黄河源高寒草原下垫面土壤冻融过程中陆-气间的水热交换特征分析

高寒草原水热交换的季节性特征显著,土壤冻融过程对地-气水热交换有着重要的影响.本文利用黄河源区汤岔玛小流域2014年5月至2015年5月陆面过程观测数据,将土壤冻融过程划分为完全融化(TT)和完全冻结(FF)两种状态与融冻(T-F)和冻融(F-T)两个过程,并分析了期间高寒草原下垫面净辐射、感热通量、潜热通量和地表热通...     

Cotton Fiber/ZrO2, A New Material for Adsorption of Cr(VI) Ions in Water

The natural cotton fiber was used to synthesize an anion exchange, containing ZrO₂ film on its surface, NCFZC (natural cotton fiber/ZrO₂ composite). This anion exchanger was produced by the reaction of the zirconium oxychloride and hydroxyl groups on surface of the natural cotton fiber. The material was used for Cr(VI) ions adsorption studies. Adsorption equilibrium time and optimum pH for Cr(VI) adsorption were found to be 6 h and 4.0, respectively. The Langmuir and Temkin isotherms were used to models adsorption equilibrium data. The adsorption capacity of NCFZC was found to be 1.33 mmol/g. Kinetic studies showed that the rate of adsorption of Cr(VI) on NCFZC obeyed a pseudo‐second‐order kinetic model.     

淹水解除后互叶白千层幼苗光合特性的恢复

为了优选用于河岸、库岸等间歇性淹水地区植被恢复的适生树种,研究了30d完全淹水解除后互叶白干层(Melaleuca alternifolia)幼苗气体交换特性、叶绿素荧光特性和质膜透性的恢复情况.在全淹30d及退水后70d的恢复生长过程中,互叶白干层成活率为100％.经过30d的全淹处理,互叶白干层的叶绿素含量、净光合...     

Numerical studies of methane production from Class 1 gas hydrate accumulations enhanced with carbon dioxide injection

Class 1 gas hydrate accumulations are characterized by a permeable hydrate-bearing interval overlying a permeable interval with mobile gas, sandwiched between two impermeable intervals. Depressurization-induced dissociation is currently the favored technology for producing gas from Class 1 gas hydrate accumulations. The depressurization production technology requires heat transfer from the surrounding environment to sustain dissociation as the temperature drops toward the hydrate equilibrium point and leaves the reservoir void of gas hydrate. Production of gas hydrate accumulations by exchanging carbon dioxide with methane in the clathrate structure has been demonstrated in laboratory experiments and proposed as a field-scale technology. The carbon dioxide exchange technology has the potential for yielding higher production rates and mechanically stabilizing the reservoir by maintaining hydrate saturations. We used numerical simulation to investigate the advantages and disadvantages of using carbon dioxide injection to enhance the production of methane from Class 1 gas hydrate accumulations. Numerical simulations in this study were primarily concerned with the mechanisms and approaches of carbon dioxide injection to investigate whether methane production could be enhanced through this approach. To avoid excessive simulation execution times, a five-spot well pattern with a 500-m well spacing was approximated using a two-dimensional domain having well boundaries on the vertical sides and impermeable boundaries on the horizontal sides. Impermeable over- and under burden were included to account for heat transfer into the production interval. Simulation results indicate that low injection pressures can be used to reduce secondary hydrate formation and that direct contact of injected carbon dioxide with the methane hydrate present in the formation is limited due to bypass through the higher permeability gas zone.     

