An Acetic Acid‐Based Extraction Protocol for the Recovery of U,Th and Pb from Calcium Carbonates for U‐(Th)‐Pb Geochronology

A new method for the simultaneous recovery of U, Th and Pb from ca. 0.5 g calcium carbonate samples for the purpose of U‐(Th)‐Pb geochronometry is presented. The protocol employs ion‐exchange chromatography. Standard anion exchange resin (AG 1‐X8 100–200 mesh) was used as the static phase, and 90% acetic acid was used as the mobile phase to elute the unwanted matrix components; dilute nitric acid was used to elute the U, Th and Pb. Blanks of 1.8 pg Th, 6.4 pg Pb and 8.4 pg U were obtained. The protocol was evaluated by determining the isotopic composition of U‐Th‐Pb separates obtained from an in‐house reference material (prepared from a natural speleothem) by MC‐ICP‐MS. An independently dated speleothem was also reanalysed. Based on these tests, the extraction protocol had an acceptable blank and produced a Pb separate sufficiently free of matrix‐induced instrumental biases to be appropriate for U‐Th‐Pb chronology.     

An Optimised 1,10‐Phenanthroline Method for the Determination of Ferrous and Ferric Oxides in Silicate Rocks,Soils and Minerals

A precise, accurate and rapid method for the sequential determination of FeO and Fe₂O₃ in rocks, soils and some non‐refractory minerals by 1,10‐phenanthroline spectrophotometry is described. Fe(II) and Fe(III) were leached from the sample (?200 mesh) using a mixture of NH₄HF₂ and H₂SO₄ at 40–80 °C for 10 min on a hot plate. Both Fe(II) and Fe(III) could be conveniently estimated sequentially from the same reaction mixture at the μg g^?1 to percentage level. The method is better than the existing wet chemical methods, including the commonly used Pratt's titrimetric redox method, for Fe(II) and Fe(III) determinations in rock and soil samples in terms of precision, accuracy and rapidity. The throughput of the method was very high; at least forty to fifty samples could be estimated easily in a day. The results obtained compare favourably with those obtained by Pratt's method, as well as for certified/recommended values of a set of eleven certified reference materials having FeO and Fe₂O₃ contents in the range 0.21–14.63% and 0.58–8.48%, respectively. The optimised 1,10 phenanthroline method was found to be accurate to within 0.21% m/m FeO and 0.30% m/m Fe₂O₃ compared with the literature values of the certified reference materials studied.     

Annual dissolved fluxes from Central Nepal rivers: budget of chemical erosion in the Himalayas

Annual dissolved element fluxes of Himalayan rivers from Central Nepal are calculated using published river discharge and a new set chemical data of rivers, including monsoon sampling. These are used to study the control on chemical erosion of carbonate and silicate over the whole basin. Chemical erosion of carbonate is mainly controlled by the river runoff but it can be limited by the availability of carbonate in limestone-free basin. Chemical erosion of silicate is well correlated to the runoff. However differences between High Himalayan and Lesser Himalayan basins suggest that physical erosion may also play an important control on silicate weathering. To cite this article: C. France-Lanord et al., C. R. Geoscience 335 (2003).     

The imprinting of aridity upon a lateritic landscape: an illustration from southwestern Australia

The southwestern region of Australia contains the Yilgarn Craton that has been exposed to subaerial weathering since mid-Proterozoic. The gently undulating landscape experienced lateritic weathering so that today variably dissected, deep in situ isovolumetrically weathered regolith is widespread. Imposition of a more arid climate since the Miocene with the cessation of effective external drainage has resulted in substantial geochemical modification of the highly porous regolith. This vast pore volume acts as a reservoir for complex solutions that may be highly saline, extremely acid to alkaline and reducing. Diverse precipitates have formed in the regolith including widespread occurrence of silcrete, calcrete, dolocrete, ferricrete and gypcrete together with localised occurrences of pyrite, alunite, jarosite, barite, halite and other salts. Clearing of bush land for agriculture in the 20th century increased recharge so that rising chemically active groundwaters are damaging farmland and infrastructure throughout the region. To cite this article: B. Gilkes et al., C. R. Geoscience 335 (2003).     

Removal of Copper,Nickel and Zinc Ions from Aqueous Solution by Chitosan‐8‐Hydroxyquinoline Beads

In this work, 8‐hydroxyquinoline is used as the active sites in cross‐linked chitosan beads with epichlorohydrin (CT‐8HQ). The CT‐8HQ material was shaped in bead form and used for heavy metal removal from aqueous solution. The study was carried out at pH 5.0 with both batch and column methods and the maximum adsorption capacity of metal ions by the CT‐8HQ was attained in 4 h in the batch experiment. The adsorption capacity order was: Cu²⁺ > Ni²⁺ > Zn²⁺ for both mono‐ and multi‐component systems with batch conditions. From breakthrough curves with column conditions, the adsorption capacity followed the order Cu²⁺ > Zn²⁺ > Ni²⁺ for both mono‐ and multi‐component systems. The CT‐8HQ beads maintained good metal adsorption capacity for all five cycles with absorbent restoration achieved with the use of 1.0 mol L^–1 HCl solution, with 90% regeneration.     

