小面元三维地震勘探技术在西山屯兰矿南五采区的应用

屯兰矿南五采区地形复杂,最大高差达271m,地表大面积为第四系黄土覆盖,激发困难。为探索研究小面元三维地震勘探技术的应用效果。在常规三维地震勘区域内划出1km^2,采用5m×5m小面元进行采集。在地震数据采集过程中,采取了加大激发井深、提高覆盖次数、减小CMP面元网格和加大接收排列等技术措施,做到“四小三高、二中一深、两个等高面”。通过插值、抽线及扩大面元处理。获得2．5m×2．5m×1ms、5m×5m×1ms、5m×10m×1ms、10m×10m×1ms以及不同叠加次数的三维数据体。资料解释工作主要是在5m×5m×1ms、2．5m×2．5m×1ms两个数据体上进行,解释落差大于或等于5m的断层6条,落差3～5m的断层8条;查明长轴直径20～30m的陷落柱4个。30～100m的陷落柱1个,大于100m的陷落柱3个。与相邻区常规三维地震比较,小面元三维地震勘探有利于对小陷落柱、小断层的控制和解释。     

提高管线探测水平分辨率的技术方法

在平顶山矿工路路面改造工程中,使用GX-2型及RD-4000型地下管线探测仪探测地下管网布设情况。根据地下管线种类、管线布设方位、埋置深度、探测难度大小进行了多次试验,在此基础上确定了电磁探测技术与方法：利用直连法提高被测管线中的交变电流,压制邻近平行管线和地下介质中的异常反映;在多管并存、且间距较小的情况下,应选择“梯度法”对磁场水平分量垂直梯度ΔHx进行观测,以得到最大清晰异常;另外,还应根据具体情况,合理选择诸如压制旁侧管线法、选择发射法、偏移感应法、动源发射法等发射方式,保证目标管线中有较强异常呈现。在管线密集区,应尽可能地降低工作频率,以减小旁侧管线中产生的二次电流及二次磁场;为防止信噪比下降,可适当减小收发距,以提高接收机的灵敏度。     

三维地震技术在煤层顶板稳定性研究中的应用

龙固井田为全隐蔽的华北型煤田,位于巨野煤田中部,其首采扩大区主采煤层为3号煤层。考虑3煤层顶板稳定性主要受其顶板的构造信息和岩性信息影响,因此首先依据三维地震勘探综合解释成果及波阻抗反演解释成果对二者进行定量化,然后对波阻抗数据进行归一化处理,使得波阻抗数据和量化后的构造数据具有相同的变化范围及等量贡献。在此距离范围内构造和岩性的权值各为0．5,依此生成综合因素煤层顶板稳定性隶属度。分析3煤层顶板以上10m、20m处的综合因素煤层顶板稳定性隶属度图可以发现,该区3煤层顶板稳定性比较好。且其稳定性主要是受构造因素控制,岩性因素相对影响较小。     

地震勘探技术在深部找煤中的应用

成矿理论与勘探实践证明,东部一些老矿由于勘探深度、范围的限制以及认识上的局限,在矿区深部、周边仍有一些矿未能发现和查明,其中相当一部分仍具有找矿潜力;而寻找西部新的煤炭资源是国家“稳定东部发展西部”战略需要。针对中国东西部不同的地质条件和勘探目标,其地震勘探野外施工方法及资料处理原则有所差异;而资料解释在东部以查明地层赋存形态、煤层赋存范围、构造发育特征为主,西部则以寻找煤系地层波阻抗差异明显、连续性好的反射波组为解释重点。地震勘探技术在中国东西部的二个典型地震时间剖面佐证了其在深部找矿的应用效果。     

A geophysical study of the granites and the sedimentary basins of the Xanthi area (N. Greece)

Intrusive features of varying size can be interpreted from the aeromagnetic map of the Xanthi area in N. Greece.The Xanthi pluton, which outcrops north of the city of Xanthi, seems to have the shape of a truncated pyramid. This feature has relatively large areal extent and reaches an approximate depth of 7 km. Another, relatively large magnetic body is buried under the sediments at the estuary of the Nestos River.3-D models of several smaller intrusions were constructed and the produced effect was compared to the observed. Some of these intrusions seem to be detached branches of the large Xanthi pluton.The basement in the outer part of the basin of the Nestos River seems to be buried at about 4 km depth. This figure is obtained by the Multiple Source Werner Deconvolution estimates and it is in agreement with the results of former geophysical studies and deep industrial boreholes.A 3-D model of the Xanthi-Komotini basin suggests that this basin is about 0.4 km deep at its southern part. The depth at its northern boundary is about 1.8 km while the boundary itself is formed by the large Kavala-Xanthi-Komotini fault.The Tertiary basin of the Nestos River and the observed magmatism are consistent with the idea of an older extensional tectonic regime in the area.     

