"99.6"梅雨锋暴雨模拟资料的诊断分析

利用非静力中尺度模式MM5V3的模拟资料对"99.6"梅雨锋暴雨过程进行了对流动量输送(CMT)和视热源视水汽汇分析。CMT诊断分析表明,水平动量残差在切变低涡发展的不同阶段的作用是不同的,在中尺度低涡发生初期对流层低层动量残差X主要是加速西南气流的北上;在对流层中层动量残差在槽后加速冷空气南下,在槽前加速西南暖湿气流北上,非常有利于东亚大槽的发展。在低涡切变线强烈发展时,850hPa的X方向与发生阶段相反,此时西南气流受到了强烈的减速作用,同时500hPa东亚大槽的前部和后部出现了减速气流的动量残差,槽后冷空气和槽前的暖湿气流都已经受到减速作用,此后低涡切变线逐渐衰减。低涡切变线发展到最强的阶段,强X矢量几乎总是与强烈上升运动区相对应,能量转换E的水平分布表明,大尺度系统与中尺度系统之间的能量转换非常复杂,并不是简单的能量串级过程,但能量主要是从大尺度向次网格尺度转换。200hPa动能转换E的带状分布非常清楚,E的正负大值中心分布在高空急流的2侧,表明高空急流在能量转换的过程中起到非常重要的作用。视热源和视水汽汇的诊断分析显示,强凝结潜热的释放与低涡的发展相伴随,但视热源只与β中尺度系统有明显的对应关系,视水汽汇有和视热源非常相似的分布特征。     

Integrating downscaled CMIP5 data with a physically based hydrologic model to estimate potential climate change impacts on streamflow processes in a mixed‐use watershed

Climatic changes have altered surface water regimes worldwide, and climate projections suggest that such alterations will continue. To inform management decisions, climate projections must be paired with hydrologic models to develop quantitative estimates of watershed scale water regime changes. Such modeling approaches often involve downscaling climate model outputs, which are generally presented at coarse spatial scales. In this study, Coupled Model Intercomparison Project Phase 5 climate model projections were analyzed to determine models representing severe and conservative climate scenarios for the study watershed. Based on temperature and precipitation projections, output from GFDL‐ESM2G (representative concentration pathway 2.6) and MIROC‐ESM (representative concentration pathway 8.5) were selected to represent conservative (Δ_C) and severe (Δ_S) change scenarios, respectively. Climate data were used as forcing for the soil and water assessment tool to analyze the potential effects of climate change on hydrologic processes in a mixed‐use watershed in central Missouri, USA. Results showed annual streamflow decreases ranging from ?5.9% to ?26.8% and evapotranspiration (ET) increases ranging from +7.2% to +19.4%. During the mid‐21st century, sizeable decreases to summer streamflow were observed under both scenarios, along with large increases of fall, spring, and summer ET under Δ_S. During the late 21st century period, large decreases of summer streamflow under both scenarios, and large increases to spring (Δ_S), fall (Δ_S) and summer (Δ_C) ET were observed. This study demonstrated the sensitivity of a Midwestern watershed to future climatic changes utilizing projections from Coupled Model Intercomparison Project Phase 5 models and presented an approach that used multiple climate model outputs to characterize potential watershed scale climate impacts.     

Seasonal evaluation of rainfall estimation by four cumulus parameterization schemes and their sensitivity analysis

Sustainable water resources management require scientifically sound information on precipitation, as it plays a key role in hydrological responses in a catchment. In recent years, mesoscale weather models in conjunction with hydrological models have gained great attention as they can provide high‐resolution downscaled weather variables. Many cumulus parameterization schemes (CPSs) have been developed and incorporated into three‐dimensional Pennsylvania State University/National Center for Atmospheric Research (PSU/NCAR) mesoscale model 5 (MM5). This study has performed a comprehensive evaluation of four CPSs (the Anthes–Kuo, Grell, Betts–Miller and Kain–Fritsch93 schemes) to identify how their inclusion influences the mesoscale model's precipitation estimation capabilities. The study has also compared these four CPSs in terms of variability in rainfall estimation at various horizontal and vertical levels. For this purpose, the MM5 was nested down to resolution of 81 km for Domain 1 (domain span 21 × 81 km) and 3 km for Domain 4 (domain span 16 × 3 km), respectively, with vertical resolutions at 23, 40 and 53 vertical levels. The study was carried out at the Brue catchment in Southwest England using both the ERA‐40 reanalysis data and the land‐based observation data. The performances of four CPs were evaluated in terms of their ability to simulate the amount of cumulative rainfall in 4 months in 1995 representing the four seasonal months, namely, January (winter), March (spring), July (summer) and October (autumn). It is observed that the Anthes–Kuo scheme has produced inferior precipitation values during spring and autumn seasons while simulations during winter and summer were consistently good. The Betts–Miller scheme has produced some reasonable results, particularly at the small‐scale domain (3 km grid size) during winter and summer. The KF2 scheme was the best scheme for the larger‐scale (81 km grid size) domain during winter season at both 23 and 53 vertical levels. This scheme tended to underestimate rainfall for other seasons including the small‐scale domain (3 km grid size) in the mesoscale. The Grell scheme was the best scheme in simulating rainfall rates, and was found to be superior to other three schemes with consistently better results in all four seasons and in different domain scales. Copyright © 2011 John Wiley & Sons, Ltd.     

