Petrogenesis of extension-related alkaline volcanism in Karaburhan (Sivrihisar–Eskisehir), NW Anatolia, Turkey

Alkaline lavas were erupted as phonolites and trachytes around Karaburhan (Sivrihisar–Eskisehir, NW Anatolia) within the Izmir–Ankara–Erzincan suture zone. These volcanic rocks were emplaced as domes, close and parallel to the ophiolite thrust line. According to ⁴⁰Ar/³⁹Ar geochronological analyses of sanidine crystals from the phonolites, the age of the alkaline volcanics is 25 Ma (Late Oligocene–Early Miocene).The flow-textured phonolites are porphyritic and consist mainly of sanidine, clinopyroxene, and feldspathoid crystals. The clinopyroxenes show compositional zoning, with aegirine (Na_0.82–0.96Fe⁺³_0.68–0.83) rims and aegirine–augite cores (containing calcium, magnesium, and Fe⁺²). Some aegirine–augites are replaced with sodium-, calcium-, and magnesium-rich amphibole (hastingsite). Feldspathoid (hauyne) crystals enriched with elemental Na and Ca have been almost completely altered to zeolite and carbonate minerals. The fine-grained trachytes with a trachytic texture consist of feldspar (oligoclase and sanidine) phenocrystals and clinopyroxene microphenocrystals within a groundmass made up largely of alkali feldspar microlites.Although there are some differences in their element patterns, the phonolites and trachytes exhibit enrichment in LILEs (Sr, K, Rb, Ba, Th) and LREEs (La, Ce, Pr, Nd) and negative anomalies in Nb and Ta. These geochemical characteristics indicate a lithospheric mantle enriched by fluids extracted from the subduction component. In addition, the high ⁸⁷Sr/⁸⁶Sr (0.706358–0.708052) and low ¹⁴³Nd/¹⁴⁴Nd (0.512546–0.512646) isotope concentrations of the alkaline lavas reflect a mantle source that has undergone metasomatism by subduction-derived fluids. Petrogenetic modeling indicates that the alkaline lavas generated from the subduction-modified lithospheric mantle have undergone assimilation, fractional crystallization, and crustal contamination, acquiring high Pb, Ba, Rb, and Sr contents and Pb isotopic compositions during their ascent through the thickened crust in an extensional setting.     

Microscopy and rock magnetism of fine grain-size titanomagnetite from the Jacupiranga Alkaline Complex,Brazil: unearthing Ti-magnesioferrite nanoparticles

Very fine samples from the mineralized zones of the Jacupiranga complex at the Cajati mine were selected for crystallographic identification of Ti-magnesioferrite (TMf) nanostructures embedded in titanomagnetite (TM) using high-resolution transmission electron microscopy (TEM). A magnetic concentrate obtained of pyroxenite samples (sites 4 to 7) was reduced and divided into fractions of distinct range sizes: 26±2 μm, 19±1 μm, 13±1 μm, 9±1 μm, 6±1 μm and 6-0.1 μm. The mineralized samples of carbonatite and pyroxenite were characterized by X-ray diffraction, transmitted and reflected light microscope, and scanning electron microscope with multielemental analysis. The finest magnetic concentrate sample (MC₆) was analyzed under high-resolution transmitted electron microscopy (TEM) and high angle annular dark field and Raman spectroscopy. Magnetic properties were measured for the distinct granulometric fractions, showing drastic changes when grain sizes go beyond the frontier from micro to nanometer sizes. Frequency-dependent magnetic susceptibility percentage (÷_fd%) report higher values (10.2%) for the finer fractions (6±1 μm and 6-0.1 μm) attributed to dominant fractions of superparamagnetic particles. Nanometer and < 6 μm grain size TMf in TM particles require a magnetic field up to 249 mT to reach saturation during the isothermal remanent magnetization experiment. Coercivity and remanent magnetization of these samples increase when the particle size decreases, probably due to parallel coupling effects. Magnetic susceptibility versus temperature experiments were conducted two times on the same (< 35 nm) sample, showing that the repetition during the second heating is probably due to the formation of new TMf nanoparticles and growth of those already present during the first heating process.     

