从碳源到碳汇：大陆弧演化过程中岩浆与剥蚀作用对长期碳循环的影响

在百万年时间尺度上,大气、海洋中的二氧化碳浓度(P_CO2,二氧化碳分压)和长期变化主要受岩浆-变质脱碳作用和硅酸盐风化作用(消耗二氧化碳)控制。因此,地球表层主要构造活动带的构造-岩浆活动对长期碳循环具有重要的驱动作用。本文在总结已发表文献的基础上,系统评估了大陆弧,尤其是晚白垩世大陆弧的岩浆作用和剥蚀作用的碳通量,并以此为依据探讨了大陆弧演化对于全球长期碳循环的影响。大陆弧岩浆作用以周期性(几十万年至一百百万年)岩浆爆发(magmatic flare-ups)为特征。在一个周期内,大规模岩浆喷发会导致CO₂排放量大幅度增加,促进温室效应。但同时,大规模的岩浆作用又会导致地壳增厚和和地表抬升,从而促进剥蚀作用、提高化学风化通量,进而增加CO₂消耗量。对于单个的大陆弧来说,在其演化的不同阶段对于碳循环扮演着不同的角色：演化早期由于岩浆作用起主导作用,表现为净碳源;而在岩浆作用减弱或停止后,由于剥蚀作用的持续进行,表现为净碳汇。因此,从长周期和全球尺度上讲,大陆弧岩浆活动表现的“碳源属性”受到化学风化作...     

跃进山杂岩的地质年代学和地球化学证据及其构造演化意义SCIEI北大核心CSCD

那丹哈达地体是中国境内唯一保存的古太平洋板块俯冲-增生的直接记录,包括跃进山杂岩和饶河增生杂岩。跃进山杂岩出露于那丹哈达地体的西缘,属于地体早期阶段的增生产物,对揭示古太平洋板块的俯冲-增生历史以及古亚洲洋构造域、泛大洋和古太平洋构造域之间的转换过程具有重要意义。本文通过野外地质调查明确了跃进山杂岩是一套构造混杂岩,主要由硅质岩、石英片岩、大理岩、二云母片岩、石英-云母片岩、变玄武岩、辉长岩、纯橄榄岩、异剥橄榄岩和单斜辉石岩组成。LA-MC-ICPMS锆石年代学测试结果表明变玄武岩原岩和辉长岩的形成时代分别为303±2Ma和278±2Ma,此外前人报道了跃进山杂岩中最年轻的玄武岩形成于232±5Ma,这些年代学研究成果限定了镁铁质-超镁铁质岩形成于303~232Ma。大量地球化学研究数据证实了跃进山杂岩中的玄武岩为洋中脊玄武岩(MORB)和洋岛玄武岩(OIB)。糜棱岩化绿泥石-绢云母板岩的绢云母^(40)Ar/^(39)Ar测试结果为193±1Ma,根据跃进山杂岩中最年轻的原岩时代为~220Ma,本文限定了跃进山杂岩的最终就位时代为220~193Ma。结合中国东北地区中生代增生杂岩及佳木斯地块和松辽地块东缘晚古生代至中生代的岩浆弧,本文揭示了中国东北地区古亚洲洋和泛大洋构造域向古太平洋构造域的转换发生在晚三叠世至早侏罗世。     

Late Permian to Early Triassic subduction and retreating of the Paleopacific slab: Constraints from continental arc magmatism in Hainan IslandSCIEI北大核心CSCD

