种植不同作物对农田N2O和CH4排放的影响及其驱动因子

以种植玉米(Zea mays)、大豆(Glycine max)和水稻(Oryza sativa)的农田生态系统为研究对象,于2003年6~10月系统观测了N2O和CH4的排放、土壤温度和湿度以及相关的生物学因子。玉米和水稻分别施化肥氮300 kg.hm-2,大豆未施氮肥。研究结果表明,作物类型对农田N2O和CH4排放具有显著的影响。土壤-玉米系统、土壤-大豆系统和土壤-水稻系统的N2O季节性平均排放通量分别为620.5±57.6、338.0±7.5和238.8±13.6μg.m-2.h-1(N2O)。种植作物促进了农田生态系统的N2O排放,玉米地土壤和裸地土壤的N2O平均排放通量分别为364.2±11.7和163.7±10.5μg.m-2.h-1(N2O)。土壤-玉米系统、土壤-水稻系统、玉米地土壤和裸地土壤N2O排放受土壤温度的影响,与土壤湿度无显著统计相关,但受土壤温度和水分的综合影响。土壤-大豆系统N2O排放随作物绿叶干重的增加而指数增加,与土壤温度和水分条件无统计相关,由大豆作物自身氮代谢所产生的N2O-N季节总量约为6.2 kg.hm-2(N)。土壤-水稻系统CH4平均排放通量为1.7±0.1 mg.m-2.h-1(CH4),烤田抑制了稻田CH4的排放。烤田前影响稻田CH4排放的主要因素是水稻生物量,烤田后的浅水灌溉及湿润灌溉阶段的CH4排放与土壤温度和水稻生物量无关。本研究未观测到旱作农田有吸收CH4的现象。     

基于RRI反演的高频大地电磁测深在深边部矿产勘探中的试验研究

随着我国国民经济的快速发展,对各种矿产资源的需求量越来越大,经过多年对近地表的矿产开采之后,找矿的目标逐渐向矿区深边部发展,本文阐述采用EH-4电导率成像系统的高频大地电磁法,并且利用RRI反演,能够准确快速地探测大深度范围内的矿化异常,对矿区的深边部矿产的赋存状态进行超前地宏观预测,并将野外的成功实例进行分析.     

我国台风高发期东海和南海海区GIIRS/FY-4A温度反演廓线精度研究

基于欧洲中期天气预报中心再分析资料ERA5,对GIIRS/FY-4A温度反演廓线在我国台风高发期东海和南海海区的反演精度进行研究,结果表明:(1)东海海区,无云时GIIRS质量控制0的数据总体RMSE为1.71 K,150～450 hPa高度范围内RMSE小于1 K,450 hPa至近海面RMSE在2 K以内.质量控制...     

Gas and Particulate Products Distribution from the Photooxidation of α-Humulene in the Presence of NOx, Natural Atmospheric Air and Sunlight

The photooxidation of -humulene in the presence of NO_x, natural sunlight, and rural background air was investigated using a combination of gas chromatography-mass spectrometry (GC-MS) and high performance liquid chromatography (HPLC). Identification and quantification of gas and particulate reaction products were reported over the course of the reaction. The daytime photooxidation was carried out in a large outdoor smog chamber (190 m³). A wide range of ring retaining and ring opening products in the gas and particle phase are reported. On average, measured gas and particle phase products accounted for 44% of the reacted -humulene carbon. Measurements show that a number of reaction products with low vapor pressures (e.g. 3-seco--humulone aldehyde, 7-seco--humulone aldehyde, -humulal aldehyde, -humulene 3-oxide or -humulene 7-oxide, -humulaic/alic acid isomers, and 3-seco--14-hydroxyhumulone aldehyde) were found in the early stage of the reaction and may play an important role in the early formation of secondary organic aerosol. A detailed mechanism is proposed to account for most products observed in this investigation.     

