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81.
82.
M. Mastalerz C. Souch G. M. Filippelli N. L. Dollar S. M. Perkins 《International Journal of Coal Geology》2001,46(2-4)
Cores from the Great Marsh area of the Indiana Dunes National Lakeshore were examined in order to document variations in concentration, type and size of anthropogenic organic matter (AnOM—coal, coke, etc.) and discuss their relationship to the concentration of such trace elements as Pb, Zn, and Mn in the near-surface sediment section. The results indicate that the first appearance of AnOM corresponds to the onset of industrialization in the area. There is also a general relationship between the occurrence of AnOM and Zn, Pb, and Mn. Trace metals were likely transported from the industrial sites to the area of their deposition as sulfur-bearing coatings on small anthropogenic particles. After deposition, these sulfur-bearing compounds reacted with organic matter within the marsh. As a result of bacterial reduction, the pyrite was produced, as suggested by a close relationship between the pyrite and AnOM. Distance from the industrial complex upwind as well as local hydrologic conditions are among the major factors controlling distribution of AnOM and trace elements. At the same distance from the source, types and sizes of AnOM are influenced by the duration and frequency of flooding. 相似文献
83.
Generation of Deccan Trap magmas 总被引:1,自引:0,他引:1
Gautam Sen 《Journal of Earth System Science》2001,110(4):409-431
Deccan Trap magmas may have erupted through multiple centers, the most prominent of which may have been a shield volcano-like
structure in the Western Ghats area. The lavas are predominantly tholeiitic; alkalic mafic lavas and carbonatites are rare.
Radioisotope dating, magnetic chronology, and age constraints from paleontology indicate that although the eruption started
some 68 Ma, the bulk of lavas erupted at around 65–66 Ma. Paleomagnetic constraints indicate an uncertainty of ± 500,000 years
for peak volcanic activity at 65 m.y. in the type section of the Western Ghats. Maximum magma residence times were calculated
in this study based on growth rates of “giant plagioclase” crystals in lavas that marked the end phase of volcanic activity
of different magma chambers. These calculations suggest that the > 1.7 km thick Western Ghats section might have erupted within
a much shorter time interval of ∼ 55,000 years, implying phenomenal eruption rates that are orders of magnitude larger than
any present-day eruption rate from any tectonic environment. Other significant observations/conclusions are as follows: (1)
Deccan lavas can be grouped into stratigraphic subdivisions based on their geochemistry; (2) While some formations are relatively
uncontaminated others are strongly contaminated by the continental crust; (3) Deccan magmas were produced by 15–30% melting
of a Fe-rich lherzolitic source at ∼ 3–2 GPa; (4) Parent magmas of the relatively uncontaminated Ambenali formation had a
primitive composition with 16%MgO, 47%SiO2; (5) Deccan magmas were generated much deeper and by significantly more melting than other continental flood basalt provinces;
(6) The erupted Deccan tholeiitic lavas underwent fractionation and magma mixing at ∼ 0.2 GPa. The composition and origin
of the crust and crust/mantle boundary beneath the Deccan are discussed with respect to the influence of Deccan magmatic episode. 相似文献
84.
Pollution vulnerability of the Quaternary aquifer near Cairo, Egypt, as indicated by isotopes and hydrochemistry 总被引:2,自引:1,他引:2
The present study was conducted to delineate the pollution vulnerability of the Quaternary aquifer in two areas, Imbaba and
Shobra El-Khima, near Cairo, Egypt. Environmental isotopes combined with hydrochemistry were used for this purpose. The groundwater
in the Imbaba area (average total dissolved solids about 900 mg/L; sodium/chloride, sulfate, and bicarbonate water types)
is more mineralized than groundwater in the Shobra El-Khima area (average total dissolved solids 500 mg/L; calcium and sodium/bicarbonate
water type). A high nitrate content and significant mineralization in the groundwater are probably due to contamination of
recharge to the aquifer by irrigation drainage, deteriorated sewage networks, and septic tanks. The deuterium and oxygen-18
compositions of the groundwater are depleted compared to Nile River water, which is the main source of aquifer recharge. This
less isotopically enriched water probably represents older Nile water recharge that flooded the region before construction
of the Aswan High Dam in 1963, or it is a mixture of a young water and originally deposited paleowater that was in deeper
horizons at a time of cooler and more humid climate. Intensive pumping has moved the paleowater higher in the aquifer. Groundwater
in the Shobra El-Khima area has higher residence time, based on the tritium concentration, than groundwater in the Imbaba
area. The percentage of the isotopically depleted water equals 75% in the Shobra El-Khima and 35% in Imbaba, and the thickness
of the clay cap above the aquifer is 38 m in Shobra El-Khima and 20 m in Imbaba. These factors are indicative of the rate
of recharge to the aquifer and were used to evaluate the pollution vulnerability in the two areas.
