考虑地表沉陷影响的复合地基承载力计算方法

受地下开采的剧烈扰动,采煤沉陷区的复合地基工程会发生非常大的下沉和水平位移,常规的承载力计算方法未考虑地表沉陷影响。在研究地表沉陷影响的复合地基承载特性的基础上,建立了考虑地表沉陷影响的复合地基受力模型,并且提出了考虑地表沉陷影响的复合地基承载力计算方法。通过一个采煤沉陷区桥梁复合地基工程实例的计算分析,发现考虑地表沉陷影响后,复合地基承载力有一定程度的下降。     

皖中泥质岩工程性质探讨

历来对半胶结泥质岩风化等级划分都带有许多主观性,从而影响提承载力,有的规范要求可不对半胶结岩石进行风化程度划分,但有时要对这些岩石进行工程地质细分,从而准确确定各分层的承载力与摩阻力。统计了合肥、六安、淮南、安庆地区等大量实践资料,用标准贯入击数、重型圆锥触探实验击数等原位测试手段来划分泥质岩风化等级,并对泥质岩的承载力与摩阻力等工程地质性质做出了评价。     

应用逼近理想解法综合评价区域水资源承载能力

在多目标决策中,基于传统的逼近于理想解的技术,根据区域水资源承载能力的强与弱和待评价的对象(评价方案)的不理想(负理想)与理想(劣与优)这些典型的模糊概念,提出了基于模糊集合的逼近理想解法(TOPSISFS),并应用于区域水资源承载能力的综合评价中。TOPSISFS与投影寻踪模型法(PP法)、理想区间法(MODMIIM)相比,简单、有效。TOPSISFS可广泛应用于多目标决策中。     

“黄河流域水资源演化规律与可再生性维持机理”研究进展

黄河是中国第二条大河,流域面积80万km2,它曾是中华民族文化的摇篮。当前在中国西部大开发中具有举足轻重的重要战略地位。但是黄河流域地处中国的半干旱与半湿润地带,流域的水资源量先天不足,流域内的人均水资源占有量很少,相当全国人均水资源占有量的1/3。由于气候的暖干变化与人类活动的影响,过去30年来,黄河下游与其主要支流频繁地发生了断流,这种发展的征兆不仅加剧了脆弱的水资源供应与需求的平衡,而且给流域上、中、下游原有生态系统与环境带来更大的冲击。黄河的治理终归是涉及国家稳定和国家安全的大事。因此,1999年科技部在“国家重点基础研究发展规划”中立项,启动了5年研究项目“黄河流域水资源演化规律与可再生性维持机理”。作者作为项目的首席科学家根据项目各课题已发表的近900篇论文与几十部专著等大量成果,简要概括了黄河水资源的基础性、技术性和应用性研究等三大方面的进展。     

老黏土地基承载力的确定

对比分析了各种确定地基承载力的方法,阐述了理论公式计算确定老黏土地基承载力的重要性.结合武昌地区的工程实例,用各种方法计算确定了老黏土的地基承载力值.研究表明,原位测试方法得到的承载力值偏低,而理论公式计算较合理.为了提高老黏土地基承载力的可信度和精度,在岩土工程勘察中除采用原位测试方法外,有必要结合理论公式计算来获取老黏土地基承载力值.     

Sequestration of CO2 in geological media: Criteria and approach for site selection in response to climate change

The well-developed coal electricity generation and coal chemical industries have led to huge carbon dioxide (CO₂) emissions in the northeastern Ordos Basin. The geological storage of CO₂ in saline aquifers is an effective backup way to achieve carbon neutrality. In this case, the potential of saline aquifers for CO₂ storage serves as a critical basis for subsequent geological storage project. This study calculated the technical control capacities of CO₂ of the saline aquifers in the fifth member of the Shiqianfeng Formation (the Qian-5 member) based on the statistical analysis of the logging and the drilling and core data from more than 200 wells in the northeastern Ordos Basin, as well as the sedimentary facies, formation lithology, and saline aquifer development patterns of the Qian-5 member. The results show that (1) the reservoirs of saline aquifers in the Qian-5 member, which comprise distributary channel sand bodies of deltaic plains, feature low porosities and permeabilities; (2) The study area hosts three NNE-directed saline aquifer zones, where saline aquifers generally have a single-layer thickness of 3‒8 m and a cumulative thickness of 8‒24 m; (3) The saline aquifers of the Qian-5 member have a total technical control capacity of CO₂ of 119.25 × 10⁶ t. With the largest scale and the highest technical control capacity (accounting for 61% of the total technical control capacity), the Jinjie-Yulin saline aquifer zone is an important prospect area for the geological storage of CO₂ in the saline aquifers of the Qian-5 member in the study area.     

