1998年春夏南海温盐结构及其变化特征

利用1998年5～8月“南海季风试验”期间“科学1”号和“实验3”号科学考察船两个航次CTD资料,分析了1998年南海夏季风暴发前后南海主要断面的温盐结构及其变化特征.观测发现,南海腹地基本被典型的南海水团所控制,但在南海东北部尤其是吕宋海峡附近,表层和次表层水明显受到西太平洋水的影响.季风暴发以后,南海北部表面温度有显著升高,升幅由西向东递减,而南海中部和南部表面温度基本没变,这使得南海北部东西向温度梯度和整个海盆南北向温度梯度均减小.北部断面表层盐度普遍由34以上降低到34以下,混合层均有所发展,是季风暴发后降水和风力加剧的结果.观测期间黑潮水跨越吕宋海峡的迹象明显但变化剧烈.4～5月,黑潮次表层水除在吕宋海峡中北部出现外,在吕宋岛以西亦有发现,表明有部分黑潮水从吕宋海峡南端沿岸向西进而向南进入南海.6～7月,次表层高盐核在吕宋海峡中北部有极大发展,但在吕宋岛以西却明显萎缩;虽然看上去黑潮水以更强的流速进、出南海,但对南海腹地动力热力结构的影响未必更大.一个超过34.55的表层高盐水体于巴拉望附近被发现,似与通过巴拉望两侧水道入侵南海的西太平洋水有关.     

南海北部海区上层水体平均声速场的变化

对所收集到的南海北部海区的温度、盐度和深度历史资料进行了声速的计算、统计与分析,结果表明该海区上层水体的平均声速场有较明显的年际变化:表层声速的平面分布显示出沿岸水与外海水强弱交替变化的特征,声速等值线的走向几乎与岸线平行,等声速线的值自近岸向外海增加,大陆架外缘海区声速的水平梯度较大;下层声速的分布以环流和水体共同作用的形式出现,50m层声速平面分布的趋势除冬季与表层稍为相似外,其余季节与表层有明显的差别,春、夏季节50m层声速自西向东增加,而秋季与其表层分布相反,自近岸向外海减小;声速的垂直分布受海水升温与降温的影响显著,春、夏季表层海水升温,海表声速最大,声速自海表随深度的增加而减小;秋、冬季表层附近水层降温,声速稍偏低,普遍出现正梯度现象,最大声速移至表层以下的水层,这个深度随季节的改变而改变,随海区的不同而不同.该海区的平均声速有年波动现象,表层波幅最大,随深度的增加波幅变小,至100m水层其波动的位相几乎与表层相反.     

煤炭资源勘查误差理论研究

对煤炭资源勘查资源量与客观物质量之间差值的误差理论探讨,提出误差由真值误差、系统误差和离差3个基本部分组成,其中真值误差是不可消除的观测误差、系统误差是控制网度所决定的准确度标准、而离差是由地质构造及矿床形态的多解性产生的资源量波动。在此基础上,构筑了一个关于误差的数学模型,最后应用误差理论对现行勘查工作中常见的错误进行分析,并就如何避免错误及减少误差提出了见解。     

