Calcium Isotope Ratio (δ44/40Ca) Measurements of Ca‐Dominated Minerals and Rocks without Column Chemistry Using the Double‐Spike Technique and Thermal Ionisation Mass Spectrometry

In this study, to evaluate whether bias free Ca isotope ratios can be properly achieved by thermal ionisation mass spectrometry (TIMS) using the ⁴²Ca–⁴³Ca double‐spike technique without chemical purification, a series of comparable experiments (with or without column chemistry) were made on Ca‐dominated minerals and rocks. Minerals, including fluorite, calcite, titanite and apatite, displayed similar Ca isotope ratios with Δ^44/40Ca_{with‐without} ranging from ?0.02 to +0.07‰. For Ca‐rich rocks, we mainly focused on the carbonates since they are the main repositories of Ca at the surface of the Earth. Coral, stalagmite, carbonatite, dolomite, marble and limestone are studied here. Interestingly, δ^44/40Ca_{SRM 915a} of these minerals and rocks without chemical purification displayed little drift compared with that of rocks with chemical purification, with Δ^44/40Ca_{with‐without} merely spanning from ?0.04 to +0.04‰. This implies that Ca isotope ratios can be achieved without column chemistry, possibly due to a property of TIMS in which Ca ions are only ionised at a target temperature and with a specific activator without ionising other ions. Therefore, for Ca‐dominated minerals or rocks, we suggest that column chemistry is unnecessary if they are totally dissolved and mixed in proper proportion with the ⁴²Ca–⁴³Ca double spike for TIMS measurement.     

Constraints on stellar-dynamical models of the Orion Nebula Cluster

The results obtained by Kroupa, Petr & McCaughrean (1999) for specific models of young compact binary-rich clusters are generalised using dynamical scaling relations, to infer the candidate set of possible birth models leading to the Orion Nebula Cluster (ONC), of which the Trapezium Cluster is the core. It is found that candidate sets of solutions exist which allow the ONC to be in virial equilibrium, expanding or contracting. The range of possible solutions is quite narrow. These results will serve as guidelines for future, CPU-intensive calculations of the stellar-dynamical and astrophysical evolution of the entire ONC. These, in turn, will be essential to quantify observables that will ultimately discriminate between models, thus allowing us to understand if the ONC is in the process of assembling a rich Galactic cluster, and, if this is the case, how it occurs.     

An Updated Coupled Model for Land-Atmosphere Interaction. Part Ⅱ: Simulations of Biological Processes

In Part Ⅰ, the authors succeeded in coupling the spectral atmospheric model (SAMIL_R42L9) developed at the State Key Laboratory of Numerical Modeling for Atmospheric Sciences and Geophysical Fluid Dynamics, Institute of Atmospheric Physics, Chinese Academy of Sciences (LASG/IAP/CAS) with the land surface model, Atmosphere-Vegetation-Interaction-Model (AVIM) and analyzed the climate basic state and land surface physical fluxes simulated by R42_AVIM. In this Part Ⅱ, we further evaluate the simulated results of the biological processes, including leaf area index (LAI), biomass and net primary productivity (NPP) etc. Results indicate that R42_AVIM can simulate the global distribution of LAI and has good consistency with the monthly mean LAI provided by Max Planck Institute for Meteorology. The simulated biomass corresponds reasonably to the vegetation classifications. In addition, the simulated annual mean NPP has a consistent distribution with the data provided by IGBP and MODIS, and compares well with the work in literature. This land-atmosphere coupled model will offer a new experiment tool for the research on the two-way interaction between climate and biosphere, and the global terrestrial ecosystem carbon cycle.     

金川镍矿含矿岩体的稀土元素及微量元素地球化学特征

通过对采自金川镍矿I矿区露天矿的第二期侵入岩体中。样品的稀土元素、微量元素进行全岩等离子质谱（ICP－MS）测定发现第二期侵入的岩体具有明显的轻稀土元素富集和无明显铕异常的特征，是上地幔低比例平衡部分熔融和分离结晶共同作用的产物。岩体中镍黄铁矿、磁黄铁矿、黄铁矿成条带状出现，表明其形成时低氧逸度的成岩环境。     

辽南42号金伯利岩管地质特征及找矿预测

辽南42号金伯利岩岩管主要由东部42-1号大岩管、西部42-2号小岩管和中部42-3号小小岩管组成。42-1号岩管从地表到40 m标高形态急剧收缩;42-2号岩管为烟筒状,40 m标高至-160 m标高面积比为1∶1.15;42-3岩管在-200 m标高处延深为脉状。42号岩管岩石类型为斑状金伯利岩、斑状富金云母金伯利岩、含或富含围岩角砾金伯利岩和含岩球斑状金伯利岩。岩石化学特征研究表明,岩石中w(SiO₂)、w(Al₂O₃)、w(TiO₂)值比山东胜利Ⅰ号金伯利岩和戴里值偏高,w(MgO)、w(Cr₂O₃)、w(K₂O)、w(Na₂O)、w(P₂O₅)值较戴里值偏低,但w(K₂O)、w(Na₂O)、w(P₂O₅)值比山东胜利Ⅰ号金伯利岩略高;w(ΣFe₂O₃+FeO)、w(CaO+H₂O)值与山东胜利Ⅰ号金伯利岩及戴里值相当。通过采样分析42-2号岩管金刚石含量高,42-1号岩管金刚石含量低;研究认为受造岩矿物橄榄石和金云母的影响,金刚石含量与橄榄石斑晶含量正相关,与金云母含量呈负相关;伴生矿物铬铁矿、镁铝榴石、碳硅石含量高,则金刚石含量也随之增高,为正相关;而锐钛矿于金刚石含量为负相关。基于研究区的三维建模、推覆构造研究,推测42号岩管不是根部相,其东部可能存在深部金伯利岩体。