杭州地区石笋稳定同位素古气候探索

用１４Ｃ测年技术和稳定同位素地球化学古温度方法，对浙江省临安瑞晶洞穴的石笋进行了１４Ｃ的测年和碳、氢、氧同位素测试，获得５～１万年间杭州地区古气候演化记录、该记录表明，在５～１万年间有三次较明显的周期性古温度变化，最高温度为１４．９℃，最低温度为６．６℃，最大温差为８℃左右，平均温差３～５℃。这段时期正处在大理冰期后期，但大理冰期并不是一个持续的低温阶段，它至少有３次温度波动。与我们获得的石笋同位素古温度相一致。另外，我们将５～１万年间杭州地区古气候变化与同期东南沿海的海平面变化进行了对比，在时间上也较为吻合，也就是温度上升、海平面也上升，温度下降、海平面也随之下降     

我国最大古岩溶型铀矿床成因的同位素地球化学研究

据对某大型古岩溶型铀矿床中铀－铅同位素体系及硫、碳、氧、氢同位素组成的研究结果，表明该矿床成矿物质源自矿区众多地层，成矿流体的变质水和古岩溶水（古大气降水）的混合水；成矿经历了古岩溶铀淋积富集，燕山早、晚期构造运动促使两次含铀热水溶液改造、叠加成矿（１３５～１１９。６５Ｍａ），成矿作用与古岩溶和区域地质构造演化密切相关，属古岩溶型热造铀矿床。     

四川成都盆地某深层富钾卤水的地球化学特征及成因

本文报道了四川成都盆地某深层富钾层卤水的化学组成，氧、氢、硫和硼同位素组成以及２５℃等温蒸发析盐过程中，从卤水中获得的固相物质组成。在此基础上讨论了卤水的成因，认为该卤水是蒸发浓缩的海相卤水、非海相卤水以及埋藏成岩过程中封存卤水对地层中海相蒸发盐溶滤作用形成的混合水。     

不同岩溶动力系统的碳稳定同位素和地球化学特征及其意义——以我国几个典型岩溶地区为例

结合水化学的野外观测及室内计算,作者对桂林岩溶试验场、四川黄龙风景区和贵州乌江渡坝区3个岩溶动力系统的碳稳定同位素特征进行了分析,进而对系统的性质、系统中CO_2的来源、碳酸盐沉积过程中的碳同位素动力分馏、水化学和钙华的成因及热水钙华的~(14)C测年等地球化学问题作了探讨。结果表明,桂林岩溶试验场属于表层岩溶作用动力系统,其中的侵蚀动力主要来源于大气降水溶解土壤中的CO_2;四川黄龙风景区属于深部岩溶动力系统,侵蚀动力来自大气降水溶解幔源的CO_2;贵州乌江渡坝区岩溶系统,虽然属于表层岩溶动力系统,但其中一部分的同位素和水化学特征已受到人类活动的重大影响。     

Isotope Tracing and Prospecting Assessment of Gold-Silver Deposits in Zhejiang Province

Three different types of gold and silver deposits in Zhejiang Province(Huangshan gold deposit, Zhilingtou gold-silver deposit and Haoshi silver deposit) showmarked differences in lead and strontium isotopic composition, suggesting three differentsources and geneses of these deposits. The Huangshan gold deposit features low initial Srisotope ratios and low μ values or low content of radiogenic Pb and its ore-forming materialscame primarily from the upper mantle; the Zhilingtou gold-silver deposit shows high initial Srisotope ratios and high μ values or high content of radiogenic Pb and the ore-forming materialswere derived mainly from the upper crust; and the Haoshi silver deposit has its Pb and Srisotope ratios between the above two cases with the ore-forming materials stemming from boththe mantle and the crust. The characteristic Pb isotopic composition may serve as an indicatorfor prospecting for different types of ore deposits.     

The Influence of CO on the Carbon Isotopic Composition of CH_4 in Closed Pyrolysis Experiment With Coal

1IntroductionThecarbonisotopiccompositionofnaturalgasesisregardedasacontanttracerusedinthegeochemicalresearchofnaturalgases .Basedonthecarbonisotopiccomposition ,thegenetictypesofnaturalgasesarebasicallydividedtodeterminethematurationofnaturalgasesandmakegas sourcecorrelations (Stahl,1 973;StahlandCarey ,1 975;Stahletal.,1 977;James ,1 983;Schoell,1 983,1 988;DaiJinxingetal.,1 992 ;FuJiamoetal.,1 992 ;XuYongchang ,1 994 ) .Theformationofnaturalgasescouldbededucedintermsofcarbonisotopicvar…     

贵州百花湖分层晚期有机质降解过程与溶解N2O循环

百花湖是一个具有季节性分层的富营养小型湖泊,在秋季湖水倒转期经常发生水质恶化事件,碳氮循环出现异常。文章研究特选择在秋初,湖泊分层开始消失时,测定了湖水中不同深度的N₂O,CH₄,CO₂,有机和无机碳同位素以及其他化学参数变化。结果发现:采样时百花湖在约6m和16m深度附近出现了两个温度不连续层(SDL和PDL),并影响到有机颗粒的沉降和分解。相对而言,有较多的有机质在这两个层内发生降解,但降解的途径有所不同,上部主要是有氧降解,下部则主要是无氧降解过程。N₂O的产生和消耗与有机质的降解过程完全对应:PDL层以上,ΔN₂O与AOU的线性关系反映了N₂O主要形成于硝化作用;PDL层以下反硝化作用导致N₂O严重不饱和;PDL内位于硝化作用和反硝化作用过渡带的N₂O峰,显然是硝化与反硝化联合作用的结果。PDL层内较大的CH₄浓度变化梯度,说明嗜甲烷细菌可能通过氧化NH+4贡献了部分N₂O。百花湖秋、冬季表层湖水N₂O都是过饱和的,都是大气N₂O的源,依据分子扩散模型计算湖泊N₂O的释放通量在12～14μmol/m·day之间,秋、冬季没有明显的差别。秋季底层湖水的反硝化作用是湖泊N₂O的汇,其消耗通量与表层的释放通量基本相当。     

