Testing the Ability of Numerical Model to Simulate Climate and Its Change With 4D-EOF Analysis

The four-dimensional empirical orthogonal function (4D-EOF), which in reality is a simple combination of three-dimensional EOF (3D-EOF) and extended EOF (EEOF), is put forward in this paper to test the ability of numerical model to simulate climate and its change. The 4D-E0F analysis is able to reveal not only the horizontal characteristic pattern of analyzed variable, and its corresponding annual and inter-annual variations, but also the vertical structural characteristics. The method suggested is then used to analyze the monthly mean 100-, 500-, 70G-, and 1000-hPa geopotential height fields (4941 grids and grid spacing 60 km) and their anomaly fields in 1989-1998 simulated by the MM5V3 from the RMIP (Regional Climate Model Inter-comparison Project for East Asia)-II, as well as their counterparts (used as the observed fields) from the NCEP/NCAR re-analysis dataset in the same period. The ability of MM5V3 in simulating East Asian climate and its change is tested by comparing the 4D-EOF analysis results of the simulated and observed datasets. The comparative analyzed results show that the horizontal pattern of the first eigenvector of the observed monthly mean geopotential height fields and its vertical equivalent barotropic feature were well simulated; the simulations of the first two eigenvectors of the observed monthly mean geopotential height anomaly fields were also successful for their horizontal abnormal distributions and significant equivalent barotropic features in the vertical were well reproduced; and furthermore, the observed characteristics, such as the variation with height, the annual and inter-annual variations of the monthly mean geopotential height/anomaly fields were also well reflected in the simulation. Therefore, the 4D-EOF is able to comprehensively test numerical model's ability of simulating the climate and its change, and the simulation ability of MM5V3 for the climate and its change in East Asia in the 1990s was satisfactory.     

南极威德尔海周边雪冰和大气气溶胶中的MSA,nssSO_4~(2-)浓度及其比率研究

分析了威德尔海周边雪冰和大气中ＭＳＡ和ｎｓｓＳＯ２－４浓度资料。结果表明,威德尔海是造成这一地区大气中高含量生物硫化物的“源”,其周边岛屿及冰架表层雪冰记载和反映了大气中生物硫化物的空间分布和季节变化特点。源区产出硫化物的强度存在显著差异：靠近南极半岛一侧高于靠近Ｆｉｌｃｈｎｅｒ－Ｒｏｎｎｅ冰架一侧。尽管诸多因素对输运和沉降过程发生影响,表层积雪ＭＳＡ和ｎｓＳＯ２－４浓度仍呈现出很有规律性的空间分布：随沉降地点离海距离和海拔高度的增加,浓度值递减;但在一定海拔之下,“高程效应”不显著。冰芯中ＭＳＡ浓度垂向分布显示出季节分配“滞后”现象,在表层表现为受天气条件制约的输运过程造成的相位差,在深层则归因于有待验证的“迁移”机制作用的结果。大气和雪冰样品对比研究结果表明,在类似威德尔海这样的高纬地区,大气中的ＳＯ２－４和ＭＳＡ“信号”在雪冰样品中会遭到不同程度的减弱。但就空间变化趋势和季节分布而言,表层雪冰仍是大气中组分（在本文是ＳＯ２－４和ＭＳＡ）的良好载体。十分接近的大气和雪冰ＭＳＡ对ｎｓｓＳＯ２－４（或ＳＯ２－４）比率证实,这两种大气组分在由大气洗净和沉降到冰雪过程中只发生微弱的分离作用。这也就是大气和雪冰中     

磺化层柱状有机膦酸锆的合成及催化反应研究

在氢氟酸溶液中,混合亚磷酸、4,4’-联苯二膦酸和锆离子反应生成4,4’-联苯二膦酸锆／亚磷酸锆（简称MCZP）,改变有机酸和亚磷酸的比例,可以合成具有相同组分但结构不同的一系列化合物。通过磺化反应,在苯环上接上磺酸基团后,它具有类似强酸性阳离子交换树脂特性．该文首次对这类化合物催化酯化、醚化等典型的酸催化有机反应进行了研究,结果表明其催化转化率高、催化剂可重复使用和再生,是一种很有发展前途的新型固体酸催化剂．     

Renewable, controlled and environmentally safe phosphorus release in soils from mixtures of NH4 +-phillipsite tuff and phosphate rocks

 The renewable and controlled-release fertilization system investigated here uses NH₄ ⁺-exchanged phillipsite tuff, from Jordan, to help in the dissolution of phosphate rock. Accordingly, controlled and renewable soluble nitrogen, phosphate and Ca are released as nutrients for plants. NH₄ ⁺ phillipsite can sequester Ca ions released by the dissolution of phosphate rock, therefore, leading to further phosphate rock dissolution. In this study the results show that the amount of phosphate released is more than that released by phosphate rock alone. This method offers an alternative to the use of highly soluble fertilizers and may avoid environmental problems associated with their extensive use in agriculture. Received: 22 May 1997 · Accepted: 12 August 1997     

