“三江”中段两类碳酸盐岩容矿铅锌矿化成因的相关性——来自稀土元素地球化学研究的启示

世界范围内的碳酸盐岩容矿铅锌矿带内常在区域上出现以方解石等碳酸盐矿物为主要脉石矿物的富碳酸盐型铅锌矿化和以碳酸盐+萤石为主要脉石矿物的富氟型铅锌矿化这两种矿化形式,但不同元素组合的出现在成因上是否有相关性并不明确。青藏高原"三江"成矿带中段玉树地区同一矿集区内近同时发育了东莫扎抓富碳酸盐型和莫海拉亨富氟型铅锌矿床,二者均为碳酸盐岩赋矿,以逆断层为主要控矿构造,具有层控的矿体产状特征,矿石矿物均为方铅矿+闪锌矿,但是,东莫扎抓矿床以方解石+白云石等碳酸盐矿物为主要脉石矿物,莫海拉亨则以方解石+萤石为主要脉石矿物。研究表明,两个矿区含钙矿物的稀土元素地球化学特征存有差异。东莫扎抓矿区方解石的稀土元素具有轻重稀土元素分馏相对明显、轻稀土元素富集、Eu负异常明显的特征,在球粒陨石标准化配分模式图上呈现右倾或轻微右倾的"V"字形曲线。莫海拉亨矿区方解石及萤石轻重稀土元素分馏不明显,有明显的Eu负异常,球粒陨石标准化配分模式图上呈现轻微的"M"型曲线。稀土元素总量上,东莫扎抓(0.46×10-6~10.79×10-6)较莫海拉亨矿床(0.25×10-6~5.88×10-6)高。稀土元素地球化学特征揭示,两个矿床的含钙矿物都沉淀自与岩浆作用无关的热液流体,伴随硫化物沉淀,流体盐度降低,还原性变弱。莫海拉亨矿床除具有一套和东莫扎抓矿床来源一致的流体外,还具有另一套来自深部变质基底的富氟流体,这套流体控制了富氟型碳酸盐岩容矿铅锌矿床的沉淀位置,使其在区域上更靠近逆冲体系主逆冲带,且多在区域上最底层的碳酸盐岩地层中发育。这一认识解释了世界上多个碳酸盐岩容矿铅锌成矿带内同一空间、时间范围内两套不同类型铅锌矿床型式共同出现的原因。     

Linking pesticides and human health: A geographic information system (GIS) and Landsat remote sensing method to estimate agricultural pesticide exposure

Accurate pesticide exposure estimation is integral to epidemiologic studies elucidating the role of pesticides in human health. Humans can be exposed to pesticides via residential proximity to agricultural pesticide applications (drift). We present an improved geographic information system (GIS) and remote sensing method, the Landsat method, to estimate agricultural pesticide exposure through matching pesticide applications to crops classified from temporally concurrent Landsat satellite remote sensing images in California. The image classification method utilizes Normalized Difference Vegetation Index (NDVI) values in a combined maximum likelihood classification and per-field (using segments) approach. Pesticide exposure is estimated according to pesticide-treated crop fields intersecting 500 m buffers around geocoded locations (e.g., residences) in a GIS. Study results demonstrate that the Landsat method can improve GIS-based pesticide exposure estimation by matching more pesticide applications to crops (especially temporary crops) classified using temporally concurrent Landsat images compared to the standard method that relies on infrequently updated land use survey (LUS) crop data. The Landsat method can be used in epidemiologic studies to reconstruct past individual-level exposure to specific pesticides according to where individuals are located.     