海南岛大规模二叠-三叠纪侵入岩的形成是与古特提斯洋有关,还是与古太平洋俯冲闭合有关还存在巨大争议。本文对琼中金波两处辉绿岩脉及其围岩花岗岩的研究显示,露头1辉绿岩脉的锆石U-Pb年龄为245.4±3.8Ma,TiO_(2)含量(1.07%~1.18%)低,而MgO(8.60%~9.41%)和Mg^(#)值(62.31~65.02)较高,为钙碱性系列,球粒陨石和原始地幔标准化配分曲线中具有明显的Eu、Nb、Ta、Ti和Ba负异常,以及显著Th、U、Zr、Rb和Pb等正异常,(^(87)Sr/^(86)Sr)_(i)=0.707138~0.712797,(^(143) Nd/^(144)Nd)_(i)=0.511884~0.511965,ε_(Nd)(t)值为-7.01~-8.58,指示其形成于大陆岛弧环境。相比之下,露头2辉绿岩锆石U-Pb年龄为242.8±3.1Ma,但其TiO_(2)(2.65%~3.06%)含量较高,而MgO(4.24%~5.39%)和Mg^(#)值(40.09~45.86)较低,具有Eu、Rb、Pb、Nb、Ta和Ti弱正异常和Th负异常,(^(87)Sr/^(86)Sr)_(i)=0.690244~0.717031,(^(143) Nd/^(144)Nd)_(i)=0.512886~0.512915,ε_(Nd)(t)值为+6.41~+7.93,具有板内玄武岩的特征,指示其形成于板内裂解环境。辉绿岩脉围岩二长花岗岩的锆石U-Pb年龄为255.3±3.0Ma和255.7±3.2Ma,含少量角闪石和黑云母,具有较高的SiO_(2)(71.62%~73.72%)、Na_(2)O+K_(2)O(6.60%~9.17%)和Al_(2)O_(3)(平均14.88%)含量,A/CNK值(0.97~1.03)较低,亏损Nb、Ta、Ti、Sr和Ba,富集Rb、Th、U和Pb,为高分异I型岛弧花岗岩。总的来看,二长花岗岩和辉绿岩形成于大陆岛弧挤压向伸展过渡的构造环境。对比二叠-三叠纪侵入岩体的走向、碰撞前-同碰撞-碰撞后岩浆岩的时代以及榴辉岩的变质年龄等,发现海南岛侵入岩与哀牢山-松马造山带明显不同,而与日本和朝鲜半岛的岛弧岩浆岩类似,由此我们认为海南岛大规模晚二叠-早三叠世岩浆岩为古太平洋板片向欧亚板块俯冲后撤的产物,后撤过程受到古特提斯俯冲板片的影响。     

黑龙江多宝山地区早古生代沟-弧-盆体系重建SCIEI北大核心CSCD

沟-弧-盆体系恢复对于研究增生造山过程和解析成矿作用具有重要指示意义,多宝山岛弧带是我国重要的铜钼多金属成矿区带,其沟-弧-盆体系恢复对成矿地质背景研究及拓展区域找矿具有重要意义。通过对多宝山地区早古生代地层、岩石和构造的野外调研和系列编图,结合最新的年代学资料,重新厘定了含矿地层单位——多宝山组、铜山组的形成时代和层位:确定多宝山组形成时代为寒武纪芙蓉世-早奥陶世,铜山组形成时代为早-中奥陶世;将铜山组置于多宝山组之上,暗示地表以下保存有规模较大的主要成矿地质体——多宝山组,由此扩大了深部找矿空间。在此基础上,重建了多宝山岛弧带早古生代地层序列。在多宝山岛弧带西北侧多宝山-三卡一带划分出早古生代俯冲增生杂岩带,根据俯冲增生杂岩带与岩浆弧、伴生沉积盆地的沉积建造及时空关系,划分出弧前盆地、弧间盆地、弧后盆地等构造单元,建立了多宝山岛弧带古生代沟-弧-盆体系格架,认为多宝山岛弧带西北侧多宝山-三卡一带存在早古生代洋盆,并于奥陶纪发生南东向俯冲。指出岩浆弧靠近俯冲增生杂岩带一侧是成矿有利部位,为多宝山岛弧带铜多金属矿的成矿背景和成矿地质条件研究提供了理论依据。     

川西义敦岛弧中部图姆沟组流纹岩年代学、地球化学特征及其对岩浆成因的限定

【研究目的】 义敦岛弧是三江特提斯复合造山带的重要组成部分。区域现有的研究较多集中在弧花岗质侵入岩及其成矿作用上,而对区内流纹岩的研究则相对匮乏。【研究方法】 本文在详细野外填图的基础上,对图姆沟组流纹岩进行岩石学、地球化学和同位素年代学研究。【研究结果】 流纹岩锆石U-Pb成岩年龄216.5 Ma,为晚三叠世。岩石SiO₂含量为73.24%~74.72%,全碱含量为5.26%~6.27%,为钙碱性系列,富集大离子亲石元素Rb、Th、U、K和轻稀土元素,亏损高场强元素Nb、Ta、Ti、P和重稀土元素,具典型的岛弧火山岩特征。【结论】 图姆沟组流纹岩是印支期甘孜—理塘洋壳向西俯冲环境下地壳部分熔融的产物。     

Contributions of trans-magmatic fluid in the formation of porphyry copper deposits: A case study from the Baoshan deposit,South China