北极地区区域经济特征研究

以环北极国家的北极行政区域为统计范围．利用环北极国家2001年和2005年的官方经济统计数据,对北极地区的经济状况、资源潜力和发展趋势作了统计和初步分析,结果表明：（1）2005年。北极地区国内生产总值（GDP）为2322亿美元,比2001年的1194亿美元几乎翻了一倍。相对于北美、北欧、俄罗斯其他地区,环北极国家的北极地区GDP对于全国的贡献不大．大部分不到1／10。（2）大部分北极地区以油气、矿物、木材、捕鱼等自然资源开采为第一经济支柱产业：在为数不多的民族自冶区或原住民居住地区保留了采撷、狩猎、毛皮加工等传统农业;金融、贸易、旅游等服务业在北欧和北美的少数北极地区有所发展。     

ZD8仪地电阻率整点值短临异常研究

高精度的地电阻率测量其观测资料中有否短临地震前兆信息, 为此分析处理了宝坻台ZD8地电仪自1987年5月至2001年3月的地电阻率整点值观测资料, 分别对发生在宝坻台附近的中等地震和华北北部5级以上地震前该项资料的短临前兆变化的对应情况和异常形态特征进行了全面的分析研究, 结果表明该项资料的短临异常指标分别为0. 5%和1. 0%, 其预报效能的R值分别为0. 4和0. 373。     

Impact of 1/8° to 1/64° resolution on Gulf Stream model–data comparisons in basin-scale subtropical Atlantic Ocean models

We investigate the impact of 1/8°, 1/16°, 1/32°, and 1/64° ocean model resolution on model–data comparisons for the Gulf Stream system mainly between the Florida Straits and the Grand Banks. This includes mean flow and variability, the Gulf Stream pathway, the associated nonlinear recirculation gyres, the large-scale C-shape of the subtropical gyre and the abyssal circulation. A nonlinear isopycnal, free surface model covering the Atlantic from 9°N to 47°N or 51°N, including the Caribbean and Gulf of Mexico, and a similar 1/16° global model are used. The models are forced by winds and by a global thermohaline component via ports in the model boundaries. When calculated using realistic wind forcing and Atlantic model boundaries, linear simulations with Munk western boundary layers and a Sverdrup interior show two unrealistic mean Gulf Stream pathways between Cape Hatteras and the Grand Banks, one proceeding due east from Cape Hatteras and a second one continuing northward along the western boundary until forced eastward by the regional northern boundary. The northern pathway is augmented when a linear version of the upper ocean global thermohaline contribution to the Gulf Stream is added as a Munk western boundary layer. A major change is required to obtain a realistic pathway in nonlinear models. Resolution of 1/8° is eddy-resolving but mainly gives a wiggly version of the linear model Gulf Stream pathway and weak abyssal flows except for the deep western boundary current (DWBC) forced by ports in the model boundaries. All of the higher resolution simulations show major improvement over the linear and 1/8° nonlinear simulations. Additional major improvement is seen with the increase from 1/16° to 1/32° resolution and modest improvement with a further increase to 1/64°. The improvements include (1) realistic separation of the Gulf Stream from the coast at Cape Hatteras and a realistic Gulf Stream pathway between Cape Hatteras and the Grand Banks based on comparisons with Gulf Stream pathways from satellite IR and from GEOSAT and TOPEX/Poseidon altimetry (but 1/32° resolution was required for robust results), (2) realistic eastern and western nonlinear recirculation gyres (which contribute to the large-scale C-shape of the subtropical gyre) based on comparisons with mean surface dynamic height from the generalized digital environmental model (GDEM) oceanic climatology and from the pattern and amplitude of sea surface height (SSH) variability surrounding the eastern gyre as seen in TOPEX/Poseidon altimetry, (3) realistic upper ocean and DWBC transports based on several types of measurements, (4) patterns and amplitude of SSH variability which are generally realistic compared to TOPEX/Poseidon altimetry, but which vary from simulation to simulation for specific features and which are most realistic overall in the 1/64° simulation, (5) a basin wide explosion in the number and strength of mesoscale eddies (with warm core rings (WCRs) north of the Gulf Stream, the regional eddy features best observed by satellite IR), (6) realistic statistics for WCRs north of the Gulf Stream based on comparison to IR analyses (low at 1/16° resolution and most realistic at 1/64° resolution for mean population and rings generated/year; realistic ring diameters at all resolutions), and (7) realistic patterns and amplitude of abyssal eddy kinetic energy (EKE) in comparison to historical measurements from current meters.     

鄂尔多斯盆地南部旬邑-宜君地区中生界储层特征

对鄂尔多斯盆地南部旬邑 -宜君地区中生界主要储集层——直罗组、延安组、延长组储层特征从沉积相、砂体纵向展布、岩性和物性等几方面进行了简要论述。通过研究指出本区储层具有低孔、低渗的特点。在纵向上以直罗组储层相对最好 ,延安组次之 ,之后才是三叠系延长组。储集层普遍具有岩性细、成岩后生变化强烈的特点。由于储层低孔、低渗 ,因此 ,油层的压裂改造措施必不可少     

Landsat 8全色影像阴影的扁平冰山出水高度提取

冰山出水高度是测量冰山厚度进而估算冰山体积的一个重要几何参数,是定量评估冰山对海洋的淡水输入量的基础。冬季冰山在海冰上成影且阴影较长,本文提出利用阴影测高模型高精度测量冰山出水高度的方法。试验选择2016年8月29日、9月7日和9月16日中心太阳高度角分别为5.43°、7.49°和11.01°的3期Landsat 8全色15 m影像,以独立扁平冰山为例,自动提取冰山在海冰上的阴影长度计算冰山出水高度,并利用不同时相同名成影点进行交叉验证评估测量精度。结果显示：阴影长度测量误差优于1个像元,在太阳高度角低于11.01°时,全色15 m影像提取的冰山出水高度均方根误差（RMSE）低于2.0 m,平均绝对误差（MAE）低于1.5 m。由此表明：在冬季低太阳高度角下,Landsat 8全色15 m影像可用于高精度测量冰山出水高度,具有大范围测量南极冰山出水高度的潜力。