Ecological significance of alkaline phosphatase activity and phosphatase-hydrolyzed phosphorus in the northern part of Gamak Bay, Korea

We investigated the ecological significance of alkaline phsophatase (APase) and alkaline phosphatase-hydrolyzable phosphorus (APHP) in the northern part of Gamak Bay, Korea. APase activity was detectable throughout the year, and dissolved inorganic phosphorus (DIP) concentration and APase activity are highly correlated and can be regarded as an indicator of DIP-limiting conditions. Also, a strong linear positive correlation between APase activity and Chl a concentration indicated that the major part of APase activity may have been induced by phytoplanktons. The APHP proportion in dissolved organic phosphorus (DOP) was above ca. 30% from winter to spring and below ca. 15% from summer to autumn due to freshwater discharge and uptake by phytoplankton. APHP may play an important role in species competition in coastal area such as northern part of Gamak Bay where DIP is limiting. Thus, APase induction by phytoplanktons may be ecologically significant, allowing dominance by these organisms under DIP-limiting conditions.     

西藏甲玛铜多金属矿区成矿斑岩的岩浆混合作用:石英及长石斑晶新证据

西藏甲玛矿区斑岩内石英和长石斑晶的阴极发光(CL)特征及元素含量变化有效记录了岩浆演化、混合及补给事件.石英斑晶的显微生长结构表明,原始岩浆经历过2次铁镁质岩浆混合作用.根据石英斑晶中Ti含量的变化可知,在2次溶蚀前后,石英结晶温度分别增高了约110℃和80℃.此外,斜长石斑晶的反环带及其Ba、Sr、Fe等元素的浓度梯...     

福建云霄晶洞花岗岩及含石榴子石伟晶岩的硅氧同位素研究

在运用常规方法和激光烧蚀同位素分析方法分别对云霄晶洞花岗岩和伟晶岩(长石、石英和石榴子石)的硅、氧同位素组成进行研究的基础上,探讨了晶涧花岗岩及其含石榴子石伟晶岩的物质来源及形成条件.伟晶岩中的石英和长石的氧、硅同位素组成分别较之花岗岩中的石英和长石的氧、硅同位素组成,均未发生明显变化,表明二者岩浆来源一致.云霄县的乌...     

Heating Stage Experimental Study of Melt Inclusions in Feldspars from Three Holocene Eruptions of Changbaishan Tianchi Volcano

There occurred several eruptions from Changbaishan Tianchi volcano in Holocene, and at least three of them were believed to be true according to the formal studies. The products of three eruptions were yellow comenditic pumice of - 5000a B.P. （Eruption Ⅰ ）, gray comenditic pumice and pyroclastic flow of - 1000a B.P. （ Eruption II, i.e. the millennium explosive eruption）, black trachy pumice and welded tuff of - 300a B.P. （ Eruption Ⅲ ） respectively. There were a large number of melt inclusions found in phenocrysts, which differ in size and color. The Leitz 1350 heating stage experiments for melt inclusions in host feldspars from three Holocene eruptions of Changbaishan Tianchi volcano imply that there were little differences between the homogenization temperatures of melt inclusions from Eruptions Ⅰ and Ⅲ, whereas it was rather complicated for Eruption H, i.e. there might be two kinds of melt with different homogenization temperature periods, which gave the evidence for the assumption that the explosive millennium eruption of Tianchi volcano was triggered by injection and mixing of two different magmas. The experimental results also indicate that （ 1 ） small melt inclusion is easy to be homogenized, while the large one, especially the one with lots of daughter crystals, is rather difficult to be homogenized; （2） homogenization temperature closely correlates with the size of melt inclusion within host crystal, with the temperature point switching from high heating rate to low heating rate, and correlates with whether it is the first time to obtain homogenization as well; and （3） a melt inclusion can get different homogenization temperatures when it is repeatedly heated. Even more, the next homogenization temperature is usually higher than the former one, which testifies the phenomenon that hydrogen migration occurs during repeated heating.     