Simultaneous solution for water,heat and salt balances in a Mediterranean coastal lagoon (Mar Menor,Spain)

A modelling approach is proposed to evaluate the environmental dynamics of coastal lagoons. The water, heat and salt balances are addressed simultaneously, providing a better estimation of evaporation and water exchanges. Compared to traditional approaches, the model presented accounts for the effects of water salinity, heat storage and net energy advected in the water body. The model was applied daily to the Mar Menor coastal lagoon (SE Spain) from 2003 through 2006. Water exchanges with the Mediterranean Sea were estimated based on the monthly trend of the lagoon salinity and were correlated with monthly averages of wind speed. The mean daily water exchange with the sea was 1.77 hm³ d⁻¹. This exchange accounted for only 1% of the heat losses in the lagoon heat balance, and it is the most important flow in the water balance. The mean annual evaporation flux amounted to 101.3 W m⁻² (3.55 mm d⁻¹), while the sensible heat flux amounted to 19.7 W m⁻², leading to an annual Bowen ratio on the order of 0.19. To validate the model, daily water temperatures were predicted based on the daily heat balance of the water body and were compared with remote sensing data from water surface standard products.     

Spatial variability and temporal dynamics of surface water pCO2, ��O2/Ar and dimethylsulfide in the Ross Sea, Antarctica

We report results from two surveys of pCO₂, biological O₂ saturation (??O₂/Ar) and dimethylsulfide (DMS) in surface waters of the Ross Sea polynya. Measurements were made during early spring (November 2006-December 2006) and mid-summer (December 2005-January 2006) using ship-board membrane inlet mass spectrometry (MIMS) for high spatial resolution (i.e. sub-km) analysis. During the early spring survey, the polynya was in the initial stages of development and exhibited a rapid increase in open water area and phytoplankton biomass over the course of our ∼3 week occupation. We observed a rapid transition from a net heterotrophic ice-covered system (supersaturated pCO₂ and undersaturated O₂) to a high productivity regime associated with a Phaeocystis-dominated phytoplankton bloom. The timing of the early spring phytoplankton bloom was closely tied to increasing sea surface temperature across the polynya, as well as reduced wind speeds and ice cover, leading to enhanced vertical stratification. There was a strong correlation between pCO₂, ??O₂/Ar, DMS and chlorophyll a (Chl a) during the spring phytoplankton bloom, indicating a strong biological imprint on gas distributions. Box model calculations suggest that pCO₂ drawdown was largely attributable to net community production, while gas exchange and shoaling mixed layers also exerted a strong control on the re-equilibration of mixed layer ??₂ with the overlying atmosphere. DMS concentrations were closely coupled to Phaeocystis biomass across the early spring polynya, with maximum concentrations exceeding 100 nM.During the summer cruise, we sampled a large net autotrophic polynya, shortly after the seasonal peak in phytoplankton productivity. Both diatoms and Phaeocystis were abundant in the phytoplankton assemblages during this time. Minimum pCO₂ was less than 100 ppm, while ??O₂/Ar exceeded 30% in some regions. Mean DMS concentrations were ∼2-fold lower than during the spring, although the range of concentrations was similar between the two surveys. There was a significant correlation between pCO₂, ??O₂/Ar and Chl a across the summer polynya, but the strength of these correlations and the slope of O₂ vs. CO₂ relationship were significantly lower than during the early spring. Summertime DMS concentrations were not significantly correlated to phytoplankton biomass (Chl a), pCO₂ or ??O₂/Ar. In contrast to the early spring time, there were no clear temporal trends in summertime gas concentrations. Rather, small-scale spatial variability, likely resulting from mixing and localized sea-ice melt, was clearly evident in surface gas distributions across the polynya. Analysis of length-scale dependent variability demonstrated that much of the spatial variance in surface water gases occurred at scales of <20 km, suggesting that high resolution analysis is needed to fully capture biogeochemical heterogeneity in this system.     