Rate constants for the reactions of the NO3 radical with HCOOH/HCOO− and CH3COOH/CH3COO− in aqueous solution between 278 and 328 K

The kinetics of the aqueous phase reactions of NO₃ radicals with HCOOH/HCOO^– and CH₃COOH/CH₃COO^– have been investigated using a laser photolysis/long-path laser absorption technique. NO₃ was produced via excimer laser photolysis of peroxodisulfate anions (S₂O ₈ ^2– ) at 351 nm followed by the reactions of sulfate radicals (SO ₄ ^– ) with excess nitrate. The time-resolved detection of NO₃ was achieved by long-path laser absorption at 632.8 nm. For the reactions of NO₃ with formic acid (1) and formate (2) rate coefficients ofk ₁=(3.3±1.0)×10⁵ l mol^–1 s^–1 andk ₂=(5.0±0.4)×10⁷ l mol^–1 s^–1 were found atT=298 K andI=0.19 mol/l. The following Arrhenius expressions were derived:k ₁(T)=(3.4±0.3)×10¹⁰ exp[–(3400±600)/T] l mol^–1 s^–1 andk ₂(T)=(8.2±0.8)×10¹⁰ exp[–(2200±700)/T] l mol^–1 s^–1. The rate coefficients for the reactions of NO₃ with acetic acid (3) and acetate (4) atT=298 K andI=0.19 mol/l were determined as:k ₃=(1.3±0.3)×10⁴ l mol^–1 s^–1 andk ₄=(2.3±0.4)×10⁶ l mol^–1 s^–1. The temperature dependences for these reactions are described by:k ₃(T)=(4.9±0.5)×10⁹ exp[–(3800±700)/T] l mol^–1 s^–1 andk ₄(T)=(1.0±0.2)×10¹² exp[–(3800±1200)/T] l mol^–1 s^–1. The differences in reactivity of the anions HCOO^– and CH₃COO^– compared to their corresponding acids HCOOH and CH₃COOH are explained by the higher reactivity of NO₃ in charge transfer processes compared to H atom abstraction. From a comparison of NO₃ reactions with various droplets constituents it is concluded that the reaction of NO₃ with HCOO^– may present a dominant loss reaction of NO₃ in atmospheric droplets.     

Modelling of the vertical fluxes of nitric acid,ammonia, and ammonium nitrate

Results from numerical investigations regarding the exchange of HNO₃, NH₃, and NH₄NO₃ between the atmosphere and the biosphere are presented. The investigations were performed with a modified inferential method which is based on the generally accepted micrometeorological ideas of the transfer of momentum, sensible heat and matter near the Earth's surface and the chemical reactions among these nitrogen compounds. This modified inferential method calculates the micrometeorological quantities (such as the friction velocity and the fluxes of sensible and latent heat), the height-invariant fluxes of the composed chemically conservative trace species with group concentrationsc ₁=[HNO₃]+[NH₄NO₃] (total nitrate),c ₂=[NH₃]+[NH₄NO₃] (total ammonia), andc ₃=[HNO₃]-[NH₃] as well as the fluxes of the individual nitrogen compounds. The parameterization of the fluxes is based on the flux-gradient relationships in the turbulent region of the atmospheric surface layer. The modified inferential method requires only the data of wind velocity, temperature, humidity and concentrations (HNO₃, NH₃, and NH₄NO₃) measured at a reference height by stations of a monitoring network.     

LonGSp: A near infra-red spectrometer

We present a new cooled grating near infra-red spectrometer designed to acquire spectra at the TIRGO telescope in the 0.9÷2.5m region with a resolving power of 300÷4000, equipped with a Rockwell NICMOS 3 detector.     