White mica K–Ar geochronology of Sanbagawa eclogites from Southwest Japan: implications for deformation-controlled K–Ar closure temperature

White mica (phengite and paragonite) K–Ar ages of eclogite-facies Sanbagawa metamorphic rocks (15 eclogitic rocks and eight associated pelitic schists) from four different localities yielded ages of 84–89 Ma (Seba, central Shikoku), 78–80 Ma (Nishi-Iratsu, central Shikoku), 123 and 136 Ma (Gongen, central Shikoku), and 82–88 Ma (Kotsu/Bizan, eastern Shikoku). With the exception of a quartz-rich kyanite-bearing eclogite from Gongen, white mica ages overlap with the previously known range of phengite K–Ar ages of pelitic schists of the Sanbagawa metamorphic belt and can be distinguished from those of the Shimanto metamorphic belt. The similarity of K–Ar ages between the eclogites and surrounding pelitic schists supports a geological setting wherein the eclogites experienced intense ductile deformation with pelitic schists during exhumation. In contrast, phengite extracted from the Gongen eclogite, which is less overprinted by a ductile shear deformation during exhumation, yielded significantly older ages. Given that the Gongen eclogite is enclosed by the Higashi-Akaishi meta-peridotite body, these K–Ar ages are attributed to excess ⁴⁰Ar gained during an interaction between the eclogite and host meta-peridotite with mantle-derived noble gas (very high ⁴⁰Ar/³⁶Ar ratio) at eclogite-facies depth. Fluid exchange between deep-subducted sediments and mantle material might have enhanced the gain of mantle-derived extreme ⁴⁰Ar in the meta-sediment. Although dynamic recrystallization of white mica can reset the Ar isotope system, limited-argon-depletion due to lesser degrees of ductile shear deformation of the Gongen eclogite might have prevented complete release of the trapped excess argon from phengites. This observation supports a model of deformation-controlled K–Ar closure temperature.     

The Reliability of Assigned Values from the GeoPT Proficiency Testing Programme from an Evaluation of Data for Six Test Materials that have been Characterised as Certified Reference Materials

Assigned values derived from the GeoPT proficiency testing programme were compared with certified values for six certified reference materials that have been used as test materials in the GeoPT programme. Statistical analysis showed that there were few significant differences between these sets of data and that these differences had no significant impact on the GeoPT assessment when fitness‐for‐purpose criteria were taken into account.     

Reconsideration of the age of blueschist facies metamorphism on the Seward Peninsula, Alaska, based on phengite 40Ar/39Ar results

Abstract ⁴⁰Ar/³⁹Ar step-heating and single-grain laser fusion ages from phengites from the polydeformed and polymetamorphosed blueschist-greenschist facies Nome Group fall into two groups. Samples from the upper part of the structural section that have experienced a relatively weak metamorphic and deformational post-blueschist facies overprint and one sample from the Cape Nome orthogneiss yield plateau ages of 116-125 Ma. More intensely overprinted samples yield hump-shaped spectra with minimum ages of 123 Ma and maximum ages of 334 Ma. Samples with hump-shaped spectra are derived from a greater structural depth than most samples with plateau ages. Unreasonably old maximum ages from some of the disturbed spectra suggest that the hump-shaped spectra result from the incorporation of excess ⁴⁰Ar. This interpretation conflicts with previous interpretations of similarly disturbed spectra from the Brooks Range, which have been argued to provide minimum ages for blueschist facies metamorphism. Since the maximum temperatures achieved by all samples were probably above the blocking temperature of Ar in phengite, the 116-125 Ma plateau ages are a minimum age for blueschist facies metamorphism on the Seward Peninsula, Alaska.     

Detecting subtle hydrochemical anomalies with multivariate statistics: an example from ‘homogeneous’ groundwaters in the Great Artesian Basin,Australia

The major ion composition of Great Artesian Basin groundwater in the lower Namoi River valley is relatively homogeneous in chemical composition. Traditional graphical techniques have been combined with multivariate statistical methods to determine whether subtle differences in the chemical composition of these waters can be delineated. Hierarchical cluster analysis and principal components analysis were successful in delineating minor variations within the groundwaters of the study area that were not visually identified in the graphical techniques applied. Hydrochemical interpretation allowed geochemical processes to be identified in each statistically defined water type and illustrated how these groundwaters differ from one another. Three main geochemical processes were identified in the groundwaters: ion exchange, precipitation, and mixing between waters from different sources. Both statistical methods delineated an anomalous sample suspected of being influenced by magmatic CO₂ input. The use of statistical methods to complement traditional graphical techniques for waters appearing homogeneous is emphasized for all investigations of this type. Copyright © 2006 John Wiley & Sons, Ltd.     

