Gas generation and expulsion characteristics of Middle–Upper Triassic source rocks,eastern Kuqa Depression,Tarim Basin,China: implications for shale gas resource potential

Frontier exploration in the Kuqa Depression, western China, has identified the continuous tight-sand gas accumulation in the Lower Cretaceous and Lower Jurassic as a major unconventional gas pool. However, assessment of the shale gas resource in the Kuqa Depression is new. The shale succession in the Middle–Upper Triassic comprises the Taliqike Formation (T₃t), the Huangshanjie Formation (T₃h) and the middle–upper Karamay Formation (T_2–3k), with an average accumulated thickness of 260 m. The high-quality shale is dominated by type III kerogen with high maturity and an average original total organic carbon (TOC) of about 2.68 wt%. An improved hydrocarbon generation and expulsion model was applied to this self-contained source–reservoir system to reveal the gas generation and expulsion (intensity, efficiency and volume) characteristics of Middle–Upper Triassic source rocks. The maximum volume of shale gas in the source rocks was obtained by determining the difference between generation and expulsion volumes. The results indicate that source rocks reached the hydrocarbon expulsion threshold of 1.1% VR and the hydrocarbon generation and expulsion reached their peak at 1.0% VR and 1.28% VR, with the maximum rate of 56 mg HC/0.1% TOC and 62.8 mg HC/0.1% TOC, respectively. The volumes of gas generation and expulsion from Middle–Upper Triassic source rocks were 12.02 × 10¹² m³ and 5.98 × 10¹² m³, respectively, with the residual volume of 6.04 × 10¹² m³, giving an average gas expulsion efficiency of 44.38% and retention efficiency of 55.62%. Based on the gas generation and expulsion characteristics, the predicted shale gas potential volume is 6.04 × 10¹² m³, indicating a significant shale gas resource in the Middle–Upper Triassic in the eastern Kuqa Depression.     

Response of detrital zircon and monazite,and their U–Pb isotopic systems,to regional metamorphism and host‐rock partial melting,Cooma Complex,southeastern Australia

Progressive Early Silurian low‐pressure greenschist to granulite facies regional metamorphism of Ordovician flysch at Cooma, southeastern Australia, had different effects on detrital zircon and monazite and their U–Pb isotopic systems. Monazite began to dissolve at lower amphibolite facies, virtually disappearing by upper amphibolite facies, above which it began to regrow, becoming most coarsely grained in migmatite leucosome and the anatectic Cooma Granodiorite. Detrital monazite U–Pb ages survived through mid‐amphibolite facies, but not to higher grade. Monazite in the migmatite and granodiorite records only metamorphism and granite genesis at 432.8 ± 3.5 Ma. Detrital zircon was unaffected by metamorphism until the inception of partial melting, when platelets of new zircon precipitated in preferred orientations on the surface of the grains. These amalgamated to wholly enclose the grains in new growth, characterised by the development of {211} crystal faces, in the migmatite and granodiorite. New growth, although maximum in the leucosome, was best dated in the granodiorite at 435.2 ± 6.3 Ma. The combined best estimate for the age of metamorphism and granite genesis is 433.4 ± 3.1 Ma. Detrital zircon U–Pb ages were preserved unmodified throughout metamorphism and magma genesis and indicate derivation of the Cooma Granodiorite from Lower Palaeozoic source rocks with the same protolith as the Ordovician sediments, not Precambrian basement. Cooling of the metamorphic complex was relatively slow (average ～12°C/10⁶y from ～730 to ～170°C), more consistent with the unroofing of a regional thermal high than cooling of an igneous intrusion. The ages of detrital zircon and monazite from the Ordovician flysch (dominantly composite populations 600–500 Ma and 1.2–0.9 Ga old) indicate its derivation from a source remote from the Australian craton.     

Accounting for sparsely observed rainfall space—time variability in a rainfall—runoff model of a semiarid Tunisian basin/Prise en compte d'observations peu denses de la variabilité spatiotemporelle de la pluie dans une modélisation pluie—débit d'un bassin semi-aride Tunisien

Abstract

The management of water excesses and deficits is a major task in semiarid Mediterranean regions, where the variability of rainfall inputs is high at different time and space scales. Thus intense hydrometeorological events, which generate both potential resource and hazards, are of major interest. A simple method is proposed, with the example of the Skhira basin (192 km²) in central Tunisia, to account for the event space–time variability of rainfall in a rainfall–runoff model, in order to check its influence on the shape, magnitude and timing of resulting hydrographs. The transfer function used is a geomorphology-based unit hydrograph with an explicit territorial significance. Simulations made for highly variable events show the relevance of this method, seen as the first step of a downward approach, and its robustness with respect to the quality and the density of rainfall data.     