Electronic Publication 相似文献
85.
Groundwater samples collected from both open and bore wells in an area of about 270 km2 from Madras City, India, have been analyzed for major ions (HCO3, Cl, Si, Na, Ca, and Mg) and trace elements (As, Se, B, V, Cr, Fe, Co, Pb, Cu, Zn, Cd, Mn, Ni, Mo, and Ba). The study reveals that the quality of potable water has deteriorated to a large extent. Seawater intrusion into the aquifer has been observed in nearly 50 percent of the study area. The toxic elements (As and Se) have already exceeded the maximum permissible limits of drinking water in almost the entire city. A positive correlation of As and Se with other toxic metals such as V, Cr, Fe, B, etc., indicates that all these elements are anthropogenic in origin. Applying multivariate analysis, the source for trace elements in groundwater has been grouped into two major factors: pollution and mobilization factors. The groundwater in the study area is largely contaminated by organic effluents and reflects the intensity of pollution caused by the overlying soil sediment and rapid infiltration of the pollutants. 相似文献
86.
Cearreta A Irabien MJ Leorri E Yusta I Quintanilla A Zabaleta A 《Marine pollution bulletin》2002,44(6):487-503
The distribution and abundance of benthic foraminifera and a range of elements have been analysed in six long cores (up to 10 m long) from the Bilbao estuary, N. Spain, to document environmental transformation of this estuarine ecosystem and to determine sediment contamination levels. Three different environmental zones could be distinguished in the recent sedimentary record based on its microfaunal and geochemical contents. Initially, a pre-industrial zone containing very abundant and diverse foraminiferal assemblages together with baseline metal levels. Secondly, an older industrial zone exhibiting co-existence of abundant and diverse foraminiferal assemblages with high concentrations of metals. Finally, a younger industrial zone with extreme concentrations of metals and barren of indigenous foraminifera. This environmental transformation has been caused by the discharge of untreated domestic and industrial effluents during the last 150 years. The occurrence of foraminifera in the two industrial zones and along the estuary is not related to defined levels of metals, and this seems to confirm oxygen limitation as the key factor to explain complete estuarine defaunation during deposition of the younger industrial zone (period 1950-2000). Effectiveness of current regeneration schemes could be assessed using microfaunal and geochemical proxies as environmental quality indicators. 相似文献
87.
R. Mackay J.A. Morakinyo 《Stochastic Environmental Research and Risk Assessment (SERRA)》2006,20(3):213-222
An industrial site is usually contaminated by accidental (and occasionally intentional) releases of pollutants to the environment
from various operations carried out on that site. Consequently, the pattern of contamination created during the life of the
site depends in part, at least, on the pattern of operations. Thus, the assessment of the pattern of contamination over the
site should be improved: if it is possible to identify the pattern of operations on the site, the duration of the different
activities and the perceived likelihood of releases from the different operations. A stochastic model has been developed that
can be used to simulate alternative realizations of contaminant releases (duration, extent and timing). The model employs
release zones associated with particular activities or groups of activities on the site and the areas of each of the zones
may be independent or overlapping. The period of activity in each zone is obtained from the site records, while the likelihood
and extent of contamination in each zone is inferred from an analysis of the contamination data obtained by point sampling.
The form of the model, the method of inference of the model parameter values from the site data and the application of the
model to the study site are presented. The release model has been developed as part of a suite of stochastic models for site
ground contamination analysis. The stochastic soil and transport models and the application of the integrated modelling system
are described in separate papers. 相似文献
88.
Numerical weather prediction models are increasingly employed for providing meteorological data for urban air quality applications.
Model resolution, physiographic parameters and surface-layer parameterisations need to be adapted to the requirements of the
urban boundary layer. The Lokalmodell of the German Weather Service was triple-nested down to a horizontal grid resolution
of 1.1 km, urbanised physiographic parameters were implemented, and an additional anthropogenic heat source was introduced.
Results of a sensitivity study for a spring dust episode in Helsinki show a clear urbanisation effect of these measures on
temperature, humidity and the partitioning of surface fluxes, leading to an increased Bowen ratio and heat storage and an
urban heat island effect. 相似文献
89.
I. González M. M. Jordán T. Sanfeliu M. Quiroz C. de la Fuente 《Environmental Geology》2007,52(7):1243-1251
In southern Chile, with a mild and rainy climate, high levels of heavy metals have been detected in many gold placer deposits.