钴—5—Br—PADNm络合物的光度性质研究及其应用

本文研究了钴(Ⅱ)-5-Br-PADNm络合物的光度性质。在pH5.0缓冲溶液中,有TritonX-100存在时,Co~(2 )与5-Br-PADNm形成1:2红色络合物,λ_(max)为547nm,ε为1.35×10~5l·mol~(-1)·cm~(-1)。所提出的方法用于矿石及茶叶中Co的测定,得到满意结果。     

Primary cracking of kerogens. Experimenting and modelling C1, C2–C5, C6–C15 and C15+ classes of hydrocarbons formed

Mathematical models of hydrocarbon formation can be used to simulate the natural evolution of different types of organic matter and to make an overall calculation of the amounts of oil and/or gas produced during this evolution. However, such models do not provide any information on the composition of the hydrocarbons formed or on how they evolve during catagenesis.From the kinetic standpoint, the composition of the hydrocarbons formed can be considered to result from the effect of “primary cracking” reactions having a direct effect on kerogen during its evolution as well as from the effect of “secondary cracking” acting on the hydrocarbons formed.This report gives experimental results concerning the “primary cracking” of Types II and III kerogens and their modelling. For this, the hydrocarbons produced have been grouped into four classes (C₁, C₂–C₅, C₆–C₁₅ and C₁₅₊). Experimental data corresponding to these different classes were obtained by the pyrolysis of kerogens with temperature programming of 4°C/min with continuous analysis, during heating, of the amount of hydrocarbons corresponding to each of these classes.The kinetic parameters of the model were optimized on the basis of the results obtained. This model represents the first step in the creation of a more sophisticated mathematical model to be capable of simulating the formation of different hydrocarbon classes during the thermal history of sediments. The second step being the adjustment of the kinetic parameters of “secondary cracking”.     

拟合法15°波动方程有限差分串联偏移

本文把最佳拟合算法（三点和五点差分格式）及串联偏移方法应用在15°波动方程偏移中。由于拟合法的差分因子随着采样间隔、步长、速度等参数的变化而变化,因此与原有的波动方程差分偏移法相比,串联偏移方法能有效的使大倾角归位,克服频散,速度及步长可以灵活变化,运算效率高等优点。     

我国海洋测井技术回顾与展望

地球物理测井是利用各种现代物理学的方法（包括电学、声学、核物理、热学、光学、磁学、力学等）对储层空间的油气水特性、沉积环境、地层层序、构造地质等现象进行定量研究，逐步形成的一门理论性、实用性很强的边缘学科．海洋测井作业环境更为特殊而复杂，不但投资大、作业风险大，而且具有技术高度密集、技术难度大的特点．发展海洋石油勘探事业，必须加强对海洋测井技术的研究，利用现代高新科学技术，开拓海洋测井新领域，为海洋石油勘探提供更丰富、更准确的地质信息．     

TBP－（X－5）反相色谱分离m－NPF分光光度法测定铀

本文研究了以磷酸三丁酯为固定相，大孔聚乙烯苯（Ｘ－５型）为担体的浸渍树脂、垂直型反相色谱柱，对铀分离富集的基本性能，以及铀（Ⅳ）－间硝基苯基萤光酮（ｍ－ＮＰＦ）一氨三乙酸（ＮＴＡ）－吐温－８０显色体系的反应条件，提出了ＴＢＰ（Ｘ－５）分离，ｍ－ＮＰＦ－ＮＴＡ－吐温－８０光度法测定铀，经标准样品验证，结果满意。     

镉—5—Br—PADAP—溴化十六烷基三甲基铵—十八醇聚氧乙烯(20)醚显色体系的研究及应用

本文研究了镉-5-Br-PADAP-溴化十六烷基三甲基铵-peregalo显色体系的光谱特征,显色条件,络合物的组成、干扰及其消除。实验证明该法灵敏度高,ε=1.3×10~5l·mol~(-1)·cm~(-1)。选择性较好,显色酸度范围较宽pH=8.0-9.5,络合物最大吸收波长为560nm,镉在0-10μg/25ml的含量范围内服从比尔定律。经标准水样、工业废水及生活用水验证,不经分离可测定水中PPb级的微量镉。