水溶液中聚合物在粘土上的吸附

水溶液中聚合物在粘土上的吸附对于聚合物污染防治和污水处理等都有重要意义。Scheutjens-Fleer理论是应用范围最广的聚合物吸附理论,适应于从单体到长链高聚物,从链无相互作用的稀溶液到纯聚合物的吸附研究。本文简要介绍了有关聚合物吸附的重要参数,包括吸附量、耦合分数或直接表面覆盖、平均层厚度和链段密度,以及相应的测定方法。文中分析了影响聚合物吸附研究发展的主要问题,指出水溶液中聚合物在粘土上的吸附研究的发展方向是综合研究吸附等温线和A/V效应、耦合分数、吸附层厚度、吸附分级现象和对粘土层间的影响,并与Scheutjens-Fleer理论计算结果进行比较。     

浙江西沪港重金属铜的配位容量和形态分析

根据2000年6月10～14日在浙江省西沪港采集的海水样品,利用AA-800石墨炉原子吸收分光光度技术和阳极溶出伏安法测定样品中重金属铜的含量,获得铜在海水中受不同的有机配体控制.不同粒级的铜表观配位容量表明西沪港海水过孔径1.00μm微孔膜的(ACuCC)较高,为144.4nmol/dm3;过0.40和0.20μm滤膜的(ACuCC)分别为103.0和102nmol/dm3;铜的有机配体条件稳定常数的对数值在7.25～9.14之间.铜的总量为21.72nmol/dm3.铜全部为稳定溶解态,其中pH2酸溶态占95.0%,强有机结合态占5.0%.溶解态铜中有机结合态占过滤海水中总铜的61.6%.     

珠江口水体中铜与悬浮颗粒物相互作用的研究

使用无机离子交换法研究珠江口水体中铜与悬浮颗粒物的相互作用，测出钢与悬浮颗粒物相互作用的ｐＨ曲线呈Ｓ形，其分级离子交换等温线是一种新的“台阶”型；从分级离子交换理论求得分级平衡常数Ｋ１为５．０，Ｋ２为７８．１，珠江口水体中铜的表观络合容量为０．９２μｍ及其条件稳定常数为３．５×１０７。     

Behavior of Pile Groups under Lateral Load

Based on investigation and model tests, and in combination with the research work on group effect for pile groups under lateral loads relating to the code of fixed offshore platforms, a series of studies have been performed on the behavior and failure mechanism of laterally loaded pile groups, critical pile spacing inducing group effect, lateral bearing capacity of pile groups and its main influence factors, the stress-strain relationship for single piles and pile groups and so on. Some new laws about non-uniformity of load distribution in the longitudinal direction of pile groups and load-deflection (p - y) curves for pile groups have been discovered, and an empirical formula is presented in order to remedy the defect of current calculating methods at home and abroad. These results can be used for reference in the design of pile foundation under lateral loads.     

Estimation of Axial Pile Bearing Capacity According to Shear Strength Parameters of Soil

At pesent,it is very popular to estimate pile bearing capacity by use of empirical formula andphysical indexes of soil provided in the design codes for civil construction in China.This paper attempts toapply mechanical indexes of soil and semi-empirical formulas,which are based on soil mechanical theoriesand were summarized and presented by Meyerhof in 1976,to calculate the axial pile bearing capacity.Lo-ading test results of 24 single piles in Tianjin area have been collected and compared with the proposed cal-ulation approach.     

东山湾贝类养殖容量的估算

以初级生产力为基础，应用营养动态模式和沿岸海域能流分析模型，估算东山湾贝类年生产量分别为269331t和295767t，平均282549t。扣除潮间带、潮下带和吊养区浮筏、随着基及延绳上附着的非养殖滤食性附着动物自然现存量35760t，贝类可养殖量为246789t。应用统计分析和逻辑斯谛种群增长模型估计贝类可养面积为11839hm^2，其中缢蛏635hm^2，石蛎1160hm^2,吊蛎1525hm^2，翡翠贻贝633hm^2，菲律宾蛤仔1154hm^2，扇贝698hm^2，江瑶248hm^2，泥蚶601hm^2，巴非蛤4151hm^2，凸壳肌蛤1034hm^2。1998年实际养殖面积和养殖产量分别为10581hm^2和220564t。尚有1258hm^2,26225t的扩大开发潜力。文中还讨论了合理布局和优化养殖结构问题。     