Many of the contaminants pose risks to human life, and consequently damage the trofic chain in this environment. The study
zones selected correspond to the handicraft gold-bearing sands of Rio Gato (Los Muermos), Carelmapu and Cucao. These are all
located in the X Region of “Los Lagos” in Chile. The type of methodology used in the characterization of the associated mineralization
consists of testing each representative sample with a grain size distribution, statistical parameter analysis and a mineralogical
analysis, using a binocular magnifying glass, a petrographic microscope, XRD and SEM/EDX. The chemical composition was defined
by means of X ray fluorescence and micro-chemical analysis. The results of the study about sediments in southern Chile are
presented. The major concentrations of heavy minerals are generally located in areas of dynamic river energy. In the samples,
more than 70% of the heavy minerals were distributed among grain sizes corresponding to thin sand with good grain selection
(meshes of 0.25–0.06 mm). The main mineral phases present in the analysed samples were gold, zircon, olivine, ilmenite, hornblende,
hypersthene, hematite, garnet, chromite, chlorite, augite, amphibolitic-epidote, etc. The main heavy metals found as a result
of the study were mercury, lead, cadmium, chrome, tellurium, indium, zinc, cobalt, copper, platinum, gold, etc., and as well
some less common elements like cerium, praseodymium, gadolinium, neodymium, samarium and lanthanum. This research work is
only a starting point for carrying out a risk probability mapping of heavy metals and the mineralogy of the Cucao, Carelmapu
and Rio Gato gold-bearing sands. 相似文献
90.
Magmatic History of Somma-Vesuvius on the Basis of New Geochemical and Isotopic Data from a Deep Borehole (Camaldoli della Torre) 总被引:3,自引:0,他引:3
Di Renzo V.; Di Vito M. A.; Arienzo I.; Carandente A.; Civetta L.; D'antonio M.; Giordano F.; Orsi G.; Tonarini S. 《Journal of Petrology》2007,48(4):753-784
A continuous-coring borehole recently drilled at Camaldoli dellaTorre on the southern slopes of SommaVesuvius providesconstraints on the volcanic and magmatic history of the Vesuvianvolcanic area since c. 126 ka BP. The cored sequence includesvolcanic units, defined on stratigraphical, sedimentological,petrological and geochemical grounds, emitted from both localand distal vents. Some of these units are of known age, suchas one Phlegraean pre-Campanian Ignimbrite, Campanian Ignimbrite(39 ka), Neapolitan Yellow Tuff (14· 9 ka) and VesuvianPlinian deposits, which helps to constrain the relative ageof the other units. The main rock types encountered are shoshonite,phonotephrite, latite, trachyte and phonolite. The sequenceincludes, from the base upwards: a thick succession of pyroclasticunits emplaced between 126 and 39 ka, most of them attributedto eruptions that occurred in the Phlegraean area; the CampanianIgnimbrite; the products of a local tuff cone formed between39 ka and the deposition of the products of the earliest activityof the Mt. Somma volcano; the products of the SommaVesuviusvolcano, which include from the base upwards a thick sequenceof lavas, pyroclastic rocks and the products of a local spattercone dated between 3· 7 ka and AD 79. The data obtainedfrom the study of the borehole show that, before the CampanianIgnimbrite eruption, low-energy explosive volcanism took placein the Vesuvian area, whereas mostly high-energy explosive eruptionscharacterized the Campi Flegrei activity. In the Vesuvian area,Campanian Ignimbrite deposition was followed by the eruptionof a local tuff cone and a long repose time, which predatedthe formation of the Mt. Somma edifice. Since 18· 3 ka(Pomici di Base eruption) the activity of SommaVesuviusbecame mostly explosive with rare lava effusions. The shallowestcored deposits belong to the Camaldoli della Torre cone, formedbetween the Pomici di Avellino and Pomici di Pompei eruptions(3· 7 kaAD 79). New geochemical and SrNdPbB-isotopicdata on samples from the drilled core, together with those availablefrom the literature, allow us to further distinguish the volcanicrocks as a function of both their provenance (i.e. Phlegraeanor Vesuvian areas) and age, and to identify different magmaticprocesses acting through time in the Vesuvian mantle source(s)and during magma ascent towards the surface. Isotopically distinctmagmas, rising from a mantle source variably contaminated byslab-derived components, stagnated at mid-crustal depths (810km below sea level) where magmas differentiated and were probablycontaminated. Contamination occurred either with Hercynian continentalcrust, mostly during the oldest stages of Vesuvian activity(from 39 to 16 ka), or with Mesozoic limestone, mostly duringrecent Vesuvian activity. Energy constrained assimilation andfractional crystallization (EC-AFC) modelling results show thatcontamination with Hercynian crust probably occurred duringdifferentiation from shoshonite to latite. Contamination withlimestone, which is not well constrained with the availabledata, might have occurred only during the transition from shoshoniteto tephrite. From the deep reservoir, magmas rosetowards a series of shallow reservoirs, in which they differentiatedfurther, mixed, and fed volcanic activity. KEY WORDS: SommaVesuvius; crustal contamination; source heterogeneity; radiogenic and stable isotopes; magmatic system 相似文献