The classical mechanism “source-transport-storage” of the formation of porphyry copper deposit has been advanced in recent studies, as the “source” is not the main factor for the mineralization in some Cu deposits, and the metallogeny may be affected by other variables factors during the magma-fluid transportation or storage. We recommend the essential role of trans-magmatic fluid in the ore-forming process, this fluid is released from the melting of the sedimentary overlying the subducted plate with high water and volatiles concentrations and high oxygen fugacity. The Baoshan granodioritic cryptoexplosion breccia representing the influence of hydrothermal events as well as the unaltered Baoshan granodiorite porphyry are conducted by LA-MC-ICP-MS analysis, to identify the contribution of trans-magmatic fluid. In case of the ε_Nd(t) of whole rock do not increase with the MgO increasing and SiO₂ decreasing, the large variations of zircons ε_Hf(t) values in Baoshan granodiorite porphyry (BGP, ?14.24 to ?6.38) and Baoshan granodioritic crypto-explosion breccia (BGCB, ?25.24 to ?6.62) were considered to be the interaction of partial melting of ancient mafic lower crust and Neoproterozoic juvenile crust. However, the copper mineralization requires high oxygen fugacity and a large amount of water, according to the tectonic settings of Baoshan, we recommend that it is the trans-magmatic fluid trapping and concentrating Cu from the whole pluton during the upwelling driven by magma convection. The initial magma was stalled by the ductile-brittle transition at shallow depths of upper-crust. The trans-magmatic fluid leads to the pressure increases at the top of the initial magma, then the overlying rock is ruptured and cryptoexplosion produced. Moreover, after the cryptoexplosion, the sudden reduction of circumference temperature and pressure leads to the decrease in the oxygen fugacity of the ore-forming system, which will change the valence state of sulfur from S⁶⁺ to S^2?. Finally, sulfur precipitates with chalcophile elements like copper in the metallogenic system and forms porphyry copper deposits with the low Sr/Y ratio. This study highlights the use of trans-magmatic fluid and ductile-brittle transition in the formation of the Baoshan porphyry copper deposits.     

Petrogenesis of Early Permian Intrusive Rocks from Southeastern Inner Mongolia, China: Constraints on the Tectonic Framework of the Southeastern Central Asian Orogenic Belt

The late Paleozoic tectonic framework of the southeastern Central Asian Orogenic Belt is key to restricting the accretion orogeny between the Siberia Craton and the North China Craton. To clarify the framework, petrogenesis of early Permian intrusive rocks from southeastern Inner Mongolia was studied. Zircon U-Pb dating for bojite and syenogranite from Ar-Horqin indicate that they were emplaced at 288–285 Ma. Geochemical data reveal that the bojite is highly magnesian and low-K to middle-K calc-alkaline, with E-MORB-type REE and IAB-like trace element patterns. The syenogranite is a middle-K calc-alkaline fractionated A-type granite and shows oceanic-arc-like trace element patterns, with depleted Sr-Nd-Hf isotopes, (87Sr/86Sr)I = 0.7032–0.7042, εNd(t) = +4.0 to +6.6 and zircon εHf(t) = +11.14 to +14.99. This suggests that the bojite was derived from lithospheric mantle metasomatized by subducted slab melt, while the syenogranite originated from very juvenile arc-related lower crust. Usng data from coeval magmatic rocks from Linxi?Ar-Horqin, the Ar-Horqin intra-oceanic arc was reconstructed, i.e., initial transition in 290–280 Ma and mature after 278 Ma. Combined with regional geological and geophysical materials in southeastern Inner Mongolia, an early Permian tectonic framework as ‘one narrow ocean basin of the PAO’, ‘two continental marginal arcs on its northern and southern’ and ‘one intra-oceanic arc in its southern’ is proposed.     

