Ｒｂ－Ｓｒ、Ｓｍ－Ｎｄ全岩等时线年龄为２０４５．８±１７和２３６９±３０Ｍａ（Ｚ），角门石４０Ａｒ－３９Ａｒ坪年龄和最高视年龄为１３６４±１９和１９３２±１９Ｍａ（１）；中亚群河边村组玄武岩Ｒｂ－Ｓｒ全岩等时线年龄图的投点呈完全离散状，Ｓｍ－Ｎｄ全岩等时线年龄为２３２２±３１Ｍａ（２），角门石４０Ａｒ－３９Ａｒ坪年龄和最高视年龄为１３６０和１７４２±１７Ｍａ（１）。根据上述Ｒｂ－Ｓｒ、Ｓｍ－Ｎｄ数据与已知青石村组、河边村组单颗粒锆石Ｕ－Ｐｂ法确定的成岩年龄２４５０±１０和２４００±２０Ｍａ（２）的明显差别，４０Ａｒ－３９Ａｒ均揭示为较典型受扰动的年龄谱和较发育的透人性构造、晚期岩脉等地质证据，认为Ｒｂ－Ｓｒ、Ｓｍ－Ｎｄ是重设的同位素体系。     

辽北清原地区太古宙地质演化及其对成矿的控制作用

辽北清原地区在时空上有系统地发育了三个太古亩地体：浑河以南的小莱河花岗岩-绿岩带（ＸＧＧＢ）、浑河以北的清原花岗岩-绿岩带（ＱＧＧＢ）和在ＱＧＧＢ东北部出露的景家沟麻粒岩-片麻岩区（ＪＧＧＲ）。绿岩带中火山岩组合在ＸＧＧＢ中以双峰式岩套为特征，而在（ＱＧＧＢ中以连续的钙碱性系列为特征。ＸＧＧＢ中斜长角门岩全岩Ｓｍ－Ｎｄ等时线年龄为３０１８±２０Ｍａ，Ｎｄ（ｔ）＝＋０．１９±０．１７，ＴＤＭ＝３３４７～３７３５Ｍａ，而ＱＧＧＢ中的斜长角闪岩全岩Ｓｍ～Ｎｄ等时线年龄为２８８４±４８Ｍａ，∈Ｎｄ（ｔ）＝＋２．６１±０．４１，ＴＤＭ＝２９３８～２９９２Ｍａ。ＪＧＧＲ中黑云麻粒岩的Ｒｂ－Ｓｒ等时线年龄为２９９４±３２５Ｍａ，可能代表变质年龄，表明其形成在ＸＧＧＢ之前。综合研究表明辽北地区太古亩地质演化模式很可能为：ＪＧＧＢ代表了古中太古代古陆的残骸，ＸＧＧＢ于中太古代形成在这个古陆边缘的裂谷盆地内，ＱＧＧＢ则形成在新太古代的大陆边缘岛弧环境，并于新太古代晚期与ＸＧＧＢ拼贴。在此陆一弧碰撞过程中，ＱＧＧＢ逆冲推覆于ＪＧＧＲ之上，后者由于后期的伸展作用而出露于地表。成矿作用是地质演化的组成部分，并受制于各个演化阶段的构造环境     

华北地台主要花岗岩-绿岩带含金丰度值的研究

近十余年来，在华北地台太古宙花岗岩－绿岩带金矿的研究中，获取了许多有关地层、岩石金丰度值的资料。早期获取的资料因化验分析方法灵敏度不高且样品中常常包含矿化、蚀变和构造破碎的岩石等原因而使其金丰度值偏高。最新的数据采用了高灵敏度化验分析方法且剔除了矿化、蚀变和破碎的岩石样品，计算出的金丰度值均明显低于或接近于地壳金丰度值。结合其它研究成果，提出绿岩带有关金矿矿源是多源的（变质的、岩浆的），甚至是深源的（下地壳或上地幔）认识。     

The hydrocarbon generation mechanism and the three-stage type model of hydrocarbon generation for carbonate source rocks

The diagenetic mechanism and process of carbonate rocks, which is different to that of clastic rocks, decides the existence of different existing state organic matters in carbonate rocks. This has been verified by both the microscopic observation of organic petrology and the analysis of organic geochemistry of many samples. Based on the hydrous pyrolysis simulation experiment of the low-mature carbonate rocks, the contrasting study on the yield and their geochemistry characteristics of different existing state soluble organic matters of a series of various maturity samples shows that the different existing state organic matters make different contributions to hydrocarbon generation during every evolution state. So that, the hydrocarbon generation process of carbonate rocks can be summarized as the following three stages: the first is the direct degradation of biogenic bitumen macromolecules during the immature stage, the second is the thermal degradation of a large amount of kerogen at the mature stage, the last stage is the expulsion or release of inclusion organic matter owing to the increased thermal expansion pressure during the high evolution stage. Part of achievements of the Eighth Five-Year National Science-Technology Key-Task Project “85-102-02-07”.     