安徽省风化花岗岩资源的开发与利用

介绍了安徽省风化花岗岩资源,通过提取钾长石矿物原料,生产免烧砖的改良土壤等途径,更好地解决开发利用风化花岗岩资源的问题,提出合理开发和保护风化花岗岩资源的建议。     

东营凹陷北部沙河街组四段深部储层多重成岩环境及演化模式

主要通过薄片鉴定、扫描电镜观察、包裹体分析、粘土矿物分析、镜质体反射率测试和岩心物性分析等手段,结合构造发育史和有机质热演化史等研究成果,以揭示东营凹陷北带古近系深部碎屑岩储层成岩环境及演化模式为目的展开研究工作。结果表明:东营凹陷北带古近系深部碎屑岩储层存在酸性、碱性和酸性碱性交替等多重成岩环境。酸性成岩环境以碳酸盐矿物溶解、长石溶解蚀变为高岭石并伴生石英次生加大等为标志,碱性成岩环境以石英质颗粒及其次生加大边溶解、长石次生加大和晚期碳酸盐矿物沉淀为标志。研究区古近系深部碎屑岩储层成岩环境由浅至深大致经历了碱性—酸性—酸性碱性交替(局部碱性较强)—碱性—弱碱性的演化过程,并建立了沙河街组四段的成岩演化和储层改造模式。     

内蒙古东七一山碱长花岗岩的地球化学特征和成因

东七一山碱长花岗岩是内蒙古北山地区规模最大的稀有金属矿化花岗岩,本文在前期岩石学及成矿特征研究基础上,首次对其岩石地球化学、同位素地球化学及年代学进行了分析探讨。岩石富硅、富碱,贫Ti、Fe、Mg、Mn等基性组分,属高钾钙碱性系列岩石。稀土元素配分模式显示Eu强亏损特征,δEu<0.1,Ba、Sr、P、Ti相对地幔显著亏损,而Rb、Nb+Ta、W、Mo、Li等元素明显富集。两类碱长花岗岩的Rb-Sr等时线年龄为128.2±1.1 Ma,相关系数为0.999 9,ISr=0.709 79,说明岩体的物质来源具有明显的壳源特征。147Sm/144Nd值相对亏损地幔值偏高,而143Nd/144Nd值偏低,Pb同位素以富含放射性成因铅为特征。结合岩石学和产出环境研究成果,认为该碱长花岗岩是在燕山晚期,由区域钾长花岗岩浆在壳层挤压-拉伸环境中进一步分异演化形成的,先形成的是碱长花岗斑岩,构成了似斑状碱长花岗岩的外部相,而似斑状碱长花岗岩是在相对封闭且挥发组分和稀有元素进一步富集、结晶分异较缓慢的过程中形成的,由残余流体产生的自交代作用也相对更发育,导致形成与锂云母化、次生钠长石化和硅化关系更密切的铌-钽、钨、锡、铷等稀有金属矿化。以上认识对在北山地区寻找与中生代花岗岩浆活动有关的金属矿产,特别是铌-钽、钨、锡、铷、钼矿产,具有重要的指导意义。     

康滇地轴中南段铀成矿条件及远景分析

本文对康滇地轴中南段铀矿化划分出３种类型（砂岩型、钠交代岩型和元古代浅变质岩型），并阐明其主要特征。提出了元古代地壳演化曾经历了原始古陆形成阶段、沉降活动阶段和基底再团结阶段，认为中元古界昆阳群是有别于典型的含铀碳硅泥岩沉积建造。通过对该区部分岩石原始铀含量进行研究，提出了有关岩石可作为该区铀源岩的新认识；划分出碱性和酸性两大类型的热液蚀变，指出本区以发育碱性蚀变地段的成矿前景较好。指出该区铀成矿前景：（１）该区不具备形成澳加式元古代不整合面型铀矿床的地质条件；（２）非澳加式元古代不整合面型的铀成矿前景较差；（３）本区碱（钠）交代岩型铀矿化具有一定的找矿前景。