BOOK REVIEWS

Books reviewed in this article: Aerial Photography and Remote Sensing Aerial photography and image interpretation for Resource Management . DAVID P. PAINE . Analytical Models and Techniques Spatial Processes Models and Applications A. D. CLIFF AND J. K. ORD Quantitative and Statistical Approaches to Geography: A Practical Manual JOHN A. MATTHEWS . Cartography and Maps Map Data Processing . HERBERT FREEMAN AND GOFFREDO G. PIERONI , eds. Computer-assisted Cartography: Principles and Prospects, 1982 . MARK S. MONMONIER . Cultural Navajo Architecture: Forms, History, Distributions . STEPHEN C. JETT AND VIRGINIA E . SPENCER . Rational Landscapes and Humanistic Geography . EDWARD RELPH . Economic The Structure and Control of a State Economy . W. L. L'ESPERANCE . Economic Geography . JAMES O. WHEELER AND PETER O. MULLER . The Myth of the Family Farm: Agribusiness Dominance of U.S. Agriculture . INGOLF VOCELER . Libya: The Experience of Oil . J. A. ALLEN . Geography of Public Finance, Welfare Under Fiscal Federalism and local Government Finance . ROBERT BENNETT . Environmental Management, Resources, and Systems Mountains and Man . LARRY W. PRICE . Environmental Geology . DONALD R. COATES . An Introduction to Environmental Systems . G. H. DURY . The Environment: Chinese and American Views . Edited by LAURENCE J. C. MA AND ALLEN G. NOBLE . Land Use in America . RICHARD H. JACKSON . Medical Conceptual and Methodological Issues in Medical Geography . MELINDA S. MEADE (ed.). Philosophy and Geographic Thought Birds in Egg/Eggs in Bird . GUNNAR OLSSON . PhysicaI Climatology: Selected Applications . J. E. OLIVER . Geomorphological Techniques . ANDREW GOUDIE (ed.). Political Politics, Geography and Behaviour . RICHARD MUIR AND RONAN PADDISON . The State of the World Atlas . MICHAEL KIDRON AND RONALD SECAL . Population The Population of the South . DUDLEY L. POSTON , JR . AND ROBERT H. WELLER , eds. Regional Latin America: Economic Development and Regional Differentiation . ARTHUR MORRIS . Developing the Amazon . EMILIO F. MORAN . Western Europe: A Systematic Human Geography . BRIAN W. ILBERY . Settlement Systems in Sparsely Settled Regions: The United States and Australia . RICHARD E. LONSDALEAND JOHN H. HOLMES , eds. African Perspectives: The Economic Geography of Nine African States . HARM DE BUJ AND ESMOND MARTIN , eds. Rural Nonmetropolitan America in Transition . AMOS H. HAWLEY AND SARA MILLS MAZIE , eds. Social Crime and Environment . R. NORMAN DAVIDSON . The Ghetto: Readings with Interpretations . JOE T. DARDEN , ed. Urban Urban Problems and Planning in the Developed World . MICHAEL PACIONE (ed.) Problems and Planning in Third World Cities . Edited by MICHAEL PACIONE . The City in West Europe . D. BURTENSHAW , M. BATEMAN , AND C. J. ASHWORTH .     

Relations entre production organique et apports terrigènes dans les sédiments fluviatiles holocènes : observations et conclusions hétérodoxes

Accumulation of organic matter in fens of fluvial valleys is often related to a low terrigenous matter delivery and to palaeoenvironmental conditions inducing low mechanical erosion. These assumptions come from the interpretation of contents in organic (MO) and mineral (MM) matters in sediments, expressed in percents, and then exactly anticorrelated. Calculation of mass accumulation rates of MO $(T_{{\mathrm{a}}_{\mathrm{MO}}})$ and MM $(T_{{\mathrm{a}}_{\mathrm{MM}}})$, expressed in g?m^?2?yr^?1, shows that $T_{{\mathrm{a}}_{\mathrm{MO}}}$ and $T_{{\mathrm{a}}_{\mathrm{MM}}}$ generally are not anticorrelated and that high values of $T_{{\mathrm{a}}_{\mathrm{MO}}}$ and $T_{{\mathrm{a}}_{\mathrm{MM}}}$ could appear simultaneously. That expression of MO and MM accumulation makes it possible to precise the climatic and human impact on sedimentation. To cite this article: J.-J. Macaire et al., C. R. Geoscience 337 (2005).     

