佘山地磁台百年磁暴（二）——极大磁暴分析

本文是佘山地磁台百年磁暴的第二部分,对其极大磁暴（主相ΔH≥400 nT）进行分析.通过与其他三组由不同地磁活动指数定义的极大磁暴对比,表明佘山台用主相幅度差对极大磁暴的定义与之基本相符.同时结合几个典型磁暴,对磁暴与太阳风、行星际磁场和电离层之间的关系进行了讨论.     

Low‐P and high‐T metamorphism of basalts: Insights from the Sudbury impact melt sheet aureole and thermodynamic modelling

Low‐pressure and high‐temperature (LP–HT) metamorphism of basaltic rocks, which occurs globally and throughout geological time, is rarely constrained by forward phase equilibrium modelling, yet such calculations provide valuable supplementary thermometric information and constraints on anatexis that are not possible to obtain from conventional thermometry. Metabasalts along the southern margin of the Sudbury Igneous Complex (SIC) record evidence of high‐grade contact metamorphism involving partial melting and melt segregation. Peak metamorphic temperatures reached at least ~925°C at ~1–3 kbar near the SIC contact. Preservation of the peak mineral assemblage indicates that most of the generated melt escaped from these rocks leaving a residuum characterized by a plagioclase–orthopyroxene–clinopyroxene–ilmenite‐magnetite±melt assemblage. Peak temperatures reached ~875°C up to 500 m from the SIC lower contact, which marks the transition to metabasalts that only experienced incipient partial melting without melt loss. Metabasalts ~500 to 750 m from the SIC contact are characterized by a similar two‐pyroxene mineral assemblage, but typically contain abundant hornblende that overgrew clino‐ and orthopyroxene along an isobaric cooling path. Metabasalts ~750 to 1,000 m from the SIC contact are characterized by a hornblende–plagioclase–quartz–ilmenite assemblage indicating temperatures up to ~680°C. Mass balance and phase equilibria calculations indicate that anatexis resulted in 10–20% melt generation in the inner ~500 m of the aureole, with even higher degrees of melting towards the contact. Comparison of multiple models, experiments, and natural samples indicates that modelling in the Na₂O–CaO–FeO–MgO–Al₂O₃–SiO₂–H₂O–TiO₂–O₂ (NCFMASHTO) system results in the most reliable predictions for the temperature of the solidus. Incorporation of K₂O in the most recent amphibole solution model now successfully predicts dehydration melting by the coexistence of high‐Ca amphibole and silicate melt at relatively low pressures (~1.5 kbar). However, inclusion of K₂O as a system component results in prediction of the solidus at too low a temperature. Although there are discrepancies between modelling predictions and experimental results, this study demonstrates that the pseudosection approach to mafic rocks is an invaluable tool to constrain metamorphic processes at LP–HT conditions.     

Fe-ZSM-5分子筛催化降解染料废水的研究

传统的Fenton均相亚铁盐催化剂处理染料废水,具有难以避免的二次污染和亚铁离子流失问题。分子筛催化剂相比传统催化剂具有高效环保的特点,在催化氧化染料废水领域有着良好的前景。本文通过液相离子交换法制备了Fe-ZSM-5非均相分子筛催化剂,替代传统的亚铁盐催化剂,应用X射线衍射对制备的Fe-ZSM-5分子筛催化剂进行表征,表明随离子交换次数的增加,Fe-ZSM-5催化剂负载的铁量上升,且较好地保持了分子筛结构,有利于提高亚铁离子的催化能力。通过实验确定了Fe-ZSM-5催化剂催化反应的最佳温度、pH值、Fe-ZSM-5的用量、反应时间等工艺参数,比较了Fe-ZSM-5催化剂和传统Fenton均相催化剂降解染料废水的脱色率和废水中铁离子的残留量,结果表明Fe-ZSM-5的脱色率达到98.5%,相比于Fenton均相催化剂的脱色率提升约3%;两种催化剂的铁离子残留量差别显著,Fe-ZSM-5催化剂处理的废水中只产生微量的Fe离子,可以认为Fe-ZSM-5非均相分子筛催化剂有效地解决了催化剂损耗和二次污染问题。     

Stationary Wave Activity Associated with the East Asian Winter Monsoon Pathway

The pathway of the East Asian winter monsoon(EAWM) that usually leads to the out-of-phase pattern of surface air temperature between northern and southern East Asia is an important feature in the variability of the EAWM besides its strength.Using the European Centre for Medium-Range Weather Forecasts 40-year(ERA40) reanalysis dataset,this study investigates the pathway-related stationary wave activity to explore the mechanism of the interannual variations in the EAWM pathway.It reveals that when the southern pathway of the EAWM is strong,the phase of the climatological stationary wave tends to be shifted westward significantly in both the horizontal and vertical directions by an anomalous wavenumber 2 pattern at mid-latitudes,whereas the changes are relatively small in the subtropics.The horizontal changes in the stationary wave phase facilitate a north-south-oriented East Asian trough in the middle troposphere that eventually produces the strong southern pathway of the EAWM.The vertical changes in the stationary wave,in contrast,feature a westward-tilted phase line with height over the North Pacific,indicating enhanced upward propagation of waves into the stratosphere.This result suggests that the phase of stationary waves at mid-latitudes dominate the interannual variations in the EAWM pathway.Moreover,it supports our previous interpretation of the possible role of the North Pacific sea surface temperature(SST) in the EAWM pathway variability.It also implies that the excitation of anomalous mid-latitude stationary waves may be the key in the response of the EAWM pathway to the North Pacific SST.     

