湘南荷花坪锡多金属矿床成矿年代研究

荷花坪锡多金属矿床是本世纪初在南岭中段湘南地区新发现的一个大型矿床,区内的锡多金属矿化产在王仙岭岩体东南内、外接触带,已发现有Ⅰ、Ⅱ、Ⅲ和Ⅳ号4个主要锡多金属矿体。其中,Ⅰ、Ⅱ和Ⅳ号矿体由早期矽卡岩型和晚期蚀变碎裂岩型矿石组成,Ⅲ号矿体则由独立产出的蚀变碎裂岩型矿石组成,且包含有部分碎裂花岗斑岩。以往研究已对Ⅳ号矿体中的矽卡岩型矿石和Ⅲ号矿体中含矿斑岩脉分别采用辉钼矿Re-Os法和锆石SHRIMP U-Pb法进行了测年,获得的年龄分别为224.0±1.9Ma和142±2Ma。本文补充了晚期蚀变碎裂岩型矿石的~(40)Ar/~(39)Ar测年,结果显示,Ⅱ号矿体中蚀变碎裂岩型矿石白云母样品和石英样品的坪年龄分别为151.88±1.58Ma和155.39±7.04Ma;Ⅳ号矿体中蚀变碎裂岩型矿石石英样品的坪年龄为156.94±1.64Ma。结合前人研究资料综合分析,认为荷花坪矿区存在印支晚期(224Ma)、燕山早期(151~156Ma)和燕山晚期(142Ma)三期成矿作用,分别与区内印支期中粗粒含电气石黑云母花岗岩、燕山早期中粗粒黑云母花岗岩和燕山晚期花岗斑岩脉有关,不同期成岩、成矿作用的构造环境均为岩石圈的拉张伸展。湘南地区印支期(205~224Ma)基性岩浆活动及荷花坪矿床印支期成岩、成矿过程中均有幔源物质的参与,它们共同指示南岭地区中生代构造体制的转换或岩石圈伸展减薄可能始于印支主期(230~244Ma)之后的224Ma左右,即晚三叠世。     

基于HJ-1A/1B的2014年黄海海域浒苔灾害时空分布

自2007年以来, 黄海海域每年的5月初～8月中下旬浒苔(Ulva prolifera)会周期性地暴发与消亡,导致海洋生态环境被破坏以及经济损失。利用2014 年的HJ-1A/1B遥感影像, 利用神经网络监督分类及RULE规则影像重分类动态阈值法, 对2014年的浒苔的漂移路径、各时期影响的海域面积、分布面积以及暴发高峰期的最大面积进行了动态监测。结果表明, 2014年浒苔持续时间为101 d, 5月中旬开始在江苏省盐城市近海出现零星斑点, 分布面积为2.299 km², 影响面积为1 744.799 km²; 6月初到6月中旬浒苔广泛分布于黄海海域, 分布面积扩大至1 367.145 km², 达到当年的峰值; 从6月下旬开始, 浒苔进入衰退期, 浒苔分布面积、相对聚集密度均急剧缩小, 但影响面积的峰值出现在该时期; 8月初消亡于青岛附近海岸, 8月20日遥感影像已难以监测到浒苔的存在。2014年黄海海域浒苔经过了“出现—发展—暴发—衰退—消亡”5个发展阶段。     

Generalised observations of wave characteristics on near‐horizontal shore platforms: Synthesis of six case studies from the North Island,New Zealand

Most field studies of wave processes on shore platforms in front of eroding cliffs focus on a single site, revealing aspects of wave dynamics at that location. Here, we analyse data from six platforms around northeastern New Zealand and describe the fundamental control of shore platform width, gradient and elevation on wave processes, including greater attenuation of short‐period waves at lower tidal stages and increases in longer period wave energy towards the cliff toe. These data suggest that empirical formulae developed from coral‐reef environments provide better predictions of wave height on platforms than formulae currently used in shore platform models.     