Estimation of Uplift Capacity of Rapidly Loaded Plate Anchors in Soft Clay

Plate anchors are extensively used in civil engineering constructions as they provide an economical alternative to gravity and other embedded anchors. The rate of loading is one of the important factors that affects the magnitude of soil resistance as well as soil suction force. This article outlines the effect of pullout rate on uplift behavior of plate anchors (70 mm diameter) buried in soft saturated clay by varying the pullout rate from 1.4 mm/min to 21.0 mm/min. The variation of breakout force and suction force with embedment depth and rate of pull are presented. A correlation between the rate of increase of undrained strength of clay and anchor capacity with rate of strain has been established. Finally an empirical equation has been proposed that includes the rate of pull in the estimation of breakout capacity of anchors.     

Discussion: A review on the behaviour of helical piles as a potential offshore foundation system

Abstract

Helical piles have emerged as an attractive foundation system for offshore applications with renewed interest from the offshore community. Significant research gap currently exists in transferring this technology offshore and this paper discusses how existing and emerging knowledge can be successfully used to bridge some of the gaps. We focus on the Coupled Eulerian Lagrangian (CEL) large deformation finite element (LDFE) modelling technique that is commercially available and can be used to model the three-dimensional installation process with consideration of strain rate and softening effects in soft offshore clays. A helical pile of L?=?7.5?m long is modelled with one or two large-diameter helices (D?=?2?m) attached to a central shaft of d?=?0.5?m in diameter.The net effect of strain rate and softening is to increase the installation torque. The measured torque is within the range of 200–400?kN.m for the offshore clay and the pile geometry studied. Additional helices increase the uplift force but to a lesser degree than that of the measured torque. Remoulding induced strength reduction is found to be within the range of 25–33% of the intact clay strength. Issues of extracting and reusing offshore helical pile foundations are discussed.     

Sustainable shellfish aquaculture in Saldanha Bay,South Africa

The carrying capacity for bivalve shellfish culture in Saldanha Bay, South Africa, was analysed through the application of the well-tested EcoWin ecological model, in order to simulate key ecosystem variables. The model was set up using: (i) oceanographic and water-quality data collected from Saldanha Bay, and (ii) culture-practice information provided by local shellfish farmers. EcoWin successfully reproduced key ecological processes, simulating an annual mean phytoplankton biomass of 7.5 µg Chl a l^–1 and an annual harvested shellfish biomass of about 3 000 tonnes (t) y^–1, in good agreement with reported yield. The maximum annual carrying capacity of Small Bay was estimated as 20 000 t live weight (LW) of oysters Crassostrea gigas, or alternatively 5 100 t LW of mussels Mytilus galloprovincialis, and for Big Bay as 100 000 t LW of oysters. Two production scenarios were investigated for Small Bay: a production of 4 000 t LW y^–1 of mussels, and the most profitable scenario for oysters of 19 700 t LW y^–1. The main conclusions of this work are: (i) in 2015–2016, both Small Bay and Big Bay were below their maximum production capacity; (ii) the current production of shellfish potentially removes 85% of the human nitrogen inputs; (iii) a maximum-production scenario in both Big Bay and Small Bay would result in phytoplankton depletion in the farmed area; (iv) increasing the production intensity in Big Bay would probably impact the existing cultures in Small Bay; and (v) the production in Small Bay could be increased, resulting in higher income for farmers.     

三角褐指藻体分泌物质对汞的络合作用

本文测定了一次培养实验和连续培养实验中三角褐指藻胞外产物的变化及其与汞的络合性能。28天的培养过程中测得胞外产物与汞的络合容量C_L为2.6×10~(-5)mol/dm~3;表观稳定常数K′为6.1×10~(10)。该结果解释了细胞培养过程中胞外有机物的释放对汞的解毒机理及对介质中汞形态的转化。