Energy efficiency evaluation,technology gap ratio,and determinants of energy productivity change in developed and developing G20 economies: DEA super-SBM and MLI approaches

This study employed Slack-based measure (SBM), Meta-frontier analysis, and Malmquist–Luenberger index (MLI) approaches to measure energy efficiency (EE), production technology heterogeneity, and energy productivity variation and its main determinants in developed and developing G20 countries for the period 1995–2020. The study's findings are: (i) Average EE for G20 countries is 0.8577, but still has an improvement potential of 14.23 percent. (ii) Developed countries have a higher average EE than developing (0.8927 > 0.8290). Results further revealed that energy efficiency scores in Argentina, Australia, Brazil, France, Saudi Arabia, South Africa, the US, the UK, and Korea are>1. (iii) Technology gap ratio (TGR) value in developed countries is higher than in developing (0.9869 > 0.6801), indicating that developed countries have advanced energy technologies superiority. The average MLI is less than one, showing a decline in energy productivity mainly due to a decline in technical efficiency, as EC < TC. (iv) Developed G20 countries get 0.64 percent aggregate growth in energy productivity as their MLI score is 1.0064, mainly due to technological growth (TC = 1.0161). Developing G20 countries, on the other hand, witnessed a decline in their energy productivity during 1995–2020, as MLI = 0.9925 > 1, designating that, on average, there is a 0.75 % decline in MLI.     

Latitudinal variation of measured O3 photolysis frequencies J(O1D) and primary OH production rates over the Atlantic Ocean between 50° N and 30° S

The latitudinal variation of the photolysis frequency of ozone to O(¹D) atoms, J(O¹D), was measured using a filter radiometer during the cruise ANT VII/1 of the research vessel Polarstern in September/October 1988. The J(O¹D) noon values exhibited a maximum of 3.6×10^-5 s^-1 (2 sr) at the equator and decreased strongly towards higher latitudes. J(O¹D) reached highest values for clean marine background air with low aerosol load and almost cloudless sky. The J(O¹D) data, measured under these conditions and a temperature of 295 K, can be expressed by: % MathType!MTEF!2!1!+-% feaafiart1ev1aaatCvAUfeBSjuyZL2yd9gzLbvyNv2CaerbuLwBLn% hiov2DGi1BTfMBaeXatLxBI9gBaerbd9wDYLwzYbItLDharqqtubsr% 4rNCHbGeaGqiVu0Je9sqqrpepC0xbbL8F4rqqrFfpeea0xe9Lq-Jc9% vqaqpepm0xbba9pwe9Q8fs0-yqaqpepae9pg0FirpepeKkFr0xfr-x% fr-xb9adbaqaaeGaciGaaiaabeqaamaabaabaaGcbaGaamOsaiaacI% cacaqGpbWaaWbaaSqabeaaiiaacqWF8baFaaGccaqGebGaaeykaiaa% bccacqWF9aqpcaqGGaGaaeyzaiaabIhacaqGWbGaaeiiaiaabUhacq% GHsislcaaI4aGaaiOlaiaaicdacaaIYaGaeyOeI0IaaGioaiaac6ca% caaI4aGaaiiEaiaaigdacaaIWaWaaWbaaSqabeaacqGHsislcaaIZa% aaaOGaaeiiaiaabIhacaqGGaGaam4uaiabgUcaRiaaiodacaGGUaGa% aGinaiaacIhacaaIXaGaaGimamaaCaaaleqabaGaeyOeI0IaaGOnaa% aakiaadofadaahaaWcbeqaaiaaikdaaaGccaGG9bGaaeikaiaaboha% daahaaWcbeqaaiabgkHiTiaaigdaaaGccaGGPaaaaa!5EE9!\[J({\text{O}}^| {\text{D) }} = {\text{ exp \{ }} - 8.02 - 8.8x10^{ - 3} {\text{ x }}S + 3.4x10^{ - 6} S^2 \} {\text{(s}}^{ - 1} )\] where S represents the product of the overhead ozone column (DU) and the secant of the solar zenith angle. The meridional profile of the primary OH radical production rate P(OH) was calculated from the J(O¹D) measurements and simultaneously recorded O₃ and H₂O mixing ratios. While the latitudinal distribution of J(O¹D) and water vapour was nearly symmetric to the equator, high tropospheric ozone levels up to 40 ppb were observed in the Southern Hemisphere, SH, resulting in higher P(OH) in the SH.