乐清湾水交换特征研究

采用EFDC模式模拟研究了乐清湾水交换的三维过程和时空变化特征,并通过计算水示踪剂质量浓度分析水体置换过程。结果表明,乐清湾水交换主要是由鹿西岛两侧流入的外海水体与湾内水体的交换,以及乐清湾口门西侧附近的湾内水体与瓯江北口径流冲淡水之间的交换。从口门到湾顶,水交换能力差别较大。以最窄的连屿至打水山断面为界,以南水体1个月基本可以完全交换,而以北水体2个月后仍然无法交换至湾口水平。连屿至打水山断面以北地形复杂,岛屿较多,污染物主要通过岛屿间的潮汐汊道输运,断面的瓶颈效应也使得断面以北的水体交换能力稍弱。在口门附近90%以上的水体被外海置换所需时间不到5 d,而此时湾顶水质未有太大改变;15 d左右,80%湾内水体被外海水置换;90%湾内水体被置换仅需40 d;70 d时的水体置换率达97%。     

浙江省入境旅游发展的空间非均衡性研究与启示

浙江省入境旅游发展势头强劲,但省内各地市间入境旅游发展却参差不齐,非均衡性空间特征显著。通过分析浙江省11个地市1999—2008年共10年的入境旅游外汇收入指标,引入标准差、相对发展率和波士顿矩阵等分析方法,归纳浙江省入境旅游发展空间非均衡基本特征,同时,对影响非均衡产生的经济社会条件、区位条件、资源环境等因子的变化趋势进行深入探究,提出浙江省入境旅游可以由非均衡发展逐步向均衡化方向发展的观点。最后,从浙江省资源整合、区域联动角度,提出了浙江省入境旅游均衡化发展的对策思路。     

黄河源区高寒草地-大气间水热交换通量特征

利用黄河源区玛曲观测站2016年涡动相关系统和微气象梯度塔观测资料,分析了高寒草地 大气间水热交换通量的特征。结果表明：夜间地表各通量值很小,净辐射和感热通量为负值,潜热通量的值较小但始终为正。日出后随着太阳辐射和地表加热作用各通量迅速增大,在14时左右达到峰值。暖季（6—8月）夜间感热通量占净辐射的比例(H/Rn)高于感潜通量占净辐射的比例(LE/Rn),日出后LE/Rn开始升高而H/Rn减小,日间LE/Rn大于H/Rn。冷季（12月—次年2月）H/Rn始终大于LE/Rn,感热通量在冷季的能量分配中占据主导地位。暖季LE/Rn、H/Rn均随土壤温度升高而升高。冷季H/Rn与5 cm深度土壤温度表现出了更为明显的二次关系,随着温度升高先降低后升高,当温度小于-7 ℃时H/Rn降低,大于-6 ℃时H/Rn增大。暖季H/Rn随着土壤湿度增大先降低后升高,LE/Rn先升高后降低。在0—1.5 kPa,暖季饱和水汽压差与LE/Rn、H/Rn均呈线性关系,并随着饱和水汽压差增大,LE/Rn增大而H/Rn减小;1.5 kPa之后,LE/Rn、H/Rn变化特征均保持其原有趋势。     

Fe-ZSM-5分子筛催化降解染料废水的研究

传统的Fenton均相亚铁盐催化剂处理染料废水,具有难以避免的二次污染和亚铁离子流失问题。分子筛催化剂相比传统催化剂具有高效环保的特点,在催化氧化染料废水领域有着良好的前景。本文通过液相离子交换法制备了Fe-ZSM-5非均相分子筛催化剂,替代传统的亚铁盐催化剂,应用X射线衍射对制备的Fe-ZSM-5分子筛催化剂进行表征,表明随离子交换次数的增加,Fe-ZSM-5催化剂负载的铁量上升,且较好地保持了分子筛结构,有利于提高亚铁离子的催化能力。通过实验确定了Fe-ZSM-5催化剂催化反应的最佳温度、pH值、Fe-ZSM-5的用量、反应时间等工艺参数,比较了Fe-ZSM-5催化剂和传统Fenton均相催化剂降解染料废水的脱色率和废水中铁离子的残留量,结果表明Fe-ZSM-5的脱色率达到98.5%,相比于Fenton均相催化剂的脱色率提升约3%;两种催化剂的铁离子残留量差别显著,Fe-ZSM-5催化剂处理的废水中只产生微量的Fe离子,可以认为Fe-ZSM-5非均相分子筛催化剂有效地解决了催化剂损耗和二次污染问题。