AS350B3型直升机在中高山航空物探测量中的优势

中高山地区作业的航空地球物理勘探飞行器需要有高原适航性。通过对比空中国王350ER在起降条件、最大升限、最大续航能力及高原机动能力等特点,提出了在中高山地区的低高度、大比例尺的航空地球物理勘探飞行器的选型原则及飞行方法。通过甘肃某测区的实际测量飞行验证了该原则和方法的可行性。分析结果显示,AS350B3型直升机在中高山地区作业时表现出的实际飞行性能满足在该类型区域低高度、大比例尺的航空地球物理勘探的要求。     

内蒙古兴和县曹四夭超大型斑岩钼铅锌金成矿系统年代学及其地质意义

曹四夭斑岩钼矿床位于内蒙古兴和县,是华北克拉通北缘最大的钼矿床。该矿床中部发育斑岩型钼矿体,外围和上部产出热液脉型铅锌金矿体。文章选取1件与斑岩钼矿化共生的绢云母样品进行了40Ar-39Ar定年,获得40Ar-39Ar坪年龄为(144.4±1.2)Ma,相应的39Ar/36Ar-40Ar/39Ar等时线年龄为(146.4±2.2)Ma(MSWD=0.31),将等时线年龄认作绢云母的Ar封闭年龄,表明曹四夭斑岩钼矿化发生在约146 Ma前。选取14件脉型铅锌矿石中的闪锌矿、黄铁矿和磁黄铁矿样品开展了Rb-Sr定年,获得4件闪锌矿的Rb-Sr等时线年龄为(145.1±3.0)Ma(MSWD=0.63);5件黄铁矿的Rb-Sr等时线年龄为(145.2±1.3)Ma(MSWD=0.53);4件闪锌矿、5件黄铁矿和1件磁黄铁矿的Rb-Sr等时线年龄为(145.3±1.0)Ma(MSWD=0.43)。硫化物Rb-Sr定年结果表明曹四夭矿床脉型铅锌矿化形成于约145 Ma前。本次绢云母40Ar-39Ar和硫化物Rb-Sr定年结果表明,曹四夭矿床斑岩型钼矿化和脉型铅锌金矿化为同期产物,两者均形成于晚侏罗世末期,属于同一个斑岩成矿系统。曹四夭矿床硫化物的w(Rb)和w(Sr)分别为0.1867×10~(-6)~1.305×10~(-6)和0.3175×10~(-6)~6.935×10~(-6),Sr同位素初始比值(87Sr/86Sr)i介于0.709 919~0.711 951之间,平均值0.710 952,结合前人获得的辉钼矿Re含量,认为曹四夭矿床的成矿物质主要来源于地壳。     

皖南东至兆吉口铅锌矿床成矿时代的厘定及其找矿指示意义

皖南东至兆吉口铅锌矿床是近年来在江南过渡带西段新发现的一个规模达中型的中-低温热液型矿床。目前揭露的铅锌矿体均赋存于东至断裂带及其西侧次级张(扭)性断裂及裂隙中。文章选取了该矿床主要矿石矿物闪锌矿以及与主成矿阶段金属硫化物紧密共生的石英,分别采用流体包裹体Rb-Sr法和40Ar-39Ar法进行同位素地质年龄测定。4件闪锌矿样品获得流体包裹体Rb-Sr等时线年龄为(128±1)Ma;2件石英样品获得流体包裹体40Ar-39Ar坪年龄分别为(128.74±3.02)Ma和(128.19±1.98)Ma,等时线年龄分别为(128.81±5.25)Ma和(128.30±3.47)Ma,反等时线年龄分别为(128.82±5.24)Ma和(128.31±3.47)Ma。同位素地质年龄测试结果基本一致,表明兆吉口铅锌矿床形成于128 Ma左右,成矿时代为早白垩世。该成矿年龄与赋矿闪长玢岩的形成时间((129.0±2.3)Ma~(128.4±2.7)Ma)一致,也与东至断裂燕山晚期的活动年龄((126.3±2.2)Ma)相近,表明该矿床成矿与燕山晚期的构造-岩浆活动密切相关,此时区域构造背景为强烈挤压后的伸展环境。这一矿化事件在成矿时代上明显晚于长江中下游成矿带中的断隆区(如铜陵、安庆-贵池等矿集区)的铜金多金属矿床和皖南成矿带中的钨钼多金属矿床(136 Ma),而与长江中下游成矿带断坳区的玢岩铁矿床的成矿时间(135~127 Ma)相近,指示长江中下游成矿带与皖南成矿带之间的江南过渡带中发育有燕山晚期较晚阶段(128 Ma左右)的铅锌矿化事件,为今后在该区开展铅锌多金属矿床找矿勘探提供了重要依据。     

