基于SMOS卫星数据的海表面盐度模型

海表面盐度是研究海洋对全球气候影响以及大洋环流的重要参量之一,而卫星遥感技术是获取海表面盐度数据的最有效方法.目前,L波段的SMOS和Aquarius/SAC-D遥感卫星正在用于探测海表面盐度,并根据卫星观测数据和物理机制反演出海表面盐度的产品.但在某些近陆地区域,由于淡水流入及陆地射频(RFI)等因素影响,卫星反演盐度的产品精度较低.文中利用“东方红2号”科学考察船的实测数据、SMOS卫星数据,首次针对中国南海海域提出了用贝叶斯网络模型计算海表面盐度,并用验证数据集(实测Argo盐度)对模型进行适应性评估.经过计算,模型误差和验证误差分别为0.47 psu和0.45 psu,而相应的SMOS Level 2产品的精度分别为1.90 psu和1.82 psu.此模型为海表面盐度的计算提供了一个新方法.     

Molybdenum Mass Fractions and Isotopic Compositions of International Geological Reference Materials

The double‐spike method with multi‐collector inductively coupled plasma‐mass spectrometry was used to measure the Mo mass fractions and isotopic compositions of a set of geological reference materials including the mineral molybdenite, seawater, coral, as well as igneous and sedimentary rocks. The long‐term reproducibility of the Mo isotopic measurements, based on two‐year analyses of NIST SRM 3134 reference solutions and seawater samples, was ≤ 0.07‰ (two standard deviations, 2s, n = 167) for δ^98/95Mo. Accuracy was evaluated by analyses of Atlantic seawater, which yielded a mean δ^98/95Mo of 2.03 ± 0.06‰ (2s, n = 30, relative to NIST SRM 3134 = 0‰) and mass fraction of 0.0104 ± 0.0006 μg g^?1 (2s, n = 30), which is indistinguishable from seawater samples taken world‐wide and measured in other laboratories. The comprehensive data set presented in this study serves as a reference for quality assurance and interlaboratory comparison of high‐precision Mo mass fractions and isotopic compositions.     

Copper Speciation in a Collection of Geochemical Reference Materials Using Sequential Extraction and Evaluation of the Validity Using XANES Spectroscopy

Copper speciation in a collection of Japanese geochemical reference materials (JSO‐1, JLk‐1, JSd‐1, ‐2, ‐3 and ‐4, JMs‐1 and JMs‐2) was achieved by sequential extraction and characterised using X‐ray absorption near‐edge structure spectroscopy. In the first step of the extraction, referred to as the acid fraction, between 1% and 20% total Cu within the reference materials was extracted. Such a result is typically accounted for by absorption of Cu onto clay minerals. However, the presence of Cu sulfate (an oxidation product of chalcopyrite) was observed in some of the stream sediments affected by mining activity (JSd‐2 and JSd‐3) instead. Copper was extracted in the reducible fraction (targeting Fe hydroxide and Mn oxide) (2–49% total Cu). Between 2% and 51% Cu was extracted in the oxidised fraction (targeting sulfides and organic matter). X‐ray absorption near‐edge structure spectroscopy clarified that the reducible fraction consisted of Cu bound to Fe hydroxide, whereas the oxidised fraction was a mixture of Cu bound to humic acid (HA) and Cu sulfide. In the oxidisable fraction, chalcopyrite was the predominant species identified in JSd‐2, and Cu bound to HA was the major species identified in JSO‐1 (a soil sample).     

An Alternative Protocol for Single Zircon Dissolution with Application to (U‐Th‐Sm)/He Thermochronometry

Zircon (U‐Th‐Sm)/He (ZHe) thermochronometry is a powerful tool that has been widely used in geology to constrain the exhumation histories of orogens. In this study, we present an alternative protocol for dissolving zircon grains for determination of parent nuclides. This new alkali fusion procedure developed at the SARM (Service d'Analyse des Roches et des Minéraux) in Nancy, France, is fast (requiring only 2 d, including cleaning steps) and offers several advantages over conventional methods by avoiding: (i) use of HF pressure dissolution and (ii) complete removing of grains from the metal microvials. After dissolution, U, Th and Sm were measured using an ICP‐MS. We tested the new procedure on two different ZHe reference materials, the Fish Canyon Tuff and Buluk Tuff; these provided precision values for ZHe‐age estimations of 9 and 6% (1s), respectively. In addition, using this method, zircons from the Buluk Tuff are shown to be chemically more homogenous and more suitable for assessing the uncertainty of the entire integrated procedure.     

Community‐Derived Standards for LA‐ICP‐MS U‐(Th‐)Pb Geochronology – Uncertainty Propagation,Age Interpretation and Data Reporting

The LA‐ICP‐MS U‐(Th‐)Pb geochronology international community has defined new standards for the determination of U‐(Th‐)Pb ages. A new workflow defines the appropriate propagation of uncertainties for these data, identifying random and systematic components. Only data with uncertainties relating to random error should be used in weighted mean calculations of population ages; uncertainty components for systematic errors are propagated after this stage, preventing their erroneous reduction. Following this improved uncertainty propagation protocol, data can be compared at different uncertainty levels to better resolve age differences. New reference values for commonly used zircon, monazite and titanite reference materials are defined (based on ID‐TIMS) after removing corrections for common lead and the effects of excess ²³⁰Th. These values more accurately reflect the material sampled during the determination of calibration factors by LA‐ICP‐MS analysis. Recommendations are made to graphically represent data only with uncertainty ellipses at 2s and to submit or cite validation data with sample data when submitting data for publication. New data‐reporting standards are defined to help improve the peer‐review process. With these improvements, LA‐ICP‐MS U‐(Th‐)Pb data can be considered more robust, accurate, better documented and quantified, directly contributing to their improved scientific interpretation.     