Genetic and ore-forming ages of the Fe–P–(Ti) oxide deposits associated with mafic–ultramafic–carbonatite complexes in the Kuluketage block,NW China

Abstract

During the past 50 years, many geological and ore-deposit investigations have led to the discovery of the Fe–P–(Ti)-oxide deposits associated with mafic–ultramafic–carbonatite complexes in the Kuluketage block, northeastern Tarim Craton. In this paper, we discuss the genetic and ore-forming ages, tectonic setting, and the genesis of these deposits (Kawuliuke, Qieganbulake and Duosike). LA-ICP-MS zircon U–Pb dating yielded a weighted mean ²⁰⁶Pb/²³⁸U ages of 811?±?5?Ma, 811?±?4?Ma, and 840?±?5?Ma for Kawuliuke ore-bearing pyroxenite, Qieganbulake gabbro and Duosike ore-bearing pyroxenite, respectively. The CL images of the Kawuliuke apatite grains show core–rim structure, suggesting multi-phase crystallisation, whereas the apatite grains from Qieganbulake and Dusike deposits do not show any core–rim texture, suggesting a single-stage crystallisation. LA-ICP-MS apatite ²⁰⁷Pb-corrected U–Pb dating provided weighted mean ²⁰⁶Pb/²³⁸U ages of 814?±?21?Ma and 771?±?8?Ma for the Kawuliuke ores, and 810?±?7?Ma and 841?±?7?Ma for Qieganbulake and Duosike ores, respectively. The core–rim texture in apatite by CL imaging as well as two different ore-forming ages in the core and rim of the apatite indicate two metallogenic events for the Kawuliuke deposit. The first metallogenic period was magmatic in origin, and the second period was hydrothermal in origin. The initial ore-forming age of the Kawuliuke Fe–P–Ti mineralisation was ca 814?Ma and the second one was ca 771?Ma. On the other hand, the ore-forming ages of the Qieganbulake and Duosike deposits were ca 810?Ma and ca 841?Ma, respectively. Qieganbulake and Duosike deposits were of magmatic origin. Combined with previous geochronological data and the research on the tectonic background, we infer that the Kawuliuke, Qieganbulake and Duosike Fe–P–(Ti)-oxide deposits were formed in a subduction-related tectonic setting and were the product of subduction-related magmatism.     

Wildfire preparedness,community cohesion and social–ecological systems

The consequences of wildfires are felt in susceptible communities around the globe on an annual basis. Climate change predictions in places like the south-east of Australia and western United States suggest that wildfires may become more frequent and more intense with global climate change. Compounding this issue is progressive urban development at the peri-urban fringe (wildland–urban interface), where continued infrastructure development and demographic changes are likely to expose more people and property to this potentially disastrous natural hazard. Preparing well in advance of the wildfire season is seen as a fundamental behaviour that can both reduce community wildfire vulnerability and increase hazard resilience – it is an important element of adaptive capacity that allows people to coexist with the hazardous environment in which they live. We use household interviews and surveys to build and test a substantive model that illustrates how social cohesion influences the decision to prepare for wildfire. We demonstrate that social cohesion, particularly community characteristics like ‘sense of community’ and ‘collective problem solving’, are community-based resources that support both the adoption of mechanical preparations, and the development of cognitive abilities and capacities that reduce vulnerability and enhance resilience to wildfire. We use the results of this work to highlight opportunities to transfer techniques and approaches from natural hazards research to climate change adaptation research to explore how the impacts attributed to the social components of social–ecological systems can be mitigated more effectively.     