副热带北太平洋SST在ENSO冷暖位相转变中的作用

2015/2016年发生的极端El Ni?o事件,与1997/1998年El Ni?o事件具有可比拟的强度,但是2016年事件转变为弱La Ni?a,而1998年事件则为强La Ni?a。本文通过对比这两次极端El Ni?o事件,揭示其转变为不同强度La Ni?a事件的物理机制。混合层热收支分析的结果表明,在El Ni?o衰减年的4~11月,2016年平流反馈和温跃层反馈相对较弱,混合层温度衰减速率慢,其产生的主要原因是赤道中西太平洋的东风异常较弱。进一步分析表明,赤道中西太平洋的东风异常与副热带东北太平洋的海表温度异常（SSTA）有关,该地区的SST在1998年表现为冷异常,2016年为暖异常。副热带东北太平洋冷的SSTA有利于信风加强,从而加强中西太平洋的东风异常;而暖的SSTA使得赤道以北出现西南风异常,从而削弱中西太平洋的东风异常。此外,合成分析也表明,副热带东北太平洋SSTA与转变的La Ni?a的强度具有关联,El Ni?o转变为强La Ni?a的情况在位相转变期伴随着副热带北太平洋冷的SSTA,而El Ni?o转变为弱La Ni?a的情况没有明显的冷SSTA。     

钼矿石物相的快速分析方法

钼矿石的主要矿物有辉钼矿,其次是钼钨钙矿、铁钼华矿、钼华矿和钼酸铅矿。样品经碱熔融分解,硫氰酸盐比色法测定总钼;利用电感耦合等离子体质谱法测定氢氧化铵溶解钼华中的钼;酒石酸溶解钼钨钙矿中的钼;碳酸钠溶解钼酸铅矿中的钼;盐酸溶解铁钼华矿中的钼。方法对不同钼矿石样品进行了5种钼矿石物相分析,结果与实际地质成矿组分符合。     

云南昭通铅锌矿pH-logfo_2和pH-loga相图对铅锌共生分异的制约

云南昭通大型铅锌矿是滇东北矿集区乃至川滇黔铅锌成矿域铅锌矿床的典型代表。矿床具有明显的矿物组合分带性的特点,区别于典型的MVT型铅锌矿床。根据矿物组合特征构建、计算、绘制了该矿床的p H-logfo2、p Hloga相图,剖析了铅锌矿共生分异的形成机理。研究表明p H、氧逸度、组分浓度的协同作用造成了铅、锌的共生分异,对矿物组合分带起控制作用,且温度下降、氧逸度升高和p H升高有利于金属硫化物的沉淀,成功解释了昭通铅锌矿床独具特色的矿物分带地质特征。     

基于低精度DEM的InSAR相位解缠方法

针对干涉图条纹密集,残差点较多,相位解缠困难甚至出现错误的情况,提出了借助低精度DEM降低条纹率,提高相位解缠精度的办法。采用Envisat ASAR数据验证了提出方法的有效性。     

浙江地区2015年冬季首场降雪的气象特征及双偏振雷达回波特征分析

基于3 h间隔的浙江快速更新同化模式资料、常规探空资料和临安双偏振雷达资料反演产品对浙江地区2015年12月5日的首场降雪过程的特征进行了分析,得到了较高的云顶高度、较低的云顶温度、较低的零度层高度、较低的低层平均温度、稳定的底层冷平流以及特殊的地形是浙西北地区在较高的地表温度情况下易形成降雪的原因;同时对临安双偏振雷达产品资料进行了分析,首次提出浙江地区此类降雪的双偏振雷达产品特征,并得到了判别阈值.希望借助两方面的研究来减少此类降雪天气的漏报率和可预报性.     

Phase equilibria modelling and LASS monazite petrochronology: P–T–t constraints on the evolution of the Priest River core complex,northern Idaho

Phase equilibria modelling, laser‐ablation split‐stream (LASS)‐ICP‐MS petrochronology and garnet trace‐element geochemistry are integrated to constrain the P–T–t history of the footwall of the Priest River metamorphic core complex, northern Idaho. Metapelitic, migmatitic gneisses of the Hauser Lake Gneiss contain the peak assemblage garnet + sillimanite + biotite ± muscovite + plagioclase + K‐feldspar ± rutile ± ilmenite + quartz. Interpreted P–T paths predict maximum pressures and peak metamorphic temperatures of ~9.6–10.3 kbar and ~785–790 °C. Monazite and xenotime ²⁰⁸Pb/²³²Th dates from porphyroblast inclusions indicate that metamorphism occurred at c. 74–54 Ma. Dates from HREE‐depleted monazite formed during prograde growth constrain peak metamorphism at c. 64 Ma near the centre of the complex, while dates from HREE‐enriched monazite constrain the timing of garnet breakdown during near‐isothermal decompression at c. 60–57 Ma. Near‐isothermal decompression to ~5.0–4.4 kbar was followed by cooling and further decompression. The youngest, HREE‐enriched monazite records leucosome crystallization at mid‐crustal levels c. 54–44 Ma. The northernmost sample records regional metamorphism during the emplacement of the Selkirk igneous complex (c. 94–81 Ma), Cretaceous–Tertiary metamorphism and limited Eocene exhumation. Similarities between the Priest River complex and other complexes of the northern North American Cordillera suggest shared regional metamorphic and exhumation histories; however, in contrast to complexes to the north, the Priest River contains less partial melt and no evidence for diapiric exhumation. Improved constraints on metamorphism, deformation, anatexis and exhumation provide greater insight into the initiation and evolution of metamorphic core complexes in the northern Cordillera, and in similar tectonic settings elsewhere.