基于OS071X测波雷达的波浪探测分析

文章利用舟山海洋环境监测站2014年第16号台风"凤凰"过境影响期间,对OS071X测波雷达和3m波浪浮标在同一海域内的波浪探测资料进行了对比验证。通过分析,OS071X测波雷达探测反演的有效波高、周期与3m波浪浮标探测结果对比,二者按先后顺序的均方根误差分别为0.27m和0.29m,相关系数分别为0.93和0.90。结果表明,OS071X测波雷达系统的探测精度得到了验证,能够满足实时探测近岸海域波浪的需求。     

Discussion on applying an analytical method to optimize the anti-freeze design parameters for underground water pipelines in seasonally frozen areas

Adopting the quasi-three-dimensional (Quasi-3D) numerical method to optimize the anti-freeze design parameters of an underground pipeline usually involves heavy numerical calculations. Here, the fitting formulae between the safe conveyance distance (SCD) of a water pipeline and six influencing factors are established based on the lowest water temperature (LWT) along the pipeline axis direction. With reference to the current widely used anti-freeze design approaches for underground pipelines in seasonally frozen areas, this paper first analyzes the feasibility of applying the maximum frozen penetration (MFP) instead of the mean annual ground surface temperature (MAGST) and soil water content (SWC) to calculate the SCD. The results show that the SCD depends on the buried depth if the MFP is fixed and the variation of the MAGST and SWC combination does not significantly change the SCD. A comprehensive formula for the SCD is established based on the relationships between the SCD and several primary influencing factors and the interaction among them. This formula involves five easy-to-access parameters: the MFP, buried depth, pipeline diameter, flow velocity, and inlet water temperature. A comparison between the analytical method and the numerical results based on the Quasi-3D method indicates that the two methods are in good agreement overall. The analytic method can be used to optimize the anti-freeze design parameters of underground water pipelines in seasonally frozen areas under the condition of a 1.5 safety coefficient.     

A new assessment model for evacuation vulnerability in urban areas

In the high-speed urbanization process of China, the urban population has been increasing significantly, leading to a high-density aggregation of population. However, the sharp increase in population density has not produced commensurate improvements in the road networks. On the contrary, the population increase induced a serious evacuation vulnerability, which cities experience during various hazards and catastrophic events. Therefore, research on evacuation vulnerability is important to urban planning. To assess the evacuation vulnerability, the optimal and worst scenarios should be considered because all possible evacuation plans occur between these extremes. However, most previous evacuation vulnerability studies are based on the worst-case scenario, only providing an upper bound of a potential evacuation assessment. To provide a more comprehensive theoretical basis for decision-makers to understand the consequences caused by all possible evacuations, this paper proposes an optimal evacuation vulnerability assessment model that provides the lower bound on potential evacuation difficulties. The model is solved by a stepwise spreading algorithm based on Graph Theory. Subsequently, to evaluate the effectiveness of the model, the study adopts the model to assess the evacuation capability of different road network topologies. A comparison with previous research was performed. The model was demonstrated in an application to the South Luogu Alley of Beijing, China. The significance of this paper is that the combination of our model with previous research may provide a more complete theoretical basis for an evacuation vulnerability assessment.     

Optimal routing for waste collection: a case study in Singapore

ABSTRACT

To collect and dispose growing amounts of municipal solid waste (MSW) changed to be a hot topic along with the rapid urbanization in past decades. Cities are more and more dependent on the incineration instead of landfilling due to the cost-efficiency and environmental concerns. Considering the limited number of incineration plants and complicated situation of transportation in both spatial and temporal dimensions in different cities, the optimal routing for waste collection turns to be meaningful research topic. In this research, the ant colony optimization (ACO)-based multi-objective routing model coupled with min-max model and Dijkstra’s algorithm is proposed to address the question of which route to take from these waste-generating points to the target incineration plant(s) considering travel time, accident probability (black spots), and population exposure, so as to support the routing decision-making. The model is successfully implemented in Singapore and the effectiveness of the model has also been justified. Besides, few limitations of this research have also been discussed, some of which would also be the future directions of our research, especially the design and integration of a web-based routing decision-making support system.     

Effects of initial step height on the headcut erosion of bank gullies: a case study using a 3D photo-reconstruction method in the dry-hot valley region of southwest China

Abstract

Headcut erosion has been recognized as one of the main processes involved in gully development in the dry-hot valley region of southwest China. To examine the effect of initial step height on headcut erosion processes, three headcuts were constructed ranging in height from 0.75 to 1.25 m on an active bank gully head, and a series of scouring experiments were conducted under a flow discharge of 120 L min^?1. The morphological evolutions of the plunge pools and soil loss volume were estimated by three-dimensional photo-reconstruction methods (3D-PR). As the step height increased, the experimental results showed that: (1) the transformed potential energy and shear stress would increase by approximately 4.89 J s^?1 and 26.4 Pa on average when the step height increased 0.25 m; (2) the mean depth and width of the plunge pool exhibited obvious growth, and the morphology of the cross-section developed from approximately V-shaped to U-shaped; and (3) soil loss volume increased logarithmically, with total soil loss volumes of 0.076, 0.105 and 0.116 m³, respectively. Although the significant effects of the initial step height on headcut erosion were verified, further quantitative studies are required to quantify the mechanism of headcut erosion, especially for plunge pool erosion.