North Atlantic climate impact on early late‐glacial climate oscillations in the south‐eastern Alps inferred from a multi‐proxy lake sediment record

High‐resolution multi‐proxy analyses of a sediment core section from Lake Jeserzersee (Saissersee) in the piedmont lobe of the Würmian Drau glacier (Carinthia, Austria) reveal pronounced climatic oscillations during the early late glacial (ca. 18.5–16.0k cal a BP). Diatom‐inferred epilimnetic summer water temperatures show a close correspondence with temperature reconstructions from the adjacent Lake Längsee record and, on a hemispheric scale, with fluctuations of ice‐rafted debris in the North Atlantic. This suggests that North Atlantic climate triggered summer climate variability in the Alps during the early late glacial. The expansion of pine (mainly dwarf pine) between ca. 18.5 and 18.1k cal a BP indicates warming during the so‐called ‘Längsee oscillation’. The subsequent stepwise climate deterioration between ca. 18.1 and 17.6k cal a BP culminated in a tripartite cold period between ca. 17.6 and 16.9k cal a BP with diatom‐inferred summer water temperatures 8.5–10 °C below modern values and a shift from wet to dry conditions. This period probably coincides with a major Alpine glacier advance termed the Gschnitz stadial. A warmer interval between ca. 16.9 and 16.4k cal a BP separates this cold phase from a second, shorter and less pronounced cold phase between ca. 16.4 and 16.0k cal a BP, which is thought to correlate with the Clavadel/Senders glacier advance in the Alps. The following temperature increase, coupled with wet (probably snow‐rich) conditions, caused the expansion of birch during the transition period to the late glacial interstadial. Copyright © 2011 John Wiley & Sons, Ltd.     

Mineral composition variation in Alpine Schist, Southern Alps, New Zealand: Implications for recrystallization and exhumation

Abstract Compositional variation of silicates (plagioclase, K-feldspar, epidote, titanite, garnet, white mica, biotite, chlorite), ilmenite, carbonates (calcite, ankerite) and apatite, in quartzofeldspathic lithologies of the Alpine Schist, New Zealand, is discussed in terms of increasing metamorphic grade and possible isograd-producing reactions. The mineral data, in conjunction with geological considerations, are used to determine polychronous P-T arrays of an early high P/T event (c. 16°C/kb; 5°C/km) overprinted by a lower P/T event (c. 50°C/kb; 15°C/km) that provides an estimation of Mesozoic and Cenozoic exhumation of schist of 11 to 13 km and 19 to 22 km respectively. The effects of possible shear heating and recrystallization to form K-feldspar zone schist near the Alpine Fault is consistent with movement along a mid to lower crustal detachment surface during Cenozoic shortening, and near isothermal exhumation of the schists to form the Southern Alps.     

Diurnal freeze–thaw depth in rockwalls: Field measurements and theoretical considerations

Rock temperatures were monitored for a year at two alpine rockwalls in the Akaishi Range, Japan, where permafrost is absent. Diurnal frost and thaw penetration depths were evaluated from subsurface isotherms drawn on the basis of the temperature records at 0, 10 and 40 cm depths. The surface of the rockwalls experienced more than 100 diurnal freeze-thaw cycles, most of which accompanied a frost or thaw penetration shallower than 50 cm, and several long duration cycles with deeper frost or thaw penetration. Theoretical frost and thaw depths were also calculated by incorporating the surface freezing indices into the modified Berggren equation, the results from which were then compared with the actual values. The modified Berggren equation provided values that showed a strong correlation with observed depths, despite somewhat underestimating the actual values. Using the modified Berggren equation, the seasonal frost depth in the observed winter was estimated to be about 4·5 m. The frost and thaw depths are considered to give the maximum estimation of the depth to which frost-induced cracking can propagate in the bedrock.     

The rate of bedrock weathering by frost action: Field measurements and a predictive model

Shattering rate, surface temperature, moisture content, and the physical and strength properties of bedrock were measured in four rockwall sites of the Japanese Alps. Five-year observations revealed that the bedrock shattering rate was usually much higher in the freeze-thaw period from October to next May than in the frost-free period from June to September. This indicates that frost action is the most important shattering process, although unusual heavy rainstorms in summer are also responsible for the shattering. A combination of some empirical relationships derived from recent laboratory experiments leads to a predictive model of the frost shattering rate. This model shows that the annual shattering rate is dependent on the annual freeze-thaw frequency on the rock surface, and the degree of saturation and tensile strength of the rock masses. The coefficients involved in the model were determined using the field data.