Rare Earth Deposits of North America

Rare earth elements (REE) have been mined in North America since 1885, when placer monazite was produced in the southeast USA. Since the 1960s, however, most North American REE have come from a carbonatite deposit at Mountain Pass, California, and most of the world’s REE came from this source between 1965 and 1995. After 1998, Mountain Pass REE sales declined substantially due to competition from China and to environmental constraints. REE are presently not mined at Mountain Pass, and shipments were made from stockpiles in recent years. Chevron Mining, however, restarted extraction of selected REE at Mountain Pass in 2007. In 1987, Mountain Pass reserves were calculated at 29 Mt of ore with 8.9% rare earth oxide based on a 5% cut‐off grade. Current reserves are in excess of 20 Mt at similar grade. The ore mineral is bastnasite, and the ore has high light REE/heavy REE (LREE/HREE). The carbonatite is a moderately dipping, tabular 1.4‐Ga intrusive body associated with ultrapotassic alkaline plutons of similar age. The chemistry and ultrapotassic alkaline association of the Mountain Pass deposit suggest a different source than that of most other carbonatites. Elsewhere in the western USA, carbonatites have been proposed as possible REE sources. Large but low‐grade LREE resources are in carbonatite in Colorado and Wyoming. Carbonatite complexes in Canada contain only minor REE resources. Other types of hard‐rock REE deposits in the USA include small iron‐REE deposits in Missouri and New York, and vein deposits in Idaho. Phosphorite and fluorite deposits in the USA also contain minor REE resources. The most recently discovered REE deposit in North America is the Hoidas Lake vein deposit, Saskatchewan, a small but incompletely evaluated resource. Neogene North American placer monazite resources, both marine and continental, are small or in environmentally sensitive areas, and thus unlikely to be mined. Paleoplacer deposits also contain minor resources. Possible future uranium mining of Precambrian conglomerates in the Elliott Lake–Blind River district, Canada, could yield by‐product HREE and Y. REE deposits occur in peralkaline syenitic and granitic rocks in several places in North America. These deposits are typically enriched in HREE, Y, and Zr. Some also have associated Be, Nb, and Ta. The largest such deposits are at Thor Lake and Strange Lake in Canada. A eudialyte syenite deposit at Pajarito Mountain in New Mexico is also probably large, but of lower grade. Similar deposits occur at Kipawa Lake and Lackner Lake in Canada. Future uses of some REE commodities are expected to increase, and growth is likely for REE in new technologies. World reserves, however, are probably sufficient to meet international demand for most REE commodities well into the 21st century. Recent experience shows that Chinese producers are capable of large amounts of REE production, keeping prices low. Most refined REE prices are now at approximately 50% of the 1980s price levels, but there has been recent upward price movement for some REE compounds following Chinese restriction of exports. Because of its grade, size, and relatively simple metallurgy, the Mountain Pass deposit remains North America’s best source of LREE. The future of REE production at Mountain Pass is mostly dependent on REE price levels and on domestic REE marketing potential. The development of new REE deposits in North America is unlikely in the near future. Undeveloped deposits with the most potential are probably large, low‐grade deposits in peralkaline igneous rocks. Competition with established Chinese HREE and Y sources and a developing Australian deposit will be a factor.     

Zircon M257 ‐ a Homogeneous Natural Reference Material for the Ion Microprobe U‐Pb Analysis of Zircon

We introduce and propose zircon M257 as a future reference material for the determination of zircon U‐Pb ages by means of secondary ion mass spectrometry. This light brownish, flawless, cut gemstone specimen from Sri Lanka weighed 5.14 g (25.7 carats). Zircon M257 has TIMS‐determined, mean isotopic ratios (2s uncertainties) of 0.09100 ± 0.00003 for ²⁰⁶pb/²³⁸U and 0.7392 ± 0.0003 for ²⁰⁷pb/²³⁵U. Its ²⁰⁶pb/²³⁸U age is 561.3 ± 0.3 Ma (unweighted mean, uncertainty quoted at the 95% confidence level); the U‐Pb system is concordant within uncertainty of decay constants. Zircon M257 contains ～ 840 μg g^?1 U (Th/U ～ 0.27). The material exhibits remarkably low heterogeneity, with a virtual absence of any internal textures even in cathodoluminescence images. The uniform, moderate degree of radiation damage (estimated from the expansion of unit‐cell parameters, broadening of Raman spectral parameters and density) corresponds well, within the “Sri Lankan trends”, with actinide concentrations, U‐Pb age, and the calculated alpha fluence of 1.66 × 10¹⁸ g^?1. This, and a (U+Th)/He age of 419 ± 9 Ma (2s), enables us to exclude any unusual thermal history or heat treatment, which could potentially have affected the retention of radiogenic Pb. The oxygen isotope ratio of this zircon is 13.9%o VSMOW suggesting a metamorphic genesis in a marble or calc‐silicate skarn.     