The ClBrI composition of 3.23 Ga modified seawater: implications for the geological evolution of ocean halide chemistry

Fluid inclusion leachates obtained from vug and vein quartz samples from an Archean (3.23 Ga) Fe-oxide hydrothermal deposit in the west-central part of the Barberton greenstone belt, South Africa, were analyzed by ion chromatography for chloride, bromide, and iodide. The deposit, known as the ironstone pods, formed by seafloor hydrothermal activity and fluid discharge. Quartz is dominated by type I liquid-vapor, aqueous inclusions with a bimodal salinity distribution (0–0.25 M_Cl⁻ and 0.9–1.8 M_Cl⁻). Bulk analytical salinities range from 0.45 to 0.99 M_Cl⁻ represent averages of type I inclusions. Bulk fluid inclusion bromide and iodide concentrations are 1.44–3.32 mM and 0.01–0.12 mM, respectively. For comparison, modern seawater has halogen contents of 590 mM chloride, 0.9 mM bromide, and 0.5 μM total iodine. In the fluids from the ironstone pods, bromide and iodide are enriched relative to chloride, when compared with modern seawater.Approximate Br⁻Cl⁻ and I⁻Cl⁻ ratios of 3.2 Ga Barberton seawater are 2.5 × 10⁻³ and 40 × 10⁻⁶, respectively. Dispersion to higher values was caused principally by reaction with organic sediments whose trends are similar to those seen for modern vent fluids at unsedimented and sedimented ridges, relative to modern seawater. These halide ratios are greater than those of modern seawater, suggesting a change in the halide ratios of seawater over geological time. The analytical data are consistent with a model in which marine organic sedimentation has fractionated bromine and iodine out of seawater relative to chloride, thereby causing the halide ratios of seawater to decrease from high early and mid-Archean values towards their present day values.     

铝对铬成矿地球化学的依存性和对抗性

基于岩浆铬矿床与超镁铁质岩石的关系，从元素亲合性和共生规律的角度揭示了铝对铬成矿制约的主导作用，分析了铝和铬亲石、亲氧的二重性及其晶体化学的依存关系。论证了超镁铁Ｓｉ－Ｏ体系中铝丰度过高或过低均不利于铬的成矿。揭示了制约元素分散富集的因素都是在一定条件下互为依存和转化的，是在动态中的矛盾的对立和统一。     

生物礁岩分类方案

本文系统地提出了一个生物礁岩分类的新方案。生物礁岩首先根据次生组分的有无分为原生礁岩和次生礁岩。次生礁岩根据次生组分来源分为骨源次生礁岩和礁源次生礁岩。次生礁岩的二级分类根据次生组分的含量进行。骨源次生礁岩分为骨屑岩和含骨屑礁（灰）岩、倒骨央和含倒骨礁（灰）岩；礁源次生礁岩分为礁屑岩和含礁屑礁（灰）岩。骨屑岩根据次生组分的粒度分为巨骨砾（屑灰）岩、骨砾（屑灰）岩、细骨砾（屑灰）岩、骨砂（屑灰）岩；     

福建沙县地区早白垩世火山岩成因及构造环境分析

本文着重阐述了沙县地区早白垩世火山岩地球化学特征，论证了中性与酸性火山岩的成因及物质来源，认为二者为不同源岩浆演化的产物，其岩浆物质来源于壳幔混源区，为省内双峰式火两端员岩石间成因关系的分析研究提供了新的例征。     

太白维山中生代火山岩特征及其与成矿的关系

晋北太白维山火山岩属钾质碱性玄武岩系列,产于板块内部活化带,来源于上地幔或下部地壳,被上部地壳物质混染,为壳幔源型或同熔型火山岩.火山岩与Ag(Pb、Zn)矿化关系密切,是成矿热液和矿质的主要来源之一.     

藏南特提斯喜马拉雅带中段二叠纪-白垩纪的火山活动(Ⅰ):分布特点及其意义

在野外实地考察和追索的基础上，详细厘定了特提斯喜马拉雅带中段晚古生代以来火山岩的分布特点和迁移规律。结果表明，在特提斯喜马拉雅带中段晚古生代以来的地层系统中，从二叠纪→三叠纪→侏罗纪→白垩纪，共有11个层位含规模不等的火山岩，它们以透镜体、薄夹层或以块状玄武岩、玄武质安山岩等形式产出于不同地层系统中；从二叠纪→早中三叠世→晚三叠世→侏罗纪和白垩纪，具有由西向东、从南→北→南→北的迁移规律。这些火山活动的发现和厘定，对填补特提斯喜马拉雅带火山岩研究的空白，了解陆下岩石圈地幔和软流圈地幔之间的相互作用和新特提斯洋盆的形成演化都具有一定的指示意义。