Oxygen isotope fractionation in mantle minerals

The increment method is adopted to calculate oxygen isotope fractionation factors for mantle minerals, particularly for the polymorphic phases of MgSiO₃ and Mg₂SiO₄. The results predict the following sequence of¹⁸O-enrichment:pyroxene (Mg, Fe, Ca)₂Si₂O₆>olivine (Mg, Fe)₂SiO₄ > spinel (Mg, Fe)₂SiO₄> ilmenite (Mg, Fe, Ca) SiO₃>perovskite (Mg, Fe, Ca) SiO₃. The calculated fractionations for the calcite-perovskite (CaTiO₃) System are in excellent agreement with the experimental calibrations. If there would be complete isotopic equilibration in the mantle, the spinel-structured silicates in the transition zone are predicted to be enriched in¹⁸O relative to the perovskite-structured silicates in the lower mantle but depleted in¹⁸O relative to olivines and pyroxenes in the upper mantle. The oxygen isotope layering of the mantle might result from differences in the chemical composition and crystal structure of mineral phases at different mantle depths. Assuming isotopic equilibrium on a whole earth scale, the chemical structure of the Earth’s interior can be described by the following sequence of¹⁸O-enrichment:upper crust>lower crust>upper mantle>transition zone>lower mantle>core. Project supported by the National Natural Science Foundation of China and the Chinese Academy of Sciences.     

利用空间测地技术结果估计地球平均下地幔粘性(英)

基于IEC－4G冰期后地壳反弹模型,和地球上Laurentia,Fennoscandia,Antarctica,andGreenland四大冰盖最近21000年以来的冰融参数,计算了对地球最大主转动惯量的影响△I33,并进而由现代空间测地技术观测资料分析得到的地球自转非潮汐加速项为约束,估计了地球平均下地幔（670km以下）粘性vLM为（0．9～2．5）·1022Pas,这个结果表明了vLM应具有1022Pas量级．     

准四年周期的北半球夏季遥相关与东亚夏季风环流的相互关系

利用ＮＭＣ的２００ｈＰａ和８５０ｈＰａ风场资料研究了北半球夏季遥相关和东亚夏季风异常环流在准４年时间尺度上的相互关系。研究发现当北半球夏季出现积雪强迫型遥相关时,东亚－西太平洋地区既存在异常纬向环流,也存在异常经向环流;而当出现东亚太平洋型遥相关时,东亚－西太平洋地区以异常纬向环流为主。分析还发现源于北太平洋的异常涡旋在向南传播的过程中,先取西南路径,在到达菲律宾东部以后折向东南。     

湖泊水位资料与模型模拟恢复的6000年前全球湿润状况的对比研究

本项研究是ＰＭＩＰ（ＰａｌａｅｏｃｌｉｍａｔｅＭｏｄｅｌｉｎｇＩｎｔｅｒｃｏｍｐａｒｉｓｏｎＰｒｏｊｅｃｔ）国际合作项目中有关模型模拟与观测资料对比的一部分。模型试验对象是６０００ｙｒ．ＢＰ的全球湿润状况。模拟试验以检测太阳辐射变化对全球大尺度气候系统的影响为主要目的。观测资料是利用地质证据恢复的古湖泊水位变化,实际上是某一地区的有效降水（降水减蒸发）的变化。通过两者的比较发现,所有模拟试验均能重现６０００ｙｒ．ＢＰ在亚洲南部与非洲北部的湿润环境,从而证实了因太阳辐射变化导致的亚洲与非洲季风的增强。但模拟的季风增强无论是强度还是范围均小于地质记录。原因很可能是模拟试验中下垫面特征用“现代”的来处理。模拟试验对北半球夏季辐射增加造成的西风带北移及由此引起的中纬度地区的气候变化不够成功。绝大多数模拟对受洋流与海温影响较大的地区是失败的。主要原因可能是所有ＰＭＩＰ中的模拟试验都未考虑海洋的作用。     

Assessment of δ13C and C/N ratios in bulk organic matter as palaeosalinity indicators in Holocene and Lateglacial isolation basin sediments,northwest Scotland

Carbon isotopes (δ¹³C) and C/N ratios from bulk organic matter have recently been used as alternative proxies for relative sea‐level (RSL) reconstruction where there are problems associated with conventional biological indictors. A previous study on a single isolation basin (Upper Loch nan Eala) in northwest Scotland has shown a clear relationship between δ¹³C, C/N ratios and palaeosalinity from Younger Dryas and Holocene aged sediments. In this paper we present results of δ¹³C and C/N ratio analyses from other isolation basins in northwest Scotland over the Holocene and the Lateglacial period in order to validate this technique. The results from the Holocene sequences support the earlier findings that this technique can be used to identify RSL change from isolation basins over the Holocene in this region. The relationship between δ¹³C, C/N ratios and RSL change is not apparent in sediments of Lateglacial age. Other environmental variables such as atmospheric CO₂ concentration, poor vegetation development and temperature influence δ¹³C values during this period. Copyright © 2007 John Wiley & Sons, Ltd.