大兴安岭南段道伦达坝铜钨锡矿床成矿作用:来自锆石和独居石U-Pb和绢云母40Ar-39Ar年龄的约束

道伦达坝中型铜钨锡矿床位于大兴安岭南段,矿体呈脉状赋存于二叠系板岩及华力西期黑云母花岗岩的断裂破碎带中。道伦达坝矿床发育铜矿体、锡矿体、钨矿体、铜钨矿体、铜锡矿体、钨锡矿体和铜钨锡矿体。矿床的成矿过程可以划分为石英-萤石-白云母-电气石-锡石-黑钨矿阶段(Ⅰ阶段)、石英-萤石-黑钨矿-黄铜矿-毒砂-磁黄铁矿阶段(Ⅱ阶段)、石英-萤石-绢云母-黄铜矿-磁黄铁矿-黄铁矿-银矿物阶段(Ⅲ阶段)和方解石-石英-萤石-黄铁矿阶段(Ⅳ阶段)。道伦达坝矿床外围的张家营子岩体中的细粒花岗岩的LA-ICP-MS锆石U-Pb年龄为136.1±0.4Ma。Ⅱ阶段Cu-W共生矿体中2件独居石的LAICP-MS U-Pb年龄分别为136.0±2.3Ma和135.1±2.2Ma。Ⅲ阶段Cu矿体中1件独居石的LA-ICP-MS U-Pb年龄为134.7±2.8Ma。Ⅲ阶段铜矿体中1件绢云母的⁴⁰Ar-³⁹Ar坪年龄为138.8±0.47Ma,等时线年龄为140.0±1.1Ma。系统的定年结果表明,道伦达坝矿床的铜钨矿体和铜矿体均形成于早白垩世,它们属于同一个成矿系统;成矿与早白垩世高分异花岗岩有密切的成因联系。     

Box-Behnken设计-效应面法优选百合防褐变加工工艺研究

目的：优选百合防褐变的加工工艺。方法：在单因素试验基础上,以王百合苷B含量、褐变度、浸出物为评价指标,采用Box-Behnken设计效应面法考察烫片时间、干燥温度、干燥时间对其质量的影响,优选百合的防褐变加工工艺参数。结果:百合防褐变加工工艺为烫片时间3.5 min,干燥温度90℃,干燥时间3.0 h。结论：优选的百合防褐变加工工艺合理可行,可适用于工业生产。     

再探温跃层有孔虫B/Ca与温度和[CO32-]的依赖性及其在24 ka以来热带西太平洋次表层碳酸盐系统重建中的应用

The B/Ca ratio of planktonic foraminifer shells has been used as a proxy for reconstructing past ocean carbonate chemistry. However, recent studies have revealed significant uncertainties associated with this proxy, such as whether seawater temperature or [ CO_3~(2-)] is the dominant control on the partition coefficient(K_D) of planktonic foraminiferal B/Ca. To address these uncertainties and thus improve our understanding of the planktonic foraminiferal B/Ca proxy, we analysed B/Ca ratios in the tests of Neogloboquadrina dutertrei(300–355 μm) and Pulleniatina obliquiloculata(355–400 μm) in surface sediment samples from the tropical western Pacific and South China Sea. The relationship between these B/Ca ratios and bottom water calcite saturation states(Δ[ CO_3~(2-)]) is weak, thus suggesting only a small dissolution effect on the B/Ca of the two species. The correlation coefficients(R~2) between the B/Ca ratios of N. dutertrei and P. obliquiloculata and environmental parameters(e.g., temperature, salinity, phosphate, DIC and ALK) in the tropical western Pacific and South China Sea are not high enough to justify using B/Ca ratios as a palaeoenvironmental proxy in the study areas. The significant correlation between K_D values of N. dutertrei and P. obliquiloculata and carbonate system parameters(e.g.,[ CO_3~(2-)], DIC, ALK, pH and [ HCO_3~-]) in the study area reflect chemical links between the K_D denominator and these variables. Based on our surface sediment calibration, an empirical relationship between the K_D of N.dutertrei and temperature is proposed in the tropical western Pacific. We also generated a record of B/Ca ratios in N. dutertrei(300–355 μm) from Core MD06-3052 in the tropical western Pacific over the past 24 ka to evaluate the application of the revised B/Ca proxy method. Based on the reconstructed empirical relationship for B/Ca and subsurface seawater ALK, we estimated subsurface seawater carbonate system parameters in the tropical western Pacific since 24 ka. In general, the estimated subsurface seawater pH and [ CO_3~(2-)] show an increase with time, and the record of subsurface seawater pCO_2 shows a decrease with time, in the tropical western Pacific over the past 24 ka. The consistent trends in subsurface seawater pCO_2 and opal flux during deglaciation may imply that the reported increase in subsurface water pCO_2 in the study area was promoted by enhanced upwelling in the Southern Ocean.