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991.
An Intercomparison of NO2 and OClO Measurements at Arrival Heights, Antarctica during Austral Spring 1996 总被引:2,自引:0,他引:2
R. W. Sanders S. Solomon K. Kreher P. V. Johnston 《Journal of Atmospheric Chemistry》1999,33(3):283-298
For several years NO2 and OClO, two species important to understanding ozone destruction in the Antarctic stratosphere, have been measured at Arrival Heights, Antarctica by two groups: New Zealand's National Institute of Water and Atmospheric Research (NIWA) and the NOAA Aeronomy Laboratory in Boulder, Colorado. Using data independently collected by these two groups during the Austral spring of 1996, it is shown that the two data sets are in extremely close agreement. Besides offering validation of the instrumentation and analysis techniques of both groups, this result provides confidence in the more complete history of these species gained by combining the two data sets. 相似文献
992.
993.
铁水预处理用鱼雷罐、铁水罐的炉衬多为Al2O3SiCC砖,随着铁水脱硫量的加大,耐火材料的侵蚀也较严重。而现在由于市场需要钢水中的磷含量要求较低,脱磷处理过程中由于国外多采用氧化铁系脱磷剂,氧化亚铁对石墨的氧化很大,对炉衬侵蚀也大,这就要求对Al2O3SiCC砖的性能进行改进以适宜工艺需要。国内对脱磷的研究较少,实际生产对铁水进行脱磷处理的厂家也很少。为探讨脱硫、磷剂对耐火材料的影响,本文对不同脱硫、磷剂侵蚀Al2O3SiCC砖后的残砖的显微结构进行了分析,探讨了铝碳化硅碳砖的侵蚀原… 相似文献
994.
Muscovite-2M1 shows a major phase transition at about 800°C, which is generally attributed in the literature to the structural dehydroxylation
process, although a number of structural models have been proposed for the dehydroxylated phase, and different transformation
mechanisms have also been put forward. The observed first order transformation involves an increase in the cell volume, and
it is not clear to date how the cell expansion is related to the loss of hydroxyl groups. The phase change has been re-investigated
here by in situ high temperature powder diffraction, both in non-isothermal and isothermal modes, to combine for the first
time the structural and the kinetic interpretation of the transformation. The results unequivocally confirm that the reaction
taking place in the temperature range 700–1000°C is truly a dehydroxylation process, involving the nucleation and growth of
the high temperature dehydroxylated phase, having Al in 5-fold coordination. Structural simulations of the basal peaks of
the powder diffraction patterns indicate that the model originally proposed by Udagawa et al. (1974) for the dehydroxylated
phase correctly describes the high temperature phase. The kinetic analysis of the isothermal data using an Avrami-type model
yields values for the reaction order compatible with a reaction mechanism limited by a monodimensional diffusion step. Apparent
activation energy of the process in vacuum is about 251 kJ/mol. Experiments carried out at temperatures much higher than the
onset temperature of the reaction show that the dehydroxylation reaction overlaps with the reaction of formation of mullite,
the final product in the reaction pathway.
Received: 24 April 1998 / Revised, accepted: 12 October 1998 相似文献
995.
胜利油田边缘及外围找寻不同类型深部天然气的可能性 总被引:9,自引:0,他引:9
笔者依据对前人资料和本人研究成果的综合分析,提出在胜利油田的边部碱性橄榄玄武岩发育地带找寻无机成因二氧化碳气藏和在油田外围金伯利角砾岩筒或含地幔岩包体的碱性玄武岩火山口附近找寻地球深部来源烃类气藏的建议。 相似文献
996.
The sorption of AuCl4
−,AuCl2
− and Au(S2O3)3- on δ-MnO2 was investigated at pH2–11.6, 0.01 mol/L and 0.1 mol/L NaNO3 solutions. At pH 4 in two electrolyte strength solutions, Au sorption densities on δ-MnO2 are 0.18–0.21 and 0.28μmoL/m2 for AuCl4
− and Au(S2O3)2
3-, respectively, and the Au surface coverage is approximate to or lower than 1%. This adsorption of the two Au complexes decreases
as the solution pH increases, which conforms to the sorption regularity of the anion on δ-MnO2. The Au sorption decreases in the sequence of Au(S2O3)2
3- >AuCl4
− >AuC12
−. The intrinsic equilibrium constants (logK
int) of the three Au complexes are 1.17–2.7, much higher than those of Cu and Cd. The hydrolysis products of AuCl4
- are preferentially adsorbed by δ-MnO2 and the inner-sphere Au-surface complexes are formed on the surface.
Project supported by the National Studying-abroad Foundation, the National Natural Science Foundation of China (Grant No.
49573200) and the Australian Mining Industry. 相似文献
997.
数字地震仪(或雷达)的文件格式及其转换方法 总被引:3,自引:0,他引:3
详细介绍了SEG新规定的SEG-2标准及其文件结构,这一标准不但适用于数字地震仪,而且也适用于地质雷达等数字化记录设备。同时给出了一个在IBM-PC环境不读取SEG-2数据文件的C语言示范程序,根据这个示范程序,用户可以很方便地将SEG-2数据文件转换成适用于特定应用软件的数据格式。 相似文献
998.
Seawater samples were collected in the North Pacific along 175°E during a cruise of the Northwest Pacific Carbon Cycle Study (NOPACCS) program in 1994. Many properties related to the carbonate system were analyzed. By using well-known ratios to correct for chemical changes in seawater, the CO2 concentration at a given depth was back calculated to its initial concentration at the time when the water left the surface in winter. We estimated sea-surface CO2 and titration alkalinity (TA) in present-day winter, from which we evaluated the degree of air-sea CO2 disequilibrium in winter was. Using a correction factor for air-sea CO2 disequilibrium in winter, we reconstructed sea-surface CO2 in pre-industrial times. The difference between the back-calculated initial CO2 and sea-surface CO2 in pre-industrial times should correspond to anthropgenic CO2 input. Although the mixing of different water masses may cause systematic error in the calculation, we found that the nonlinear effect induced by the mixing of different water masses was negligible in the upper layer of the North Pacific subtropical gyre along 175°E. The results of our improved method of assessing the distribution of anthropogenic CO2 in that region show marked differences from those obtained using the previous back-calculation method. 相似文献
999.
本文主要论述了摆式波力电站的吸能机制,提出了吸能原理,从力和作功的角度探讨了吸能的实质,分析比较了几种摆板运动方程形式之间的联系和区别。给出了波能转换效率的定义,并进一步分析了波能转换效率的组成和性质。 相似文献
1000.
对黄河三角洲东北部地区的高分辨率水声学资料进行了综合研究。根据所记录的破坏土体变形程度、运动产生的平面形状和地貌特征形态,对土体失稳过程进行分类:浅表土体变形、塌陷凹坑、滑坡和沉积物重力流。结果表明:(1)浅表土体形变的变形程度最低,出现在研究区斜坡上部平滑海底,主要为绳网状泄水构造和表层拉张裂隙。(2)塌陷凹坑在研究区内广泛出现,是局部土体液化后发生了垂直沉降的结果。(3)滑坡多发生在水下斜坡的中上部,由弧形塌陷区、狭窄的冲沟通道和负地形沉积物堆积区组成。滑坡陡坎后缘发现拉张裂隙。(4)沉积物重力流是土体发生变形程度最大,搬运距离最长的土体破坏变形形式。局部区域多次受到沉积物重力流切割和充填作用。 相似文献