GDX-502树脂富集高效液相色谱法测定地表水中酚类化合物

采用自制GDX-502固相萃取小柱萃取水中苯酚、对硝基酚、间甲酚、2，4-二氯酚、2，4，6-三氯酚、五氯酚等6种酚类化合物，以乙腈作为洗脱剂，选择280nm和290nm双波长紫外高效液相色谱进行检测。结果表明，方法检出限为0．01-0．05mg／L，IL水的平均加标回收率为82．5％-95．0％，精密度（RSD，n=7）为3．6％-9．2％。方法用于实际地表水中痕量酚类化合物的检测，操作简单，有机溶剂用量少，分析效率高；萃取小柱可多次重复使用，分析成本低。     

The Role of Pressure in Producing Compositional Diversity in Intraplate Basaltic Magmas

Basaltic magmas found in intraplate suites appear to followmore than one differentiation trend. Many ocean island suitesfollow the ocean island tholeiitic trend, with the basalts differentiatingfrom olivine tholeiite through basaltic andesite, andesite,and dacite to sodic rhyolite. Many continental intraplate magmaticregimes, such as those of the Snake River Plain and the plutonicsequences associated with massif anorthosites, follow the potassicsilica-saturated alkalic trend, in which basalt differentiatesfrom olivine tholeiite through ferrobasalt (jotunite or ferrodiorite),Fe-rich intermediate rocks (trachybasalt or monzonite), andtrachyte (syenite) to potassic rhyolites and granites. Crystallizationexperiments on an olivine tholeiite from the Snake River Plainshow that the basaltic portions of the ocean island tholeiitictrend and the potassic silica-saturated alkalic trend (whichleads to strong alkali, P, Ti, and Fe enrichment and silicadepletion) can arise from the same ‘dry’ tholeiiticparental magma. These compositional differences are inducedby changes in phase equilibria as a function of pressure, withthe ocean island tholeiitic series arising from crystal–liquiddifferentiation at low pressure and the potassic silica-saturatedalkalic series arising via differentiation at elevated pressures. KEY WORDS: tholeiite differentiation; experimental petrology; phase equilibria; ferrodiorite; ferrobasalt     

一次暴雨过程的EOF分析

在用21层η坐标细网格模式对1998年7月21～22日发生在武汉地区的一次持续性特大暴雨过程数值模拟的基础上， 利用较高时空分辨的模式输出结果对暴雨过程做经验正交函数分解（EOF分析）尝试。结果表明:EOF第1主分量的空间分布代表典型的暴雨环境背景场的低值系统；EOF第2主分量的空间分布与人字形切变线（西部为冷式切变，东部为暖式切变）相联系，是影响这次暴雨的重要形势场；利用相轨线分析方法发现，暴雨过程中EOF第1主分量和EOF第2主分量的时间系数在暴雨临近阶段，两者正相关，激发暴雨，在暴雨后期两者负相关，促使这次暴雨趋于减弱结束。     

多频数据组合在周跳探测和修复上的应用

利用模拟的L5观测数据，结合传统的伪距／载波组合法，对周跳的探测与修复进行了实例计算，并与双频组合观测值的周跳探测方法进行了比较。结果证明，不管对大周跳还是小周跳，该方法均能在单历元间准确地探测出各个频率上发生的周跳，较之双频组合观测值的探测方法具有更大的优越性。     

鲁东胶北地区中太古代唐家庄岩群

１０余年来,通过对鲁东胶北地区太古宙地层的研究,原胶东群中剔除出大量的变质变形深成侵入岩,并从其底部分离出一套呈包体状态残存于花岗质岩石中的紫苏磁铁石英岩、二辉斜长角闪麻粒岩等,据此建立了唐家庄岩群。该岩群为一套经受角闪麻粒岩相高级变质的表壳岩组合,同位素测年数据为２７６３～２９３６Ｍａ,与之相伴产出的超基性岩同位素地质年龄值为２６９３～３１５０Ｍａ,其特征与鲁西地区沂水岩群相似,说明太古宙时鲁东和鲁西曾是一个统一的克拉通陆核。     

榴辉岩中绿辉石的测定方法研究

通过对某地榴辉岩中伴生的有用矿物的纯矿物物质组成的研究,发现Ｎａ可作为其中绿辉石的特征性成分,且Ｎａ２Ｏ含量与其纯度呈正相关。因此,推荐用测定Ｎａ２Ｏ量并以求得的换算系数计算榴辉岩中绿辉石含量的化学物相分析方法。经合成样品验证,方法的相对误差＜１．７％,用于生产样品分析,所得结果的重现性好,平均偏差＜０．５％。     

泥石流的结构两相流模型：I.理论

泥石流的运动既有类似于固液两相流之处,又在很程度上不同于固液两相流。在泥石流滨汉体模型,膨胀体模型,粘塑体模型及颗粒流模型研究的基础上,本文提出了一种新的模型－泥石流的“结构两相流模型”这种模具有以往各类模型的优点,同时又便于对不同类型的泥石流进行描述,在理论上,它比现行各类模型更加严密,在应用上,它较现行各类模式更加方便,能够适用于更加广泛的各类条件,泥石流的结构两相流模型中将现行模型的作为特例     

THE CONSTITUTIVE RELATION OF DEBRIS FLOW 1

ＴＨＥＣＯＮＳＴＩＴＵＴＩＶＥＲＥＬＡＴＩＯＮＯＦＤＥＢＲＩＳＦＬＯＷ１ＳＨＥＮＳｈｏｕｃｈａｎｇ２ＡＢＳＴＲＡＣＴＩｎｏｒｄｅｒｔｏｉｎｖｅｓｔｉｇａｔｅｔｈｅｓｔｒｅｓｃｏｎｓｔｉｔｕｔｉｖｅｒｅｌａｔｉｏｎｏｆｄｅｂｒｉｓｆｌｏｗ,ｔｈｅｅｘｐ...     

Identification method of weak seismic phases on the basis of wavelet packet transform

This paper describes a sort of new method identifying seismic phase by the name of wavelet packet transform. Perfectness and development of the wavelet packet transform is based upon the idea of its multiscale analysis. The method of wavelet packet transform can depict the anomalous changes information of transient spectra of seismic wave onset, and come true the target of identifying seismic phase especially weak seismic phase. Then this paper presents discriminating examples of simulating digital signals and actual seismic phase. Compared with conventional seismic phase discrimination, studied results show that the wavelet packet transform method is an available tool of weak signal analyses, and have unexampled merits and attractive application foreground. This research gets hold of Higher School Doctor Scientific Research Foundation (No. 157 WJ0704 9435611) and supported by the National Natural Science Foundation (No. 49474211).