<Superscript>40</Superscript>Ar/<Superscript>39</Superscript>Ar chronology and geochemistry of high-K volcanic rocks in the Mangkang basin,Tibet

Our two newly obtained high-quality ⁴⁰Ar/³⁹Ar ages suggest that the high-K volcanic rocks of the Lawuxiang Formation in the Mangkang basin, Tibet were formed at 33.5 ± 0.2 Ma. The tracing of elemental and Pb-Sr-Nd isotopic geochemistry indicates that they were derived from an EM2 enriched mantle in continental subduction caused by transpression. Their evidently negative anomalies in HFSEs such as Nb and Ta make clear that there is an input of continental material into the mantle source. The high-K rocks at 33.5 ± 0.2 Ma in the Mangkang basin may temporally, spatially and compositionally compare with the early one of two-pulse high-K rocks in eastern Tibet distinguished by Wang J. H. et al., implying that they were formed in the same tectonic setting.     

The eruptive history of the Tequila volcanic field, western Mexico: ages, volumes, and relative proportions of lava types

The eruptive history of the Tequila volcanic field (1600 km²) in the western Trans-Mexican Volcanic Belt is based on ⁴⁰Ar/³⁹Ar chronology and volume estimates for eruptive units younger than 1 Ma. Ages are reported for 49 volcanic units, including Volcán Tequila (an andesitic stratovolcano) and peripheral domes, flows, and scoria cones. Volumes of volcanic units 1 Ma were obtained with the aid of field mapping, ortho aerial photographs, digital elevation models (DEMs), and ArcGIS software. Between 1120 and 200 kyrs ago, a bimodal distribution of rhyolite (~35 km³) and high-Ti basalt (~39 km³) dominated the volcanic field. Between 685 and 225 kyrs ago, less than 3 km³ of andesite and dacite erupted from more than 15 isolated vents; these lavas are crystal-poor and show little evidence of storage in an upper crustal chamber. Approximately 200 kyr ago, ~31 km³ of andesite erupted to form the stratocone of Volcán Tequila. The phenocryst assemblage of these lavas suggests storage within a chamber at ~2–3 km depth. After a hiatus of ~110 kyrs, ~15 km³ of andesite erupted along the W and SE flanks of Volcán Tequila at ~90 ka, most likely from a second, discrete magma chamber located at ~5–6 km depth. The youngest volcanic feature (~60 ka) is the small andesitic volcano Cerro Tomasillo (~2 km³). Over the last 1 Myr, a total of 128±22 km³ of lava erupted in the Tequila volcanic field, leading to an average eruption rate of ~0.13 km³/kyr. This volume erupted over ~1600 km², leading to an average lava accumulation rate of ~8 cm/kyr. The relative proportions of lava types are ~22–43% basalt, ~0.4–1% basaltic andesite, ~29–54% andesite, ~2–3% dacite, and ~18–40% rhyolite. On the basis of eruptive sequence, proportions of lava types, phenocryst assemblages, textures, and chemical composition, the lavas do not reflect the differentiation of a single (or only a few) parental liquids in a long-lived magma chamber. The rhyolites are geochemically diverse and were likely formed by episodic partial melting of upper crustal rocks in response to emplacement of basalts. There are no examples of mingled rhyolitic and basaltic magmas. Whatever mechanism is invoked to explain the generation of andesite at the Tequila volcanic field, it must be consistent with a dominantly bimodal distribution of high-Ti basalt and rhyolite for an 800 kyr interval beginning ~1 Ma, which abruptly switched to punctuated bursts of predominantly andesitic volcanism over the last 200 kyrs.Electronic Supplementary Material Supplementary material is available in the online version of this article at Editorial responsility: J. Donnelly-NolanThis revised version was published online in January 2005 with corrections to Tables 1 and 3.An erratum to this article can be found at