准噶尔盆地东北缘石炭系火山岩形成机制:对准噶尔洋盆闭合时限的新启示

准噶尔古大洋作为古亚洲洋北部的重要分支及阶段性演化产物,其洋盆的俯冲、闭合时限以及盆地基底属性一直存在分歧。本文选取准噶尔盆地东北缘(乌伦古地区)石炭系火山岩来说明其岩浆来源及成因机制,通过主微量元素、Sr-Nd同位素分析结果,进一步阐明准噶尔洋盆在晚古生代的闭合时限。本次研究包括玄武岩、玄武质安山岩和安山岩三类火山岩,岩体显示低TiO₂(0.60%~0.84%)、较高的全碱K₂O+Na₂O含量(1.18%~8.59%),玄武岩为岛弧拉斑系列,安山岩类的钙碱元素含量高,具有火山弧火山岩特征。中-低⁸⁷Sr/⁸⁶Sr_(i)(0.703 250~0.704 559)、相对亏损的Nd同位素(+4.8~+6.8)以及t_DM2(483~625 Ma)值表明玄武岩、玄武质安山岩和安山岩同为亏损地幔熔融岩浆分异结晶的产物,安山岩为地幔熔融岩浆后期分离结晶形成;微量元素与同位素地球化学示踪暗示玄武岩、玄武质安山岩和安山岩含有洋壳俯冲过程的脱水流体交代上覆地幔楔的消减组分,安山岩在深部岩浆房经历了壳-幔混合作用,受地壳成分的混染程度更大。大离子亲石元素(LILE)Ba、Sr和轻稀土元素、不相容元素(Th、U、K)相对富集,高场强元素(HFSE)Nb、Ta相对亏损,以及Pb、Zr、Hf的富集,说明该区属于与俯冲消减带相关的构造背景;结合本套火山岩高Ba/La(30.14~208.86)值、低TiO₂(0.60%~0.84%)值,以及Ce/Nb比(8.71~12.05)、Th/Nb比(0.93~1.74)等,表明准噶尔洋盆于石炭纪沿着大陆板块下部持续俯冲,洋壳板片的俯冲脱水流体交代地幔楔后增生岛弧。该套中-基性火山岩建造佐证了准噶尔洋盆闭合时限为晚石炭世(ca. 305.5±4.4 Ma),结合区域地质资料分析,提出与俯冲带有关的岩浆通过岛弧拼贴增生到大陆地壳上,进一步为准噶尔盆地基底的岛弧拼贴成因提供了新依据。     

华南晚中生代陆弧迁移与海域盆地演化

陆弧和弧前盆地是俯冲体系中具有密切联系的构造单元。中生代以来,华南受多期板块俯冲的控制,发育大规模岩浆岩带及海域广泛分布的弧前盆地。但陆域弧岩浆岩较少,海域又缺乏足够钻井,各时期陆弧的位置存在较大争议,同时,南海北部至东海一带弧前盆地也缺乏系统认识,因此,亟须新的研究思路深化对华南晚中生代俯冲体系和俯冲过程的认识。本文以前人研究为基础,对海域钻遇中生界的典型钻井进行了详细分析,系统开展了海域盆地区域构造和沉积对比,将弧前盆地发育与岛弧变迁相结合综合分析。结果表明早侏罗世—早白垩世陆弧位于南海北部—东海靠近陆域一侧,经历了早侏罗世局限陆弧、中晚侏罗世沿海陆弧带、早白垩世向海沟方向的迁移。在此过程中,华南海域弧前盆地群于中侏罗世正式形成,早白垩世发育盆缘角度不整合,粗碎屑相带向海沟方向迁移,晚白垩南海北部与东海各自进入新的构造体制,结束弧前盆地的发育。华南沿海海域中生代盆地的发育可为陆弧的展布提供重要约束,弧岩浆岩带的迁移控制了弧前盆地的演化。     

The significance of cherts as markers of Ocean Plate Stratigraphy and paleoenvironmental conditions: New insights from the Neoproterozoic–Cambrian Blovice accretionary wedge,Bohemian Massif

The Ediacaran to early Cambrian Blovice accretionary complex, Bohemian Massif, hosts abundant chert bodies that formed on an oceanic plate and were involved in subduction beneath the northern margin of Gondwana. Field relationships of cherts to their host, their microstructure and elemental as well as isotopic compositions revealed diverse processes of chert petrogenesis reflecting depositional environment and position on the oceanic plate. The deep-water cherts formed through a hydrothermal precipitation of silica-rich gels on outer trench swell of the subducted slab with none or only minor addition of terrigenous material. On the contrary, the shallow-water cherts formed in lagoons on seamount slopes, and at least some of them represent a product of hydrothermal replacement of former carbonate and/or evaporite precursors. For both chert types, the hydrothermal fluids were of low temperature and continuous pervasive hydrothermal alteration of oceanic crust, together with an elevated Si content in Neoproterozoic seawater, served as the major source of silica. On the other hand, minor carbon enrichment in chert is mostly linked to variable incorporation of organic matter that was deposited on the seafloor. Rare earth element (REE) systematics of the cherts indicate predominantly oxygenated environment for the shallow-water cherts whereas the deep-water cherts were deposited in diverse redox conditions, depending on their distance from hydrothermal vent. Using these data, we demonstrate that the cherts once formed a part of Ocean Plate Stratigraphy (OPS) now dismembered and mixed with terrigenous siliciclastic material to form OPS mélanges. Combining our data with those from the existing literature, we show that cherts can serve as significant markers of OPS since the Archean, recording a complex interplay between seafloor-related volcanic (production of MORB- and OIB-like magmas) and sedimentary processes, hydrothermal activity at mid-ocean ridges and seamount chains as well as at outer slopes of subducting slabs. However, the cherts also exhibit a secular change in composition and petrogenesis most profoundly affected by an overturn in seawater silica cycle across the Precambrian–Phanerozoic boundary.