福建地下流体氟离子动态非地震前兆异常识别

2008年3—7月福建地区共发生4次中等地震,福建地下流体氟离子有多孔观测井,在震前或震后出现高值突跳的现象;2008年9-11月福建地下流体氟离子又有多孔观测井出现高值异常。本研究通过实验提出:该氟离子高值异常为非地震前兆异常,建议准备一支氟离子选择性电极作为备用电极,用于对比观测,以提高氟离子观测数据异常的判别。     

Ammonium adsorption by tidal flat surface sediments from the Yangtze Estuary

Ammonium adsorption by sediments plays an important role in the cycle of nitrogen in the estuarine tidal flat ecosystem. Ammonium adsorption on tidal flat sediments from the Yangtze estuary was studied using the simulation experiment. The findings indicated that there was linear adsorption by the tidal flat sediments for the lower ammonium concentration (<10 mM) in the overlying waters. The adsorption coefficient of ammonium in the study area ranged from 3.81 to 9.00, and had a significant positive correlation with total organic carbon (r = 0.779, = 0.02284 , n=8), reflecting that organic matter might be one of the main factors controlling the behavior of ammonium adsorption. It also showed that salinity had a pronounced effect on ammonium adsorption, and that salinity affected the distribution of ammonium between the sediments and waters. The amount of ammonium adsorption on sediments gradually decreased with the increasing salinity. Especially within the range of lower salinity, just a little change of salinity had a dramatic influence on ammonium adsorption by sediments.     

孔隙水中NH_4~+和HPO_4~(2-)浓度异常:一种潜在的天然气水合物地球化学勘查新指标

在海洋天然气水合物的勘查与研究中地球化学方法发挥了重大作用。利用海洋沉积物孔隙水中各种离子含量和同位素异常可以有效示踪天然气水合物的存在, 其中Cl-浓度异常、SO42-浓度梯度和氧同位素组成异常已成为指示天然气水合物存在的灵敏示踪剂。通过对比有和没有天然气水合物存在的海域浅表层沉积物中孔隙水的NH4+和HPO42-含量, 发现有天然气水合物区的孔隙水中NH4+和HPO42-浓度明显偏高, 且存在与SO42-类似的浓度梯度曲线, 认为孔隙水中NH4+和HPO42-浓度异常有可能成为一种新的地球化学示踪剂, 指示天然气水合物的存在; 探讨了引起孔隙水中NH +和HPO 2-浓度异常的可能机理及精确测定这些离子含量的方法。     

Species Composition and Seasonal Variations of the Gastropoda in Upper Sakarya River System (Turkey) in Relation to Water Quality

Species composition, abundance, and seasonal distribution of the Gastropoda fauna and the physical and chemical variables of Upper Sakarya River System have been investigated between October 1998 and August 1999. Gastropod fauna in the Upper Sakarya River System was represented by 9 species of Prosobranchia and 7 species of Pulmonata. Diversity, dominance, and abundance of the Gastropoda species were recorded seasonally. The abundance of some of the 16 species was correlated positively with temperature, dissolved oxygen and negatively or positively with pH and nitrate. It was observed that Gyraulus albus (Müller, 1774), Physa acuta Draparnaud, 1805, Valvata pulchella Studer, 1820, and Oxyloma elegans (Risso, 1826) can tolerate a high level of NO‐N while V. piscinalis (Müller, 1774) spread out in unpolluted water. Although the species and their numbers change at the stations, the maximum numbers were found during autumn, while minimums were identified during the winter sampling. Gyraulus albus was the most widespread species in our research area. Only 5 species (Gyraulus albus, Physa acuta, Valvata cristata (Muller, 1774), Valvata pulchella, Melanopsis praemorsa costata (Olivier, 1804)) were determined each season. However, no Gastropoda were found at the station 3 that has high BOD, NO‐N, NO‐N, and NH₃ levels.     

Low-temperature behaviour of ammonium ion in buddingtonite [N(D/H)<Subscript>4</Subscript>AlSi<Subscript>3</Subscript>O<Subscript>8</Subscript>] from neutron powder diffraction

The structural response of buddingtonite [N(D/H)₄AlSi₃O₈] on cooling has been studied by neutron diffraction. Data have been collected from 280 K down to 11 K, and the crystal structure refined using the Rietveld method. Rigid-body constraints were applied to the ammonium ion to explore the structural properties of ammonium in the M-site cavities at low-temperature. Low-temperature saturation is observed for almost all the lattice parameters. From the present in situ low-temperature neutron diffraction studies, there is no strong evidence of orientational order–disorder of the ammonium ions in buddingtonite.     