The Epi－continental arc of Southeast China and relevant earthquakes

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Seasonal variations of atmospheric sulfur dioxide and dimethylsulfide concentrations at Amsterdam Island in the southern Indian Ocean

Daily measurements of atmospheric sulfur dioxide (SO₂) concentrations were performed from March 1989 to January 1991 at Amsterdam Island (37°50 S–77°30 E), a remote site located in the southern Indian Ocean. Long-range transport of continental air masses was studied using Radon (²²²Rn) as continental tracer. Average monthly SO₂ concentrations range from less than 0.2 to 3.9 nmol m^-3 (annual average = 0.7 nmol m^-3) and present a seasonal cycle with a minimum in winter and a maximum in summer, similar to that described for atmospheric DMS concentrations measured during the same period. Clear diel correlation between atmospheric DMS and SO₂ concentrations is also observed during summer. A photochemical box model using measured atmospheric DMS concentrations as input data reproduces the seasonal variations in the measured atmospheric SO₂ concentrations within ±30%. Comparing between computed and measured SO₂ concentrations allowed us to estimate a yield of SO₂ from DMS oxidation of about 70%.     

The concentration and distribution of different mercury species in the water columns and sediment of Aha Lake

In order to find out whether Aha Lake was polluted by the acid mining waste water or not, the concentration and distribution of different mercuryspecies in the water columns and sediment profile collected from Aha Lake were investigated. It was found that discernible seasonal variation of different mercury species in water body were obtained in the Aha Reservoir. With regards to the whole sampling periods, the concentrations of HgP in the Aha Reservoir water body were evidently correlated to the concentrations of total mercury, showing that total mercury was mostly associated with particle mercury. The concentrations of methylmercury in water body were also evidently correlated to the concentrations of dissolved mercury. The dissolved mercury evidently affects the distribution and transportation of methylmercury. However, there is no correlation between methylmercury and total mercury. The dissolved mercury, reactive mercury, dissolved methylmercury levels in the water body of high flow period were much higher than those in low flow period. The distribution, speciation and levels of mercury within the Aha Reservoir water body were governed by several factors, such as the output of river, the release of sediment . Discernible seasonal variation of total mercury and methylmercury in porewater was described during the sampling periods, with the concentrations in high flow period generally higher than those in low flow period. The methylmercury in pore water column was evidently correlated to that of the sediment. The results indicated that highly elevated MeHgD concentrations in the porewater were produced at the depths from 2 to 5 cm in the sediment profile, and decreased sharply with depth. A positive correlation has been found between MeHgD formation and sulfate reducing bacterial activity. These highly elevated concentrations of MeHgD at the intersurface between waters and sediments suggest a favorable methylation condition. Moreover,     

Response of Ruppia maritima to the reclaimed wastewater in coastal artificial landscape river

In recent years, reclaimed wastewater as a water source for urban artificial landscape rivers is being rapidly developed in some coastal cities with limited water resource available in China. However, eutrophication occurs more often in the landscape waterbody with reclaimed wastewater than in natural rivers and lakes. The study of restoration and reconstruction of macrophytes, especially the submerged aquatic vegetation, is essential to inhibit eutrophication of reclaimed wastewater. This study investigated the seasonal variation of biomass of Ruppia maritima in the artificial landscape river using reclaimed wastewater as the only water source in Tianjin, China. It was found that there were two seasonal growth peaks of Ruppia maritima each year in the coastal reclaimedwastewater. The contents of nitrogen and phosphorus of Ruppia maritima varied with the season.     

A comparative error analysis of manual versus automated methods of data acquisition for algebraic strain estimation

This paper presents a statistical analysis of the algebraic strain estimation algorithm of Shimamoto and Ikeda [Shimamoto, T., Ikeda, Y., 1976. A simple algebraic method for strain estimation from deformed eillipsoidal objects: 1. Basic theory. Tectonophysics 36, 315–337]. It is argued that the error in their strain estimation procedure can be quantified using an expected discrepancy measure. An analysis of this measure demonstrates that the error is inversely proportional to the number of clasts used. The paper also examines the role of measurement error, in particular that incurred under (i) a moment based and (ii) manual data acquisition methods. Detailed analysis of these two acquisition methods shows that in both cases, the effect of measurement error on the expected discrepancy is small relative to the effect of the sample size (number of objects). Given their relative speed advantage, this result favours the use of automated measurement methods even if they incur more measurement error on individual objects. Validation of these results is carried out by means of a simulation study, as well as by reference to studies appearing in previous literature. The results are also applied to obtain an upper bound on the error of strain estimation for various studies published in the literature on strain analysis.