鄂尔多斯盆地奥陶系海相碳酸盐岩生烃性能与中部长庆气田气源成因研究

用激光 -荧光显微镜等有机岩石学方法 ,挑选样品中有明显生、排烃现象的碳酸盐岩 ,再以测定的这类碳酸盐岩的有机碳含量为依据 ,确定本区高成熟碳酸盐气源岩残余有机碳的下限指标用 0 .13%～ 0 .14 %比较合理。根据碳酸盐岩储层孔隙中充填沥青和皮膜状残余沥青的分布和含量 ,论证了陕参 1井等奥陶系碳酸盐岩地层在地质历史中 ,存在若干油气有效储层。采用连续升温 ,步进取样的热模拟实验方法 ,揭示了本区煤与碳酸盐岩干酪根随热演化作用增强 ,烃类气体产物的干燥系数增大 ,δ1 3C1 、δ1 3C2 明显变重的规律 ,并根据样品实验结果推算 ,本区石炭系—二叠系煤最大生气阶段的δ1 3C1 应为 - 2 7‰～ - 2 8‰ ,碳酸盐岩最大生气阶段的δ1 3C1 应为- 31.7‰～ - 33‰。在气源成因判识中 ,根据主生气期阶段对天然气成藏储聚的贡献最大、甲烷碳同位素较重以及长庆气田风化壳气藏天然气δ1 3C1 重值区并不与石炭系—二叠系煤的镜质组反射率高值区匹配的现象等进行气源判识 ,认为长庆奥陶系风化壳气藏 ,具有下古生界海相碳酸盐岩气与上古生界石炭系—二叠系煤成气的混源成因     

Metamorphism and metamorphic K–Ar ages of the Mesozoic accretionary complex in Northland, New Zealand

Abstract A southwest dipping Mesozoic accretionary complex, which consists of tectonically imbricated turbiditic mudstone and sandstone, hemipelagic siliceous mudstone, and bedded cherts and basaltic rocks of pelagic origin, is exposed in northern North Island, New Zealand. Interpillow limestone is sometimes contained in the basaltic rocks. The grade of subduction‐related metamorphism increases from northeast to southwest, indicating an inverted metamorphic gradient dip. Three metamorphic facies are recognized largely on the basis of mineral parageneses in sedimentary and basaltic rocks: zeolite, prehnite‐pumpellyite and pumpellyite‐actinolite. From the apparent interplanar spacing d₀₀₂ data for carbonaceous material, which range from 3.642 to 3.564 Å, the highest grade of metamorphism is considered to have attained only the lowermost grade of the pumpellyite‐actinolite facies for which the highest temperature may be approximately 300°C. Metamorphic white mica K–Ar ages are reported for magnetic separates and <2 µm hydraulic elutriation separates from 27 pelitic and semipelitic samples. The age data obtained from elutriation separates are approximately 8 m.y. younger, on average, than those from magnetic separates. The age difference is attributed to the possible admixture of nonequilibrated detrital white mica in the magnetic separates, and the age of the elutriation separates is considered to be the age of metamorphism. If the concept, based on fossil evidence, of the subdivision of the Northland accretionary complex into north and south units is accepted, then the peak age of metamorphism in the north unit is likely to be 180–130 Ma; that is, earliest Middle Jurassic to early Early Cretaceous, whereas that in the south unit is 150–130 Ma; that is, late Late Jurassic to early Early Cretaceous. The age cluster for the north unit correlates with that of the Chrystalls Beach–Taieri Mouth section (uncertain terrane), while the age cluster for the south unit is older than that of the Younger Torlesse Subterrane in the Wellington area, and may be comparable with that of the Nelson and Marlborough areas (Caples and Waipapa terranes).     

K–Ar geochronology of the temporal change of eruptive style in the eastern Izu peninsula, central Japan

Abstract   A recent K–Ar study elucidated that eruptive style in the eastern Izu peninsula changed from polygenetic to monogenetic volcano at 0.3–0.2 Ma. To narrow down the time of change, we determined 10 K–Ar ages on Togasayama Andesite of Amagi volcano, the youngest polygenetic volcano in the area, and Togasayama Monogenetic Volcano, one of the oldest monogenetic volcanoes in the area, which overlies a part of the Togasayama Andesite. Dating results showed that the Togasayama Andesite effused at least from 0.34 to 0.20 Ma, whereas the Togasayama Monogenetic Volcano erupted at 0.26–0.29 Ma, suggesting that the northern part of the Togasayama Andesite effused after the eruption of the Togasayama Monogenetic Volcano. Considering previous data, it is therefore inferred that change of eruptive style in the eastern Izu area occurred during the period 0.29–0.20 Ma, with considerable overlap of both polygenetic and monogenetic volcanism.