The role of vibrationally excited nitrogen and oxygen in the ionosphere over Millstone Hill during 16-23 March, 1990

We present a comparison of the observed behavior of the F region ionosphere over Millstone Hill during the geomagnetically quiet and storm period on 16/23 March, 1990, with numerical model calculations from the time-dependent mathematical model of the Earths ionosphere and plasmasphere. The effects of vibrationally excited N₂(v) and O₂(v) on the electron density and temperature are studied using the N₂(v) and O₂(v) Boltzmann and non-Boltzmann distribution assumptions. The deviations from the Boltzmann distribution for the first five vibrational levels of N₂(v) and O₂(v) were calculated. The present study suggests that these deviations are not significant at vibrational levels v = 1 and 2, and the calculated distributions of N₂(v) and O₂(v) are highly non-Boltzmann at vibrational levels v > 2. The N₂(v) and O₂(v) non-Boltzmann distribution assumption leads to the decrease of the calculated daytime NmF2 up to a factor of 1.44 (maximum value) in comparison with the N₂(v) and O₂(v) Boltzmann distribution assumption. The resulting effects of N₂(v > 0) and O₂(v) > 0) on the NmF2 is the decrease of the calculated daytime NmF2 up to a factor of 2.8 (maximum value) for Boltzmann populations of N₂(v) and O₂(v) and up to a factor of 3.5 (maximum value) for non-Boltzmann populations of N₂(v) and O₂(v). This decrease in electron density results in the increase of the calculated daytime electron temperature up to about 1040/1410 K (maximum value) at the F2 peak altitude giving closer agreement between the measured and modeled electron temperatures. Both the daytime and nighttime densities are not reproduced by the model without N₂(v > 0) and O₂(v > 0), and inclusion of vibrationally excited N2 and O2 brings the model and data into better agreement. The effects of vibrationally excited O2 and N2 on the electron density and temperature are most pronounced during daytime.     

A self-consistent estimate of O+ + N2– rate coefficient and total EUV solar flux with λ < 1050 Å using EISCAT observations

There are differences between existing models of solar EUV with < 1050 Å and between laboratory measurements of the O⁺ + N₂ – reaction rate coefficient, both parameters being crucial for the F2-region modeling. Therefore, indirect aeronomic estimates of these parameters may be useful for qualifying the existing EUV models and the laboratory measured O⁺ + N₂ – rate coefficient. A modified self-consistent method for daytime F2-region modeling developed by Mikhailov and Schlegel was applied to EISCAT observations (32 quiet summer and equinoctial days) to estimate the set of main aeronomic parameters. Three laboratory measured temperature dependencies for the O⁺ + N₂ – rate coefficient were used in our calculations to find self-consistent factors both for this rate coefficient and for the solar EUV flux model from Nusinov. Independent of the rate coefficient used, the calculated values group around the temperature dependence recently measured by Hierl et al. in the 850–1400 K temperature range. Therefore, this rate coefficient may be considered as the most preferable and is recommended for aeronomic calculations. The calculated EUV flux shows a somewhat steeper dependence on solar activity than both, the Nusinov and the EUVAC models predict. In practice both EUV models may be recommended for the F2-region electron density calculations with the total EUV flux shifted by ±25% for the EUVAC and Nusinov models, correspondingly.     

黄土-古土壤沉积物中酸溶相硼的分离及其同位素测定

用０．５ｍｏｌ／ＬＨＣｌ提取黄土、古土壤中的酸溶相成分,并用混合树脂法和硼特效树脂法两方法叠加以硼进行分离和纯化,Ｃｓ２ＢＯ２＾＋法测同位素比值。结果表明,虽然混合树脂法和硼特效脂法都是较成熟的方法,但用来处理杂质离子含量相对高而硼含量低的样品深液并不成功。两种方法叠加处理后达到理想的效果,重复处理黄土－古土壤样品的精度（２ＲＳＤ）在０．４‰～０．４‰之间,这与标样（ＮＩＳＴ ＳＲＭ９５１）水平（     

离子交换反应合成铅长石的实验研究

对长石与Pb(NO_3)_2粉末在380℃条件下反应48h的产物进行XRD分析,显示出现了d值分别为6.54、3.42、3.32、3.27,2.57的铅长石的5个特征峰。XPS分析表明Pb4f7/2在长石矿物中的结合能为138.39~138.44eV。实验证明Pb2 与长石结构中的碱性或碱土性离子发生了离子交换反应,生成了铅长石。     

Measurement of free heavy metal ion concentrations in soils using Donnan membrane technique

In natural systems heavy metals are present in very low concentrations (less than micro-molar) , so precise measurement of the free metal ions is difficult. Recently, a new method has been developed called the Donnan membrane technique (DMT). Several heavy metals could be measured simultaneously using this method. Furthermore, all the metals did not interfere with each other, and the balance between the measured system and the surrounding condition could not be disturbed. Improvements were made according to the internal condition. The free heavy metal ion concentrations were measured in different systems using the improved method, and satisfied results have been obtained.