基于系统动力学的巢湖流域水资源承载力动态预测与调控

湖泊流域水资源承载能力动态预测与调控是维护湖泊生态安全、保障社会经济健康持续发展的重要基础和手段.本文以巢湖流域为研究对象,提出基于系统动力学的湖泊流域水资源承载力动态预测技术和试验优化调控方法.首先以县(市)为基本单元构建水资源承载力系统动力学模拟与动态预测模型;再从空间上将各县(市)耦合为流域系统整体模型,并通过敏感性分析筛选量质要素调控指标;最后采用正交试验设计确定流域水资源承载力优化调控方案.结果表明:由于流域内产业规模的扩大以及城镇化率的提升,20172050年巢湖流域水资源承载状态值整体呈恶化趋势,并于2030年以后将长期处于超载状态,通过对影响要素针对性优化调控后,20172050年流域水资源承载状态均达到临界或可载.研究表明本文提出的方法对于促进区域社会经济环境协调发展和改善流域水资源承载力具有较好的实际应用价值.     

Heavy Metal Load of Sediments of the River Gurk (Carinthia/Austria) — Merits and Limitations of Sequential Leaching Schwermetallbelastung des Sediments der Gurk in Kärnten — Vorzüge und Einschränkungen sequentieller Löseverfahren

By means of the analysis of sediments cored in the small river Gurk (Carinthia/Austria), the input of Ag, Cd, Ce, Cr, Hg, La, Mo, Ni, V, and W from a chemical industrial plant could be detected. To estimate the actual load, and to obtain data for comparison with other sites, both unsieved fine sediments and sediments sieved to 20 μm were investigated from the same cores. Environmental mobilities of toxic heavy metals (Co, Cr, Cu, Ni, Zn) have been shown by sequential leaching following Tessier/Förstner. In the last step, HNO₃ leaches a purely geogenic fraction, which is fairly constant along the investigated river. Whereas the additional Cr from the input of the chemical plant is mainly found in the oxalate-leachable fraction, short-time-load to unpolluted sediments in the laboratory is found mainly in hydroxylamine/acetic acid. Both is due to the high affinity of Cr to Fe- and Mn-oxides. Adsorption/desorption experiments reveal that the low carbonate content of the Gurk sediments increases the importance of Fe/Mn-oxides for the sorption of Cr compared to other samples containing carbonate. The Ni-load was primarily found in weak-acid-leachable and oxalate-leachable fractions. Similarly, the oxalate-leachable fraction is dominant for adsorption of other metals and phosphorus. Other interelement relationships among the amounts leached, which are attributable partly to carbonate-, silicate-, organic or coating phases, have been found by means of factor analyses together with marker fractions for each type.     

Adsorption und Hydrolyse von Methylparathion an Aktivkohle und Adsorberharz Adsorption and Hydrolysis of Methyl Parathion (MPT) on Activated Carbon and Adsorption Resin

Investigating adsorption of methyl parathion on the activated carbons Filtrasorb 400 and F 44 and on the adsorption polymer Wofatit Y 77 we found a stronger adsorption on the carbons at smaller concentration whereas the resin has the larger capacity at higher concentration. Adsorbents were regenerated through hydrolysis of the pesticide at pH = 11.7. The velocity of hydrolysis in the adsorbed state is reduced to a tenth of that in solution. However, a transport resistance in the pores of adsorbents seems to be negligible as may be concluded from the very small measured particle diameter dependence of the velocity constants. In adsorption-regeneration measurements the capacity of the adsorbents stabilized at about 70% of that of the fresh adsorbents.     

Removal of Selenium by Adsorption onto Granular Activated Carbon (GAC) and Powdered Activated Carbon (PAC)

The present work involves the study of Se(IV) adsorption onto granular activated carbon (GAC) and powdered activated carbon (PAC). The adsorbents are coated with ferric chloride solution for the effective removal of selenium. The physico-chemical characterization of the adsorbents is carried out using standard methods, e. g., proximate analysis, scanning electron microscopy (SEM), fourier transform infrared spectroscopy (FTIR), thermo-gravimetric (TGA) and differential thermal analysis (DTA), etc. The FTIR spectra of the GAC and PAC indicate the presence of various types of functional groups, e. g., free and hydrogen bonded OH groups, silanol groups (Si-OH), alkenes, and CO group stretching from aldehydes and ketones on the surface of adsorbents. Batch experiments are carried out to determine the effect of various factors such as adsorbent dose (w), initial pH, contact time (t), and temperature (T) on the adsorption process. The optimum GAC and PAC dosage is found to be 10 g/L and 8 g/L, respectively, for Se(IV) removal with C₀ = 100 mg/L. The percent removal of Se(IV) increases with increasing adsorbent concentration, while removal per unit weight of adsorbent increases with decreasing adsorbent concentration. Se(IV) adsorption onto both the GAC and PAC adsorbents is high at low pH values, and decreases with increased initial pH. The results obtained are analyzed by various kinetic models. The parameters of pseudo-first order, pseudo-second order kinetics, and Weber-Morris intra particle kinetics are determined. It is seen that the sorption kinetics of Se(IV) onto GAC and PAC can be best represented by the pseudo-second order kinetic model.