Climate Change of 4°C Global Warming above Pre-industrial Levels

Using a set of numerical experiments from 39 CMIP5 climate models, we project the emergence time for 4°C global warming with respect to pre-industrial levels and associated climate changes under the RCP8.5 greenhouse gas concentration scenario. Results show that, according to the 39 models, the median year in which 4°C global warming will occur is 2084. Based on the median results of models that project a 4°C global warming by 2100, land areas will generally exhibit stronger warming than the oceans annually and seasonally, and the strongest enhancement occurs in the Arctic, with the exception of the summer season. Change signals for temperature go outside its natural internal variabilities globally, and the signal-to-noise ratio averages 9.6 for the annual mean and ranges from 6.3 to 7.2 for the seasonal mean over the globe, with the greatest values appearing at low latitudes because of low noise. Decreased precipitation generally occurs in the subtropics, whilst increased precipitation mainly appears at high latitudes. The precipitation changes in most of the high latitudes are greater than the background variability, and the global mean signal-to-noise ratio is 0.5 and ranges from 0.2 to 0.4 for the annual and seasonal means, respectively. Attention should be paid to limiting global warming to 1.5°C, in which case temperature and precipitation will experience a far more moderate change than the natural internal variability. Large inter-model disagreement appears at high latitudes for temperature changes and at mid and low latitudes for precipitation changes. Overall, the inter-model consistency is better for temperature than for precipitation.     

西南岩溶地区找水的地球物理方法探讨

总结了目前国内主要的物探找水技术方法,分析了各种方法的优缺点及其适应范围。以云南个旧市的找水成果作为典型案例,重点介绍了EH4电磁成像找水方法的技术特点、在岩溶区找水的可行性分析、数据处理和成果解释过程,最后推断出可能存在地下水的位置,并布设井位用于指导施工。后期追踪调查表明,勘察区已成功打出地下水,证明了使用EH4电磁成像技术在岩溶区找水的可行性。     

4A沸石吸附模拟核素Sr,Cs后的组分变化和结构表征

通过4A沸石吸附模拟核素Sr,Cs前后的化学成分分析、X衍射分析和红外光谱分析等手段方法,分析探讨了模拟核紊Sr,Cs在4A沸石的赋存状态,结果表明：4A沸石与模拟核素Sr,Cs之间主要以离子交换的方式发生作用,Sr^2 ,Cs^ 取代4A沸石中的可交换离子Na^ ,占据4A沸石a笼中的6元环和8元环。导致4A沸石的晶胞参数增大,晶格发生畸变。     

塔东地区古城4井上寒武统—中、上奥陶统流体地球化学示踪

通过对塔东地区古城4井上寒武统和中、上奥陶统碳酸盐岩围岩及充填物的碳、氧、锶同位素地球化学和流体包裹体成分的对比研究表明,充填于中、上奥陶统和上寒武统的流体分属于2个不同来源的流体体系。充填于中、上奥陶统灰岩裂缝中方解石脉的w(87Sr)/w(86Sr)介于0.7084~0.7088,它与早奥陶世海水的w(87Sr)/w(86Sr)相近;流体体系为CH4-H2O体系;充填物与围岩间具有明显的碳、氧同位素差异,表明上部流体体系中的流体来自于奥陶系地层本身。上寒武统白云岩裂缝中方解石脉的w(87Sr)/w(86Sr)为0.7138,明显地高于同时代海水的锶同位素值;流体体系为CO2-H2O体系;下部流体体系中的流体为外来富锶流体。上、下流体体系间互不连通暗示着上寒武统地层具有相对较好的保存条件。     

基于扰动模式的四维变分资料同化系统框架的设计完善和数值试验

为了建立一个应用于区域数值预报的四维变分资料同化（4DVar）系统,在近期开发的扰动预报模式GRAPES_PF基础上,开发完善增量四维变分同化系统框架。该框架中暂不包含物理过程（长短波辐射、边界层过程、对流参数化和云微物理等）。对比业务使用的GRAPES 3DVar系统,增加了温度控制变量。将无量纲Exner气压与流函数的线性风压平衡方程直接在地形追随垂直坐标面上求解,且通过广义共轭余差法（GCR）求解扰动亥姆霍兹（Helmholtz）伴随方程。利用人造“探空”资料对2015年10月台风“彩虹”进行了理想数值试验。试验结果表明,所开发的扰动四维变分同化框架得到了预期的结果,即同化更多资料并反复受到模式约束的四维变分同化系统能有效改善初值质量,进而改善区域数值预报。建立的区域四维变分同化框架合理可行,为进一步发展包含完整物理过程的区域四维变分同化系统奠定了研究基础。      

深水风浪的平均波长与平均周期的关系

在Gaussian波场基础上,推导出以P-M谱和平均JONSWAP谱代表的充分成长和有限风区的深水风浪平均波长与平均波周期之间的关系为.推导中运用了Rice跨零点问题的解并通过滑动时间平均技术估计4阶谱矩.在风浪水槽进行了实验,实验结果与有限风区下推导出的关系相比较,符合较好.